File name: Pandora197s1_Nagoya_20221202_L2Fit_fout2c42d20221101p1-8.txt File generation date: 20260324T110102.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c42p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v42d20221101.txt Level 1 file used: Pandora197s1_Nagoya_20221202_L1_smca1c42d20221101p1-8.txt.bz2 Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20221202 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0291 305.1703 305.3116 305.4528 305.5940 305.7352 305.8764 306.0176 306.1587 306.2999 306.4410 306.5822 306.7233 306.8644 307.0055 307.1466 307.2876 307.4287 307.5698 307.7108 307.8518 307.9929 308.1339 308.2749 308.4158 308.5568 308.6978 308.8387 308.9797 309.1206 309.2615 309.4024 309.5433 309.6842 309.8251 309.9659 310.1068 310.2476 310.3884 310.5292 310.6700 310.8108 310.9516 311.0924 311.2331 311.3739 311.5146 311.6553 311.7960 311.9367 312.0774 312.2181 312.3588 312.4994 312.6401 312.7807 312.9213 313.0619 313.2025 313.3431 313.4837 313.6242 313.7648 313.9053 314.0458 314.1864 314.3269 314.4674 314.6078 314.7483 314.8888 315.0292 315.1696 315.3101 315.4505 315.5909 315.7313 315.8716 316.0120 316.1524 316.2927 316.4330 316.5734 316.7137 316.8540 316.9943 317.1345 317.2748 317.4150 317.5553 317.6955 317.8357 317.9759 318.1161 318.2563 318.3965 318.5366 318.6768 318.8169 318.9570 319.0971 319.2372 319.3773 319.5174 319.6575 319.7975 319.9376 320.0776 320.2176 320.3576 320.4976 320.6376 320.7776 320.9175 321.0575 321.1974 321.3374 321.4773 321.6172 321.7571 321.8970 322.0368 322.1767 322.3165 322.4564 322.5962 322.7360 322.8758 323.0156 323.1554 323.2951 323.4349 323.5746 323.7143 323.8541 323.9938 324.1335 324.2731 324.4128 324.5525 324.6921 324.8318 324.9714 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221201T222748.6Z 8370.935979 89 1 49.51 2 82.81 123.28 149.65 12.39 0.00 1 0.00 1 0 25 3.527e-01 2.667e-02 3.282e-01 2.096e-02 6.559778e-01 1.152653e-02 7.671909e-03 -6.000000e+00 1.989662e-01 224.09 -2.00 3.39 -2.00 321.74 0.00e+00 4.534419e-03 5.475363e-03 4.714367e-03 -6.000000e+00 9.152345e-03 282.72 -2.00 20.00 -2.00 321.21 0.00e+00 7.364 0.006 302.00 328.00 3 1.0287e+00 4.0666e-02 8.2515e-02 -6.0000e+00 4.9012e-01 7.2647e-01 5.0906e-02 4.3261e-02 -6.0000e+00 5.3224e-01 -1.0763e+00 4.0002e-02 2.1841e-02 -6.0000e+00 3.1771e-01 4.4410e-01 1.9639e-02 6.3666e-03 -6.0000e+00 1.3909e-01 7.5438e-05 -6.2473e-04 6.2672e-04 1.2676e-04 -6.0000e+00 9.3605e-03 4.3523e-02 -4.3569e-05 12 8 8 10 0 0 99.72 16.27 0.90 0.04352 0.03883 50 11 1 5 0 989.990 21.38 14.99 16.27 11.78 27.1 917.72 111512 -67105 900000 57740 900000 168710 -10309 173571 -79125 -17792 -74724 -20383 -39627 -66062 2407 -50215 10902 39639 4621 -39242 25839 62535 -34215 22005 -48015 -10045 -63685 6689 11751 41313 -25181 -14008 81426 -18183 39130 -33936 25450 18614 84722 63295 41999 48415 18737 75582 5109 57411 16765 14208 16773 32740 -658 29221 12394 18493 56690 19445 37525 15352 5237 5456 2795 24552 7586 4458 16689 -3995 21317 -931 16669 3874 7931 6626 14848 179 103 -2385 -2485 -5818 -20524 -6514 -1869 3963 -4593 -1838 -2763 8347 1771 -2393 1593 -5150 2312 -8369 -1262 -2838 1398 -3240 1140 -216 -5855 2109 -2181 -303 -3853 -2036 -3101 -1689 -2211 -3659 1318 1905 3815 364 861 2217 -5236 -524 -2630 794 54 715 1810 261 2182 1504 3307 -1191 1790 -699 1028 -957 853 1282 -517 -903 -548 282 -334 2288 357 -467 -471 -2441 900000 2278 -3656 900000 1180 900000 3447 -211 3546 -3503 -463 -3331 -568 -1619 -4295 94 -3731 466 1325 223 -2915 960 1510 -2161 817 -3656 -522 -5441 261 415 1151 -1590 -911 2269 -1385 1526 -2647 1182 1072 2990 3174 2808 3147 1670 3790 512 3412 1495 1319 1558 2736 -84 3039 1634 2439 5791 2673 4753 2352 845 858 468 3662 1519 1020 3444 -971 3963 -224 3780 1140 2414 2085 4156 54 28 -590 -584 -1474 -6961 -2289 -729 1652 -2252 -927 -1507 4332 1027 -1477 934 -3072 1190 -4514 -621 -1519 826 -2344 918 -202 -6149 2000 -1987 -243 -3015 -1643 -2744 -1556 -2187 -3984 1527 2483 5378 553 1291 3143 -7595 -710 -3761 1167 85 1150 2821 397 3173 2132 4459 -1619 2340 -1027 1706 -1818 1730 2736 -1189 -2233 -1446 765 -930 6288 983 -1229 -1161 -5800 900000 SS 20221201T223851.7Z 8370.943654 92 1 49.21 2 80.94 125.05 149.05 17.42 0.00 1 0.00 1 0 17 3.101e-01 1.599e-02 7.162e-02 4.179e-03 5.824689e-01 2.214091e-03 7.580806e-03 -6.000000e+00 1.746068e-01 224.09 -2.00 3.39 -2.00 321.29 0.00e+00 6.160290e-03 1.024652e-03 6.416958e-03 -6.000000e+00 7.765874e-03 282.72 -2.00 20.00 -2.00 320.74 0.00e+00 6.025 0.003 302.00 328.00 3 3.3676e-01 7.5057e-03 7.2178e-02 -6.0000e+00 4.3048e-01 3.0843e-01 9.6543e-03 4.7403e-02 -6.0000e+00 4.6739e-01 -5.2376e-01 8.4815e-03 2.3105e-02 -6.0000e+00 2.7907e-01 2.2067e-01 4.1350e-03 6.1096e-03 -6.0000e+00 1.2162e-01 5.9097e-04 -5.7744e-04 1.2183e-04 1.4732e-04 -6.0000e+00 8.1325e-03 4.2938e-02 -2.8483e-05 12 8 8 10 0 0 17.03 16.27 0.94 0.04294 0.03860 143 31 1 5 0 344.000 21.38 15.00 16.27 12.63 27.0 922.19 -97623 -64471 -73392 -108280 -59883 -117487 -95932 -122793 -96183 -82991 -104518 -83791 -98536 -14711 -54133 -6569 -29816 -21674 -18743 -2225 -1879 -32601 -1495 -29005 -20000 -23880 -11300 -7133 -34192 -11277 -5992 -3734 -5646 2807 -10877 -10650 23 2747 15458 9246 21862 4311 17660 6232 15033 13593 12793 11338 6336 13140 5930 18492 12404 14146 9899 