File name: Pandora197s1_Nagoya_20221230_L2Fit_fout2c42d20221101p1-8.txt File generation date: 20260324T110502.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c42p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v42d20221101.txt Level 1 file used: Pandora197s1_Nagoya_20221230_L1_smca1c42d20221101p1-8.txt.bz2 Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20221230 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0291 305.1703 305.3116 305.4528 305.5940 305.7352 305.8764 306.0176 306.1587 306.2999 306.4410 306.5822 306.7233 306.8644 307.0055 307.1466 307.2876 307.4287 307.5698 307.7108 307.8518 307.9929 308.1339 308.2749 308.4158 308.5568 308.6978 308.8387 308.9797 309.1206 309.2615 309.4024 309.5433 309.6842 309.8251 309.9659 310.1068 310.2476 310.3884 310.5292 310.6700 310.8108 310.9516 311.0924 311.2331 311.3739 311.5146 311.6553 311.7960 311.9367 312.0774 312.2181 312.3588 312.4994 312.6401 312.7807 312.9213 313.0619 313.2025 313.3431 313.4837 313.6242 313.7648 313.9053 314.0458 314.1864 314.3269 314.4674 314.6078 314.7483 314.8888 315.0292 315.1696 315.3101 315.4505 315.5909 315.7313 315.8716 316.0120 316.1524 316.2927 316.4330 316.5734 316.7137 316.8540 316.9943 317.1345 317.2748 317.4150 317.5553 317.6955 317.8357 317.9759 318.1161 318.2563 318.3965 318.5366 318.6768 318.8169 318.9570 319.0971 319.2372 319.3773 319.5174 319.6575 319.7975 319.9376 320.0776 320.2176 320.3576 320.4976 320.6376 320.7776 320.9175 321.0575 321.1974 321.3374 321.4773 321.6172 321.7571 321.8970 322.0368 322.1767 322.3165 322.4564 322.5962 322.7360 322.8758 323.0156 323.1554 323.2951 323.4349 323.5746 323.7143 323.8541 323.9938 324.1335 324.2731 324.4128 324.5525 324.6921 324.8318 324.9714 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221229T224723.0Z 8398.949572 63 1 49.39 2 82.58 125.26 135.90 44.66 0.00 1 0.00 1 0 25 3.369e-01 2.215e-02 2.166e-01 1.220e-02 7.162712e-01 6.533507e-03 8.210849e-03 -6.000000e+00 1.869588e-01 224.03 -2.00 3.39 -2.00 321.95 0.00e+00 3.922041e-03 3.273539e-03 6.781109e-03 -6.000000e+00 8.320278e-03 280.66 -2.00 20.00 -2.00 321.42 0.00e+00 7.171 0.006 302.00 328.00 3 5.6728e-01 2.3657e-02 8.6325e-02 -6.0000e+00 4.6096e-01 8.3566e-01 2.9494e-02 5.6875e-02 -6.0000e+00 5.0313e-01 -1.2292e+00 2.2635e-02 2.4795e-02 -6.0000e+00 3.0025e-01 4.9798e-01 1.1091e-02 5.6906e-03 -6.0000e+00 1.2753e-01 1.3423e-04 -1.1550e-03 3.4615e-04 1.3923e-04 -6.0000e+00 8.8001e-03 9.6924e-03 -7.9092e-05 12 8 8 10 0 0 76.22 16.17 0.73 0.00969 0.00101 58 13 1 5 0 851.390 20.87 15.00 16.17 11.01 27.1 931.17 -23021 -47062 87362 -11095 -26494 -15584 -89591 -79162 -102218 -47734 -65732 229884 -52174 -9382 42033 29034 54205 -30791 32779 -32965 3702 -6090 -11081 106309 -22714 1057 -33457 -28183 -19736 -19080 42030 37536 40793 -29727 16407 -49204 -2936 29010 14306 63306 10335 51142 36128 -2893 7554 17160 28186 28037 57600 10955 36021 8865 35751 17327 28650 28808 19106 35905 7703 14696 52 6391 17445 16029 22223 14595 23174 4470 13614 6199 8483 12466 6952 9333 -417 -9148 -12610 -6782 -8825 -3533 -2193 2407 -2202 1558 408 -1826 2742 -591 3666 -41 -1952 -2659 -2689 -3547 -4181 -4468 -5361 -62 -3303 -1237 -615 -3708 -5474 -3744 -4945 -4982 -1031 -974 -818 1686 2820 1738 494 -327 -1448 -1003 -719 902 69 276 881 1182 3258 1489 2149 -41 1863 165 781 1411 -244 -127 -924 460 -151 -205 245 479 697 -250 -121 -1102 -1560 -753 -2147 1039 -319 -736 -371 -3997 -3596 -6081 -1652 -2631 2735 -2257 -325 1046 942 1466 -2032 1170 -2246 168 -283 -527 1610 -1278 47 -2027 -1494 -897 -887 1227 1340 1588 -2444 781 -4205 -165 1349 913 2876 872 2987 2501 -294 678 1392 2043 2062 3564 1031 3172 1129 3743 2330 3579 3668 2705 4187 1127 1923 8 1004 2781 2918 3993 2744 3915 936 2867 1615 2362 3441 1977 2410 -107 -2264 -3016 -1566 -2363 -1076 -775 931 -977 704 199 -969 1459 -333 1972 -22 -991 -1278 -1257 -1760 -2388 -3009 -4261 -54 -3246 -1189 -548 -3044 -4188 -2869 -4160 -4446 -939 -961 -899 2062 3825 2537 735 -477 -2031 -1359 -991 1293 106 440 1372 1761 4605 2081 2890 -54 2374 229 1248 2553 -495 -274 -2133 1121 -398 -567 687 1358 1956 -674 -303 -2616 -3639 SS 20221229T232031.1Z 8398.972582 80 1 10.52 2 77.25 130.77 130.89 53.16 0.00 1 0.00 1 0 25 2.255e-01 1.178e-02 3.557e-02 2.659e-03 4.924698e-01 1.332147e-03 5.665188e-03 -6.000000e+00 1.251719e-01 224.03 -2.00 3.39 -2.00 320.21 0.00e+00 3.291561e-03 4.528120e-04 1.560428e-03 -6.000000e+00 5.569895e-03 280.66 -2.00 20.00 -2.00 319.57 0.00e+00 4.408 0.001 302.00 328.00 3 7.5698e-01 3.9206e-03 4.9811e-02 -6.0000e+00 3.0862e-01 5.6686e-02 4.7728e-03 2.5133e-02 -6.0000e+00 3.3684e-01 -1.7030e-01 4.0353e-03 1.3374e-02 -6.0000e+00 2.0101e-01 7.2997e-02 2.0674e-03 4.6325e-03 -6.0000e+00 8.5390e-02 1.9891e-03 -6.7646e-04 7.4689e-05 5.6461e-05 -6.0000e+00 5.8909e-03 8.7236e-03 -8.5777e-05 12 9 9 12 1 1 41.43 16.17 0.78 0.00872 0.00364 41 43 1 5 0 246.370 20.87 15.00 16.17 12.67 27.1 940.53 -73933 -65404 -68603 -70829 -76481 -84261 -83279 -86950 -68092 -65611 -58303 -59579 -29649 -43110 -30288 -21293 -14424 -6360 -2441 -5582 -7104 -6098 -15465 -7449 -9068 -9144 -12041 -13479 -11417 -10455 -5417 -1350 -1567 -5744 -7750 -9321 -7545 1256 1660 4892 5301 4909 2537 4122 6806 6764 3530 3806 5171 1409 4458 4354 5097 4275 3557 4621 2417 2116 518 1238 999 4191 