File name: Pandora197s1_Nagoya_20230112_L2Fit_fout2c42d20221101p1-8.txt File generation date: 20260324T110703.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c42p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v42d20221101.txt Level 1 file used: Pandora197s1_Nagoya_20230112_L1_smca1c42d20221101p1-8.txt.bz2 Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20230112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0291 305.1703 305.3116 305.4528 305.5940 305.7352 305.8764 306.0176 306.1587 306.2999 306.4410 306.5822 306.7233 306.8644 307.0055 307.1466 307.2876 307.4287 307.5698 307.7108 307.8518 307.9929 308.1339 308.2749 308.4158 308.5568 308.6978 308.8387 308.9797 309.1206 309.2615 309.4024 309.5433 309.6842 309.8251 309.9659 310.1068 310.2476 310.3884 310.5292 310.6700 310.8108 310.9516 311.0924 311.2331 311.3739 311.5146 311.6553 311.7960 311.9367 312.0774 312.2181 312.3588 312.4994 312.6401 312.7807 312.9213 313.0619 313.2025 313.3431 313.4837 313.6242 313.7648 313.9053 314.0458 314.1864 314.3269 314.4674 314.6078 314.7483 314.8888 315.0292 315.1696 315.3101 315.4505 315.5909 315.7313 315.8716 316.0120 316.1524 316.2927 316.4330 316.5734 316.7137 316.8540 316.9943 317.1345 317.2748 317.4150 317.5553 317.6955 317.8357 317.9759 318.1161 318.2563 318.3965 318.5366 318.6768 318.8169 318.9570 319.0971 319.2372 319.3773 319.5174 319.6575 319.7975 319.9376 320.0776 320.2176 320.3576 320.4976 320.6376 320.7776 320.9175 321.0575 321.1974 321.3374 321.4773 321.6172 321.7571 321.8970 322.0368 322.1767 322.3165 322.4564 322.5962 322.7360 322.8758 323.0156 323.1554 323.2951 323.4349 323.5746 323.7143 323.8541 323.9938 324.1335 324.2731 324.4128 324.5525 324.6921 324.8318 324.9714 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230111T223337.0Z 8411.940011 273 1 48.16 2 84.94 121.12 59.42 258.81 0.00 1 0.00 1 0 17 7.107e-01 1.121e-01 5.641e-01 1.105e-01 9.550790e-01 6.265283e-02 1.114348e-02 -6.000000e+00 4.027231e-01 224.22 -2.00 3.39 -2.00 321.16 0.00e+00 -6.759641e-03 1.375640e-02 2.285264e-03 -6.000000e+00 1.925511e-02 280.01 -2.00 20.00 -2.00 320.41 0.00e+00 9.748 0.014 302.00 328.00 3 -3.3662e-02 1.8112e-01 1.0658e-01 -6.0000e+00 9.9693e-01 2.3401e+00 2.1277e-01 4.5360e-02 -6.0000e+00 1.0920e+00 -2.2910e+00 1.1794e-01 2.2768e-02 -6.0000e+00 6.5013e-01 7.9083e-01 6.3644e-02 8.5959e-03 -6.0000e+00 2.7646e-01 1.0357e-05 -4.4062e-03 2.8315e-03 1.3018e-04 -6.0000e+00 1.9270e-02 7.2292e-03 4.0547e-05 12 8 8 10 0 0 24.93 16.65 2.44 0.00723 -0.02588 13 3 1 5 0 3703.620 21.27 15.00 16.65 6.65 26.8 914.03 139610 73042 900000 119038 133422 -69813 44545 -18626 80137 -42569 -44523 900000 900000 44445 312815 183057 900000 74973 900000 18601 -33381 60081 34501 -50808 289465 57756 -2412 18059 900000 -32567 254500 107347 7186 -62177 116 900000 7478 900000 -9008 133767 -10237 900000 38832 -12417 900000 4325 -268 67422 -49056 -49207 4587 66590 14226 198966 312755 84226 95011 1293 -8172 -9272 76441 -45535 14883 -23050 -9022 -11058 -20645 15936 40393 106169 -1642 90695 -9378 24373 -9754 -28581 -51584 12870 3492 42838 6369 31805 -21072 12387 9232 1895 -37791 92308 18444 29933 -2229 -39391 22742 -288 21588 -4510 33320 13977 21596 -739 5128 -446 -2773 15417 -2486 9427 11328 13143 44571 16253 -3095 4806 6771 -3182 -6065 -9429 -142 -9865 2722 -6084 -2983 -3982 8498 13315 1040 7378 883 -4030 -8550 -5550 -3777 -1488 1749 -597 706 3440 -1495 3557 -1336 3358 1208 4699 -7539 15012 11781 900000 12800 14347 -23146 4790 -3505 8617 -10299 -10373 900000 900000 5177 33636 19684 900000 8062 900000 3167 -8674 6460 3710 -13203 31126 6210 -401 2118 900000 -5094 27366 11543 1054 -18842 17 900000 877 900000 -1585 14384 -2302 900000 5314 -2670 900000 676 -42 7250 -12468 -12987 762 7160 2503 21394 33630 9057 10216 278 -1757 -1813 8220 -12463 2473 -6309 -2293 -2810 -5651 3116 6713 11416 -514 12678 -3117 5766 -2832 -8605 -17750 2353 788 7831 1986 8892 -11103 4928 3971 917 -28039 18859 