10461 9530 1530 4403 -797 9338 4379 8970 9543 8089 6050 1002 5050 477 5851 2865 4960 3038 942 569 -5466 -6324 -10174 -3281 -3356 -494 -1162 -1822 -1574 -428 1031 932 1472 621 1040 -2112 -2897 -2498 -4948 -2455 -2858 99 -686 166 -969 -2271 -1919 -2997 -1903 -3176 -1590 -1637 -169 570 1188 1637 1289 1079 -751 -621 -558 -248 254 88 72 309 2197 1756 1804 546 -31 472 178 390 -307 -91 -543 -162 -310 42 273 621 663 -5 -254 -951 -1044 900000 -2423 -1290 -1658 -3209 -954 -3133 -2132 -3866 -2494 -1937 -3020 -2173 -3686 -300 -2005 -175 -1093 -787 -694 -72 -60 -1365 -47 -1246 -815 -1035 -427 -246 -1507 -426 -253 -180 -314 148 -608 -642 1 187 1115 825 1879 465 1734 696 1550 1446 1387 1275 772 1585 848 2569 1976 2369 1795 1935 1802 307 831 -157 1746 958 2127 2492 2185 1595 272 1362 151 2012 1100 1914 1163 345 189 -1733 -1912 -3304 -1140 -1385 -230 -613 -1044 -952 -274 696 660 1061 448 711 -1384 -1789 -1489 -3193 -1761 -2388 92 -736 188 -1080 -2362 -1788 -2671 -1764 -3232 -1680 -1840 -201 747 1733 2593 2115 1743 -1175 -915 -801 -365 396 146 124 521 3506 2735 2709 802 -44 656 269 667 -588 -188 -1181 -370 -687 100 668 1544 1672 -14 -607 -2155 -2473 900000 SS 20221201T225932.6Z 8370.958016 103 1 1.94 2 77.56 128.51 147.46 26.28 0.00 1 0.00 1 0 17 1.866e-01 2.121e-02 1.584e-01 1.537e-02 4.583096e-01 7.747214e-03 5.478749e-03 -6.000000e+00 1.050910e-01 224.09 -2.00 3.39 -2.00 319.83 0.00e+00 7.575813e-03 2.326270e-03 1.933961e-03 -6.000000e+00 4.673050e-03 282.72 -2.00 20.00 -2.00 319.18 0.00e+00 4.511 0.001 302.00 328.00 3 1.8163e+00 2.2250e-02 4.9891e-02 -6.0000e+00 2.5910e-01 1.3805e-01 2.6183e-02 2.3008e-02 -6.0000e+00 2.8127e-01 -2.7213e-01 1.9878e-02 1.3895e-02 -6.0000e+00 1.6794e-01 1.2427e-01 1.0448e-02 7.2046e-03 -6.0000e+00 7.3217e-02 6.2871e-04 -4.8457e-04 4.3066e-04 9.1805e-05 -6.0000e+00 4.8921e-03 4.1105e-02 9.9446e-06 12 9 9 12 1 1 999.00 16.27 0.93 0.04110 0.03746 1 12 1 5 0 876.080 21.38 15.00 16.27 14.43 26.8 931.13 -91749 -45064 6660 -84707 -12922 -63168 -79554 -18486 -64078 -13252 -53168 27552 -27797 -5777 -24700 -12775 6164 -11696 3130 -13342 24315 -26696 6935 -29191 -9691 27049 6067 11335 12922 32403 -31051 11038 -3537 -1719 -5665 19427 -22060 -10787 17545 -139 7018 -3930 8356 1772 17077 21680 2039 7710 -1633 11559 7419 10196 6406 836 2316 3951 3967 5162 1853 3563 3386 4704 474 6806 5584 3253 -4658 1669 -544 -992 2269 2234 2078 -4325 -1494 -1924 -7069 -6046 -3615 -3371 -2040 1419 -3239 -27 -3980 2107 -904 -513 1771 2835 1660 -2797 -1585 -2051 -681 -2548 1574 -131 -1291 1613 -832 -1000 -4323 -399 -3571 -1987 -1057 -1953 1245 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