4014 4418 3376 1960 -407 -99 921 1255 1696 1225 597 181 -770 -2166 -3607 -4530 -3682 -2905 -2006 -1853 -2564 -1628 -1394 -360 -28 494 1105 1071 281 -666 -2094 -1587 -1417 -672 554 930 144 -328 -1000 -1528 -1565 -979 -1154 -993 -714 -295 283 1265 1271 1224 1099 30 -601 -388 -538 -31 -93 -611 -395 768 1554 1036 760 49 455 395 170 185 -171 -194 -578 -164 184 24 550 580 106 -47 -386 -654 -875 -1603 -1511 -1747 -1787 -1821 -2251 -2311 -2796 -2031 -2042 -1708 -1885 -838 -1733 -1312 -988 -688 -302 -119 -294 -389 -326 -926 -440 -581 -614 -843 -919 -731 -686 -385 -107 -141 -576 -752 -889 -769 138 221 750 903 894 495 809 1311 1326 720 784 1071 316 1058 1142 1437 1306 1148 1522 834 729 176 413 346 1542 1663 2021 1613 905 -185 -45 455 647 959 726 353 102 -403 -1132 -1766 -2222 -1972 -1646 -1303 -1357 -2050 -1361 -1246 -341 -25 463 1028 1046 257 -569 -1714 -1313 -1295 -639 596 1129 190 -429 -1226 -1701 -1624 -1044 -1340 -1216 -920 -403 385 1882 2055 2050 1808 48 -890 -549 -772 -46 -150 -1037 -667 1245 2426 1566 1105 69 664 558 269 323 -300 -355 -1103 -330 395 50 1175 1260 231 -98 -824 -1332 -1759 SS 20221229T234953.1Z 8398.992976 93 1 9.39 2 72.89 136.10 126.00 59.64 0.00 1 0.00 1 0 17 1.257e-01 1.261e-02 1.031e-01 9.521e-03 3.857363e-01 4.705384e-03 4.387130e-03 -6.000000e+00 6.980030e-02 224.03 -2.00 3.39 -2.00 319.51 0.00e+00 1.729553e-03 1.283889e-03 5.155819e-04 -6.000000e+00 3.104946e-03 280.66 -2.00 20.00 -2.00 318.84 0.00e+00 3.348 0.001 302.00 328.00 3 3.6858e+00 1.3246e-02 3.7932e-02 -6.0000e+00 1.7210e-01 1.0832e-02 1.5585e-02 1.9082e-02 -6.0000e+00 1.8781e-01 -4.9013e-02 1.1948e-02 9.7007e-03 -6.0000e+00 1.1208e-01 2.1616e-02 6.2656e-03 3.1534e-03 -6.0000e+00 4.7626e-02 3.2091e-04 -2.4485e-04 2.7355e-04 3.3554e-05 -6.0000e+00 3.2836e-03 7.5432e-03 -5.1743e-05 12 9 9 12 1 1 999.00 16.18 0.69 0.00754 0.00570 2 3 1 5 0 3070.000 20.87 15.00 16.18 13.96 27.1 946.50 -56922 -21326 9086 -41860 -46146 -27658 -65106 -30945 -16263 -6615 19061 45041 -8909 50164 5336 -9507 -10822 4119 4034 5304 11693 -9449 7212 7397 -24587 -13891 5996 -5896 -1956 15890 -6854 15623 -5746 -5358 -1912 -4782 -2698 -5260 6354 1383 -2080 850 1478 2074 103 3841 4883 6360 -567 6829 301 -247 1971 2981 1719 -966 3186 -249 1089 -1177 1885 -2845 4901 3430 109 -1639 -3243 -1383 1266 -1202 1730 1284 1825 683 1483 -497 -635 -5014 2312 -4201 -1417 47 -2295 -1044 -1597 -115 -224 -175 2013 1769 2343 -1128 -1718 -1782 2 -2531 1480 548 59 -101 -456 -1560 -924 -932 -2265 -1178 -1550 -38 717 1351 1616 1007 407 808 -832 -592 -225 -844 -146 -23 -445 833 547 438 685 -289 62 653 841 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