File name: Pandora197s1_Nagoya_20230201_L2Fit_fout2c42d20221101p1-8.txt File generation date: 20260324T110905.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c42p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v42d20221101.txt Level 1 file used: Pandora197s1_Nagoya_20230201_L1_smca1c42d20221101p1-8.txt.bz2 Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20230201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0291 305.1703 305.3116 305.4528 305.5940 305.7352 305.8764 306.0176 306.1587 306.2999 306.4410 306.5822 306.7233 306.8644 307.0055 307.1466 307.2876 307.4287 307.5698 307.7108 307.8518 307.9929 308.1339 308.2749 308.4158 308.5568 308.6978 308.8387 308.9797 309.1206 309.2615 309.4024 309.5433 309.6842 309.8251 309.9659 310.1068 310.2476 310.3884 310.5292 310.6700 310.8108 310.9516 311.0924 311.2331 311.3739 311.5146 311.6553 311.7960 311.9367 312.0774 312.2181 312.3588 312.4994 312.6401 312.7807 312.9213 313.0619 313.2025 313.3431 313.4837 313.6242 313.7648 313.9053 314.0458 314.1864 314.3269 314.4674 314.6078 314.7483 314.8888 315.0292 315.1696 315.3101 315.4505 315.5909 315.7313 315.8716 316.0120 316.1524 316.2927 316.4330 316.5734 316.7137 316.8540 316.9943 317.1345 317.2748 317.4150 317.5553 317.6955 317.8357 317.9759 318.1161 318.2563 318.3965 318.5366 318.6768 318.8169 318.9570 319.0971 319.2372 319.3773 319.5174 319.6575 319.7975 319.9376 320.0776 320.2176 320.3576 320.4976 320.6376 320.7776 320.9175 321.0575 321.1974 321.3374 321.4773 321.6172 321.7571 321.8970 322.0368 322.1767 322.3165 322.4564 322.5962 322.7360 322.8758 323.0156 323.1554 323.2951 323.4349 323.5746 323.7143 323.8541 323.9938 324.1335 324.2731 324.4128 324.5525 324.6921 324.8318 324.9714 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230131T224317.9Z 8431.946735 180 1 49.09 2 81.25 118.38 118.73 350.50 0.00 1 0.00 1 0 25 5.253e-01 3.362e-02 4.717e-01 3.201e-02 7.598220e-01 1.763754e-02 8.727267e-03 -6.000000e+00 2.980394e-01 224.76 -2.00 3.39 -2.00 321.96 0.00e+00 -9.723029e-04 8.792611e-03 9.425470e-03 -6.000000e+00 1.336896e-02 279.64 -2.00 20.00 -2.00 321.42 0.00e+00 6.210 0.004 302.00 328.00 3 2.4876e+00 6.3503e-02 9.0264e-02 -6.0000e+00 7.3940e-01 7.9109e-01 8.0862e-02 8.2965e-02 -6.0000e+00 8.1019e-01 -1.1580e+00 6.4021e-02 3.1248e-02 -6.0000e+00 4.7992e-01 4.6705e-01 3.0926e-02 6.5073e-03 -6.0000e+00 2.0092e-01 4.4570e-05 -8.1422e-04 9.1200e-04 1.1862e-04 -6.0000e+00 1.4332e-02 2.6252e-03 -3.2797e-05 12 8 8 10 0 0 99.69 16.53 1.21 0.00263 -0.00349 33 7 1 5 0 1487.070 21.06 15.00 16.53 6.39 26.8 921.75 188109 -3593 -41172 50774 171435 -107816 -104009 900000 -125500 -1748 -91205 -59524 156145 -51344 900000 -35494 900000 7293 900000 26857 900000 -51934 7266 -58311 -85390 85564 67650 900000 15108 206376 -43515 -27580 150717 -14420 6815 119299 900000 -5678 39937 24761 20278 77990 -31200 92865 1517 131266 -4989 9250 129437 -2449 59482 77322 157257 22090 14085 8668 34631 2444 12225 43113 472 18255 27277 59317 21213 4689 -1538 -5426 25705 4479 14406 2346 27566 5770 -4527 470 -23469 13606 -9044 3954 1517 20294 -6109 -684 17846 -3749 6224 -1059 4846 -8277 440 -4108 -9272 -5761 -10296 2000 -7707 1818 -6357 1899 -2654 -4014 -2690 -3381 -3032 -3875 2642 -4106 -1045 2697 -617 4808 -2012 5171 -159 1484 -2960 1895 649 -1224 -389 301 4162 2014 2979 -2886 2137 227 854 1217 -827 338 -964 -1863 357 1042 274 914 -633 -560 83 -1067 -14 5864 -112 -1283 1583 5344 -4238 -4126 900000 -7113 -54 -3748 -1856 4867 -2110 900000 -1710 900000 258 900000 837 900000 -3091 248 -3883 -7864 2667 2109 900000 471 6433 -2713 -1719 4698 -942 334 3719 900000 -354 1897 1617 1535 3473 -4214 3584 142 4092 -489 796 4035 -258 3894 4700 4902 2720 1976 1324 4156 396 1696 4166 70 2447 3784 6749 3736 950 -326 -1235 4728 1173 3750 713 6359 1538 -1200 105 -6182 2524 -2382 1097 508 6484 -2799 -314 7260 -2010 3162 -592 2538 -4734 215 -1972 -4567 -2882 -6163 1243 -6175 1531 -6361 1752 -2391 -3266 -1962 -2509 -2424 -3310 2240 -4032 -1109 3153 -840 6632 -3008 7004 -216 1919 -4064 2611 962 -1909 -589 432 5845 2806 3973 -3944 2707 313 1355 2202 -1689 731 -2236 -4437 892 2712 731 2451 -1705 -1507 205 -2498 -31 SS 20230131T225614.2Z 8431.955720 185 1 49.29 2 78.94 120.47 119.06 353.66 0.00 1 0.00 1 0 25 4.008e-01 1.512e-02 7.650e-02 3.811e-03 6.652095e-01 1.991820e-03 7.678407e-03 -6.000000e+00 2.232344e-01 224.76 -2.00 3.39 -2.00 321.41 0.00e+00 6.708701e-03 9.566241e-04 4.142636e-03 -6.000000e+00 9.857980e-03 279.64 -2.00 20.00 -2.00 320.89 0.00e+00 5.029 0.002 302.00 328.00 3 1.0855e+00 6.7921e-03 6.1846e-02 -6.0000e+00 5.5150e-01 3.2409e-01 8.9651e-03 3.8975e-02 -6.0000e+00 6.0155e-01 -5.4063e-01 8.3899e-03 2.2146e-02 -6.0000e+00 3.5858e-01 2.2500e-01 4.0304e-03 8.0030e-03 -6.0000e+00 1.5208e-01 6.2636e-04 -9.8315e-04 1.0457e-04 1.4046e-04 -6.0000e+00 1.0468e-02 2.9576e-03 -8.3351e-05 12 8 8 10 0 0 99.17 16.53 0.83 0.00296 -0.00443 129 28 1 5 0 382.010 21.06 15.00 16.53 6.87 26.8 924.74 -164346 -124171 -97446 -118025 -119457 -104481 -141583 -137407 -127942 -112327 -122671 -130270 -71402 -73049 -31089 -49214 -22489 -20631 -21464 -20494 -23383 -32372 -25825 -6342 -13132 -20296 -37460 -28009 -45318 -25086 -8012 -8258 -2496 382 -10154 -6957 -2086 3292 -1200 9937 9790 8970 12674 15370 18653 10211 10080 8792 13108 