7735 10621 -1007 -24143 7336 -124 8589 -2764 16481 9769 15558 -676 4136 -335 -1879 8454 -1737 6183 7674 9469 26360 14855 -3960 6254 8955 -4619 -8740 -13585 -187 -15063 3864 -9682 -4458 -5652 10143 14747 1264 8171 1016 -5200 -13607 -10086 -7635 -3216 3931 -1484 1867 9320 -4323 9868 -3849 8739 2949 10155 -17591 SS 20230111T224708.1Z 8411.949399 276 1 49.43 2 82.60 123.23 62.11 260.93 0.00 1 0.00 1 0 25 2.976e-01 2.179e-02 2.554e-01 1.295e-02 7.593743e-01 7.012183e-03 8.546464e-03 -6.000000e+00 1.653491e-01 224.22 -2.00 3.39 -2.00 322.06 0.00e+00 5.414752e-03 3.645690e-03 5.765955e-03 -6.000000e+00 7.330582e-03 280.01 -2.00 20.00 -2.00 321.56 0.00e+00 7.191 0.006 302.00 328.00 3 5.2429e-01 2.5922e-02 8.4887e-02 -6.0000e+00 4.0795e-01 8.6588e-01 3.2596e-02 5.0542e-02 -6.0000e+00 4.4519e-01 -1.2459e+00 2.6165e-02 2.3812e-02 -6.0000e+00 2.6554e-01 5.0341e-01 1.2739e-02 6.4607e-03 -6.0000e+00 1.1272e-01 1.2853e-04 -1.6549e-03 3.6350e-04 1.4691e-04 -6.0000e+00 7.7735e-03 7.0599e-03 -6.9169e-05 12 8 8 10 0 0 -4.06 16.65 0.99 0.00706 -0.00538 61 13 1 5 0 810.170 21.27 15.00 16.65 7.73 26.8 920.76 -38876 -35503 -79496 -43427 -72142 -31516 -78992 26690 -61491 -68849 -6270 -101842 -74681 -55054 9878 -27828 57742 8466 5046 32028 -18686 -31114 -55699 93392 -5857 135721 -58237 11401 13498 -62292 275 2868 -20217 -805 -6521 11078 14887 30343 10563 38840 11585 29813 41913 52569 26776 23099 40259 15530 17414 12455 27379 9516 48227 37079 35152 34830 6703 17109 5778 18713 -6435 19944 -3413 22074 18016 13546 14002 8631 14944 17851 18134 14711 16278 11998 1132 -4388 -14704 -9387 -8545 -3410 2477 4292 840 -1118 -106 -1788 978 -981 687 2022 373 -344 -10759 -7835 -9088 -1192 -2585 321 834 -2519 -3833 -3161 -4688 -5437 -3059 -2808 -2452 -1582 413 3420 6 800 408 271 -420 24 -652 -432 -1031 -244 1484 2216 2098 2545 3101 -139 706 1301 381 -150 51 585 -699 -267 444 -116 940 -221 639 -555 -645 -520 -1268 -1064 -1046 -3682 -1280 -2354 -597 -2328 337 -1765 -2134 -101 -4444 -3001 -2276 261 -1246 1193 301 191 919 -858 -1500 -3326 1287 -222 1714 -3611 327 356 -3648 10 122 -1230 -43 -337 445 598 1185 594 1918 825 1849 2358 2656 1722 1538 2265 1141 1300 1030 2352 983 4020 3700 3729 3783 974 2183 781 2127 -951 2469 -608 3457 3117 2395 2423 1624 2907 3878 4306 3735 3968 2834 267 -970 -3362 -2087 -2148 -982 795 1556 347 -499 -50 -908 506 -532 365 1016 177 -155 -5246 -3909 -5269 -754 -1949 273 776 -2431 -3500 -2555 -3494 -4120 -2449 -2380 -2198 -1526 437 4022 8 1168 606 393 -586 33 -898 -627 -1605 -390 2285 3238 2965 3482 4085 -184 901 1770 606 -275 103 1268 -1627 -663 1177 -323 2647 -639 1813 -1516 -1640 -1232 -2943 SS 20230111T225815.1Z 8411.957119 279 1 49.19 2 80.72 125.01 64.34 262.62 0.00 1 0.00 1 0 25 3.593e-01 1.628e-02 9.743e-02 4.533e-03 6.543795e-01 2.383075e-03 7.536566e-03 -6.000000e+00 1.996106e-01 224.22 -2.00 3.39 -2.00 321.61 0.00e+00 7.472396e-03 1.194204e-03 3.506048e-03 -6.000000e+00 8.850673e-03 280.01 -2.00 20.00 -2.00 321.07 0.00e+00 5.897 0.003 302.00 328.00 3 5.1079e-01 8.3637e-03 6.7679e-02 -6.0000e+00 4.9248e-01 3.9020e-01 1.0982e-02 3.5990e-02 -6.0000e+00 5.3746e-01 -6.2102e-01 1.0101e-02 2.0790e-02 -6.0000e+00 3.2057e-01 2.5391e-01 4.8293e-03 8.3831e-03 -6.0000e+00 1.3606e-01 5.0934e-04 -9.6309e-04 1.2775e-04 1.4016e-04 -6.0000e+00 9.3858e-03 7.5864e-03 -8.2393e-05 12 8 8 10 0 0 8.91 16.65 0.91 0.00759 0.00035 130 28 1 5 0 378.290 21.27 15.00 16.65 9.01 26.6 927.38 -83941 -78950 -75589 -40864 -161010 -112097 -169668 -107469 -115961 -103144 -101392 -120141 -63521 -72735 -27500 -30570 -8183 -17864 4024 6821 -34951 -2398 -38398 -33176 -31933 -20162 -15235 -14063 -8380 -44716 -22642 -40373 468 -15805 1900 -5806 16845 17047 10130 10732 2186 20327 6368 19976 19559 18753 14770 -389 16321 1599 12012 11790 15863 16018 17779 16687 8730 7781 -1076 4749 3730 11169 9818 15276 12598 9494 5105 -126 3561 4336 6909 6887 5067 3339 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