File name: Pandora197s1_Nagoya_20240727_L2Fit_fwvt1c43d20230601p1-8.txt File generation date: 20240727T151441.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c43p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v43d20230601.txt Level 1 file used: Pandora197s1_Nagoya_20240727_L1_smca1c43d20230601p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20240727 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: VP4_July 2023 First and last pixel inside fitting window: 1617 1765 Nominal wavelengths inside fitting window [nm]: 492.0813 492.2028 492.3242 492.4457 492.5671 492.6886 492.8100 492.9314 493.0528 493.1741 493.2955 493.4168 493.5381 493.6594 493.7807 493.9019 494.0232 494.1444 494.2656 494.3868 494.5080 494.6292 494.7503 494.8715 494.9926 495.1137 495.2348 495.3559 495.4769 495.5979 495.7190 495.8400 495.9610 496.0819 496.2029 496.3238 496.4447 496.5656 496.6865 496.8074 496.9283 497.0491 497.1699 497.2907 497.4115 497.5323 497.6531 497.7738 497.8945 498.0152 498.1359 498.2566 498.3773 498.4979 498.6185 498.7391 498.8597 498.9803 499.1009 499.2214 499.3419 499.4624 499.5829 499.7034 499.8239 499.9443 500.0648 500.1852 500.3056 500.4259 500.5463 500.6666 500.7870 500.9073 501.0276 501.1479 501.2681 501.3884 501.5086 501.6288 501.7490 501.8692 501.9894 502.1095 502.2297 502.3498 502.4699 502.5900 502.7100 502.8301 502.9501 503.0701 503.1901 503.3101 503.4301 503.5500 503.6700 503.7899 503.9098 504.0297 504.1495 504.2694 504.3892 504.5090 504.6288 504.7486 504.8684 504.9881 505.1079 505.2276 505.3473 505.4670 505.5866 505.7063 505.8259 505.9456 506.0652 506.1847 506.3043 506.4239 506.5434 506.6629 506.7824 506.9019 507.0214 507.1408 507.2603 507.3797 507.4991 507.6185 507.7379 507.8572 507.9765 508.0959 508.2152 508.3345 508.4537 508.5730 508.6922 508.8114 508.9306 509.0498 509.1690 509.2882 509.4073 509.5264 509.6455 509.7646 509.8837 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240726T202959.1Z 8973.854157 202 1 27.05 2 84.69 70.25 30.65 207.39 0.00 1 0.00 1 0 29 1.050e-02 1.047e-02 1.353e-03 1.348e-03 1.649692e+04 1.089198e+02 1.034186e+03 -6.000000e+00 6.429208e+02 292.20 -2.00 20.00 -2.00 505.32 0.00e+00 3.132463e-03 3.946235e-05 1.713214e-04 -6.000000e+00 3.099380e-04 292.20 -2.00 20.00 -2.00 500.34 0.00e+00 1.531887e+00 2.786862e-02 9.828082e-02 -6.000000e+00 2.154144e-01 231.93 -2.00 3.39 -2.00 501.96 0.00e+00 9.361 0.013 489.00 513.00 1 5.7459e+00 2.1510e-03 1.6259e-02 -6.0000e+00 1.6622e-02 1.3173e-02 5.3087e-04 2.4413e-03 -6.0000e+00 4.2436e-03 1.3895e-03 6.9726e-03 1.4637e-04 9.3354e-05 -6.0000e+00 1.3034e-03 5.1620e-02 -2.0031e-04 12 9 9 12 1 1 -125.16 15.28 1.25 0.05162 0.09999 6 3 1 4 0 3861.930 20.67 14.99 15.28 35.47 19.0 1018.08 -2096 -1824 -690 349 556 1675 1347 1459 1150 108 -66 -947 -1108 -1337 -1120 -891 -463 235 276 699 675 1048 1016 1298 1146 626 434 -475 -1319 -1756 -1310 -578 285 212 189 -137 162 -52 -122 -60 411 784 1250 1607 1266 1151 772 -126 -566 -1329 -1791 -2233 -1415 -975 18 380 952 975 1174 1429 1443 1637 1370 959 449 128 -180 -632 -730 -1117 -1120 -691 -377 -247 -702 -1272 -1559 -1482 -1749 -1309 -1284 -1030 -900 -817 -404 -811 -625 -230 44 356 1118 1326 1278 1255 554 438 -559 -1345 -1763 -2254 -1495 -625 -33 0 -16 -655 -695 -674 -533 51 445 1126 1423 1873 2362 2481 1743 1436 679 -230 235 331 863 881 749 485 546 472 90 -207 -1219 -946 -1293 -1227 -1188 -392 25 372 533 767 931 531 740 260 153 -554 -954 -1462 -1568 -2119 -1788 -688 355 577 1750 1426 1543 1211 113 -69 -978 -1134 -1364 -1143 -918 -484 249 296 752 728 1130 1100 1340 1185 647 467 -506 -1386 -1824 -1355 -604 303 219 197 -143 168 -53 -125 -62 422 811 1302 1682 1334 1209 804 -130 -575 -1328 -1851 -2299 -1454 -969 18 389 981 1009 1214 1477 1495 1695 1418 990 460 130 -180 -627 -718 -1096 -1098 -678 -372 -244 -692 -1242 -1503 -1483 -1743 -1297 -1276 -979 -863 -788 -390 -786 -602 -220 42 339 1065 1261 1202 1211 521 399 -501 -1191 -1554 -2006 -1352 -581 -32 0 -15 -632 -669 -649 -515 50 435 1101 1393 1836 2323 2460 1751 1443 680 -229 229 320 831 851 727 472 532 459 87 -200 -1177 -903 -1239 -1185 -1164 -388 25 377 522 757 924 530 737 259 151 -543 -927 -1417 -1527 SQ 20240726T204307.4Z 8973.863280 205 1 9.98 2 82.15 72.04 31.92 213.04 0.00 1 0.00 1 0 29 1.035e-02 1.033e-02 1.235e-04 1.233e-04 1.342241e+04 9.556685e+00 8.383174e+02 -6.000000e+00 6.341742e+02 292.20 -2.00 20.00 -2.00 505.32 0.00e+00 2.644332e-03 3.602709e-06 1.452777e-04 -6.000000e+00 3.056659e-04 292.20 -2.00 20.00 -2.00 500.49 0.00e+00 1.166115e+00 2.523469e-03 8.634164e-02 -6.000000e+00 2.123327e-01 231.93 -2.00 3.39 -2.00 502.07 0.00e+00 6.817 0.005 489.00 513.00 1 7.5138e-01 1.9478e-04 1.2572e-02 -6.0000e+00 1.6387e-02 -2.8297e-03 4.8147e-05 2.0685e-03 -6.0000e+00 4.1791e-03 3.0534e-01 5.9332e-03 1.3783e-05 7.9214e-05 -6.0000e+00 1.2857e-03 2.0689e-02 4.6861e-05 12 8 8 10 0 0 34.02 15.28 1.26 0.02069 0.06184 536 116 1 4 0 18.000 20.67 15.00 15.28 35.70 19.2 1019.54 -2458 -1613 -708 73 844 1453 1587 1519 1065 417 -147 -731 -1150 -1351 -1280 -894 -240 360 437 610 688 889 1046 1278 1048 805 321 -420 -1226 -1553 -1408 -839 -33 334 313 198 99 -83 -187 -15 295 734 1073 1354 1401 1186 737 97 -590 -1395 -1932 -2056 -1541 -787 -30 483 734 917 1058 1325 1512 1489 1466 1156 733 192 -273 -598 -959 -1101 -978 -714 -331 -230 -646 -1129 -1424 -1520 -1558 -1540 -1313 -1192 -946 -830 -749 -725 -644 -375 50 409 969 1297 1320 1047 682 150 -465 -1229 -1779 -1904 -1370 -444 129 117 -264 -693 -785 -668 -266 187 557 992 1534 1913 2178 2294 1892 1269 630 273 162 469 677 719 719 591 387 302 138 -381 -869 -1190 -1373 -1179 -812 -451 -70 328 605 741 847 830 796 549 70 -624 -1231 -1595 -1445 -2413 -1607 -719 73 859 1495 1648 1580 1105 430 -151 -741 -1159 -1356 -1287 -906 -247 374 460 624 706 913 1077 1318 1083 830 328 -440 -1266 -1583 -1433 -863 -33 344 326 206 102 -85 -191 -15 303 757 1116 1415 1468 1241 765 100 -597 -1390 -1963 -2074 -1556 -778 -30 492 756 946 1092 1367 1561 1539 1513 1188 747 193 -273 -593 -944 -1079 -957 -702 -326 -228 -637 -1104 -1376 -1505 -1535 -1516 -1295 -1182 -913 -807 -732 -709 -628 -363 48 396 939 1255 1266 1020 648 139 -423 -1144 -1648 -1774 -1252 -417 125 113 -257 -680 -768 -653 -260 184 552 987 1528 1909 2184 2242 1864 1253 619 273 160 460 664 707 709 584 384 299 136 -374 -848 -1155 -1334 -1152 -802 -437 -69 325 606 748 860 846 811 558 70 -627 -1226 -1582 -1435 SQ 20240726T204317.7Z 8973.863399 205 2 9.98 2 82.11 72.07 31.94 213.11 0.00 1 0.00 1 0 29 1.032e-02 1.027e-02 1.255e-04 1.252e-04 1.340707e+04 9.690496e+00 8.365840e+02 -6.000000e+00 6.321744e+02 292.20 -2.00 20.00 -2.00 505.29 0.00e+00 2.657226e-03 3.663743e-06 1.464284e-04 -6.000000e+00 3.046996e-04 292.20 -2.00 20.00 -2.00 500.45 0.00e+00 1.154574e+00 2.563993e-03 8.543991e-02 -6.000000e+00 2.116541e-01 231.93 -2.00 3.39 -2.00 502.04 0.00e+00 6.793 0.005 489.00 513.00 1 7.8457e-01 1.9819e-04 1.2517e-02 -6.0000e+00 1.6335e-02 -2.4392e-03 4.9078e-05 2.0448e-03 -6.0000e+00 4.1655e-03 2.9661e-01 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