17703 16996 14849 13669 11970 13576 8973 9596 5194 3439 1218 7174 7568 8430 8482 7540 6692 6669 2492 6848 6293 5312 3427 1763 2657 -1093 -1375 -4947 -4891 -4286 -2592 -1163 -2471 -1901 -1981 227 293 538 249 801 -180 366 -1199 -3110 -3521 -2824 -2252 -642 403 -452 -1066 -1191 -2359 -2984 -1965 -2289 -1751 -1165 -1344 -371 753 1149 1219 1079 184 -647 -828 -401 -46 -207 -176 114 1525 2301 1311 991 181 321 671 386 209 536 270 -515 -145 -84 -322 323 426 391 25 -456 -973 -1108 -4664 -2769 -1778 -2552 -2301 -1589 -3157 -3157 -2896 -2277 -2777 -3433 -1303 -1752 -620 -1413 -555 -544 -609 -595 -703 -1028 -768 -163 -377 -645 -1418 -927 -1730 -831 -265 -329 -109 19 -536 -339 -103 179 -82 720 793 780 1112 1342 1588 964 970 882 1310 1790 1908 1898 1925 1851 2170 1544 1673 934 606 214 1221 1412 1780 2027 1925 1679 1636 653 1889 2014 1891 1293 665 932 -361 -406 -1410 -1414 -1389 -988 -513 -1265 -1060 -1168 140 192 370 177 564 -123 231 -719 -1829 -2155 -1942 -1798 -587 420 -518 -1226 -1279 -2290 -2661 -1758 -2223 -1790 -1251 -1557 -469 1063 1797 2014 1786 296 -992 -1222 -597 -73 -345 -277 194 2450 3542 1971 1439 255 438 968 636 392 1094 533 -1078 -322 -200 -802 814 1089 993 61 -1042 -2097 -2333 SS 20230131T230215.7Z 8431.959904 188 1 41.08 2 77.88 121.47 119.17 355.13 0.00 1 0.00 1 0 25 3.820e-01 1.336e-02 5.183e-02 2.607e-03 6.174192e-01 1.358492e-03 7.123523e-03 -6.000000e+00 2.127923e-01 224.76 -2.00 3.39 -2.00 321.14 0.00e+00 6.470769e-03 6.086120e-04 2.864732e-03 -6.000000e+00 9.396020e-03 279.64 -2.00 20.00 -2.00 320.57 0.00e+00 4.624 0.001 302.00 328.00 3 1.0011e+00 4.4546e-03 5.5736e-02 -6.0000e+00 5.2571e-01 2.0267e-01 5.7607e-03 3.2984e-02 -6.0000e+00 5.7338e-01 -3.5955e-01 5.3651e-03 1.9488e-02 -6.0000e+00 3.4179e-01 1.4873e-01 2.6217e-03 8.0182e-03 -6.0000e+00 1.4498e-01 1.0566e-03 -8.6114e-04 7.2980e-05 1.1227e-04 -6.0000e+00 9.9763e-03 2.4779e-03 -6.3439e-05 12 9 9 12 1 1 98.07 16.53 0.76 0.00248 -0.00399 120 32 1 5 0 338.020 21.06 15.00 16.53 7.32 26.8 927.50 -149254 -114319 -123638 -103989 -110445 -106354 -127226 -126975 -109513 -118554 -125230 -110476 -94640 -68041 -36288 -30783 -28008 -26606 -17748 -19047 -26965 -27334 -24474 -19059 -18945 -9550 -22786 -33431 -40833 -21832 -13454 -10428 2718 -3622 -5024 -15913 -6350 -7632 -5249 12387 5374 7350 8112 7521 7949 7669 10007 7406 6243 8835 13555 8337 9861 7650 9698 5371 6676 5927 2936 3224 1994 5518 6258 7982 5333 4673 2983 200 3350 2628 4531 1976 2908 708 200 -3014 -4973 -5353 -4628 -3059 -2484 -1134 -1856 -1312 -703 -395 1163 876 1988 70 255 -1247 -2912 -2713 -2584 -1021 -590 267 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