File name: Pandora197s1_Nagoya_20250127_L2Fit_fout2c43d20230601p1-8.txt File generation date: 20250128T002819.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c43p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v43d20230601.txt Level 1 file used: Pandora197s1_Nagoya_20250127_L1_smca1c43d20230601p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20250127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: VP4_July 2023 First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0252 305.1664 305.3077 305.4489 305.5901 305.7314 305.8726 306.0137 306.1549 306.2961 306.4372 306.5784 306.7195 306.8606 307.0017 307.1428 307.2839 307.4250 307.5661 307.7071 307.8482 307.9892 308.1302 308.2712 308.4122 308.5532 308.6942 308.8351 308.9761 309.1170 309.2579 309.3989 309.5398 309.6807 309.8215 309.9624 310.1033 310.2441 310.3850 310.5258 310.6666 310.8074 310.9482 311.0890 311.2297 311.3705 311.5112 311.6520 311.7927 311.9334 312.0741 312.2148 312.3555 312.4961 312.6368 312.7774 312.9180 313.0587 313.1993 313.3399 313.4804 313.6210 313.7616 313.9021 314.0427 314.1832 314.3237 314.4642 314.6047 314.7452 314.8857 315.0261 315.1666 315.3070 315.4474 315.5878 315.7282 315.8686 316.0090 316.1493 316.2897 316.4300 316.5704 316.7107 316.8510 316.9913 317.1316 317.2719 317.4121 317.5524 317.6926 317.8328 317.9730 318.1132 318.2534 318.3936 318.5338 318.6739 318.8141 318.9542 319.0943 319.2344 319.3745 319.5146 319.6547 319.7948 319.9348 320.0749 320.2149 320.3549 320.4949 320.6349 320.7749 320.9149 321.0548 321.1948 321.3347 321.4746 321.6145 321.7544 321.8943 322.0342 322.1741 322.3139 322.4538 322.5936 322.7334 322.8732 323.0130 323.1528 323.2926 323.4323 323.5721 323.7118 323.8516 323.9913 324.1310 324.2707 324.4103 324.5500 324.6897 324.8293 324.9689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250127T005558.5Z 9158.038872 158 1 51.02 2 61.69 144.94 64.37 180.62 0.00 1 0.00 1 7 257 1.354e-01 1.212e-01 5.382e-03 3.582e-03 1.150029e-01 1.759837e-03 3.762137e-03 -6.000000e+00 7.543411e-02 224.61 -2.00 3.39 -2.00 315.50 0.00e+00 5.022286e-03 1.655294e-04 1.195715e-03 -6.000000e+00 3.332288e-03 279.69 -2.00 20.00 -2.00 314.85 0.00e+00 2.099 0.000 302.00 328.00 3 4.9426e+00 4.4538e-03 2.0945e-02 -6.0000e+00 1.8630e-01 8.7035e-02 5.0068e-03 6.3014e-03 -6.0000e+00 2.0318e-01 -1.8547e-01 2.8858e-03 1.5166e-03 -6.0000e+00 1.2113e-01 7.2210e-02 1.2761e-03 1.0923e-03 -6.0000e+00 5.1422e-02 4.9323e-04 -6.7408e-04 9.9609e-05 3.6055e-05 -6.0000e+00 3.5363e-03 2.9284e-03 0.0000e+00 12 10 10 10 0 0 99.20 16.98 16.73 0.00293 -0.00214 15 3 1 5 0 3400.980 22.19 14.99 16.98 15.44 24.4 989.58 18258 24845 24375 15114 -1288 -12220 -15778 -12843 -7379 -6853 -13867 -17698 -10272 -3417 6955 14621 13424 12994 12984 14636 13617 7431 3999 3586 4289 3059 -569 -8506 -17031 -24236 -22161 -19656 -15218 -14829 -24862 -32975 -28375 -16398 -1284 10519 15906 18622 19478 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-11548 -23563 -31642 -31601 -22700 -13804 -6586 -3395 -114 6476 13390 18376 21635 21388 17359 7798 -4043 -15759 -23504 -20612 -12110 -1979 7813 13044 10433 2021 -8000 -15089 -10832 -1285 5427 9912 13556 18508 24350 29397 28201 20365 8650 -4371 -14750 -15990 -10737 -1241 7773 11051 10354 6914 -412 -9105 -17546 -27370 -28507 -22317 -15693 -10390 -10074 -10776 -5683 2113 9285 11891 15879 16443 11748 6539 -552 -3266 SS 20250127T010228.8Z 9158.043389 161 1 35.42 2 60.94 146.48 64.39 182.15 0.00 1 0.00 1 7 257 1.351e-01 1.233e-01 1.054e-03 8.019e-04 1.292513e-01 3.958266e-04 3.295136e-03 -6.000000e+00 7.524505e-02 224.61 -2.00 3.39 -2.00 314.56 0.00e+00 4.142608e-03 3.183792e-05 7.698622e-04 -6.000000e+00 3.324103e-03 279.69 -2.00 20.00 -2.00 314.02 0.00e+00 2.050 0.000 302.00 328.00 3 2.6427e+00 9.9526e-04 2.0891e-02 -6.0000e+00 1.8583e-01 1.2093e-01 1.1163e-03 7.7804e-03 -6.0000e+00 2.0267e-01 -2.0296e-01 6.4378e-04 2.3848e-03 -6.0000e+00 1.2083e-01 7.4865e-02 2.7830e-04 8.1681e-04 -6.0000e+00 5.1290e-02 4.9986e-03 -6.4076e-04 2.1665e-05 3.6401e-05 -6.0000e+00 3.5277e-03 3.5731e-03 0.0000e+00 12 11 11 12 1 1 98.37 16.97 16.73 0.00357 -0.00124 63 19 1 5 0 553.360 22.19 14.99 16.97 15.93 24.3 991.72 17648 22973 22662 14312 -2903 -15258 -17985 -12913 -6920 -5439 -12092 -17168 -12253 -2115 7281 13643 13918 12462 12381 12585 12054 7657 3800 3811 4062 4093 1640 -6087 -16297 -22616 -22342 -19664 -15760 -15017 -24643 -32476 -28504 -17089 -2155 10579 17023 18972 20147 19827 18038 16438 12182 6445 466 -3459 -2265 1819 4406 6498 6574 5577 4970 2958 -427 -1499 326 5921 12053 16374 13703 3039 -8880 -15809 -12862 -1718 6498 9844 9169 5214 -2181 -13869 -26080 -34691 -33834 -24416 -14555 -6882 -2139 612 6472 12909 17938 20421 20139 15955 7126 -3930 -15689 -22087 -18947 -10826 -1946 6875 11220 8733 1277 -7413 -12917 -9340 -1359 3633 7063 10334 14152 18906 22471 21674 15802 6665 -3748 -10846 -11782 -7721 -1017 5083 7558 6848 4487 -662 -6799 -12624 -18844 -19800 -14994 -10216 -7047 -6617 -6463 -3487 1731 5840 7851 9725 9889 7189 3681 -92 -2287 7335 9762 9715 6196 -1276 -6759 -8083 -5867 -3192 -2535 -5730 -8200 -5947 -1035 3609 6834 7059 6406 6457 6639 6444 4143 2086 2107 2271 2312 938 -3521 -9557 -13429 -13436 -12033 -9760 -9423 -15652 -20894 -18600 -11302 -1442 7168 11663 13134 14076 14012 12897 11896 8948 4791 351 -2626 -1740 1413 3467 5181 5311 4555 4109 2474 -362 -1281 282 5178 10670 14620 12406 2774 -8199 -14779 -12144 -1638 6250 9560 8988 5161 -2182 -12748 -24168 -32483 -32065 -23433 -14110 -6757 -2120 614 6560 13223 18523 21319 21231 16962 7649 -4259 -17172 -24440 -21180 -12207 -2216 7902 13057 10225 1510 -8831 -15560 -11370 -1673 4512 8864 13094 17987 24149 28843 28022 20597 8751 -4963 -14459 -15855 -10493 -1401 6527 9803 8913 6375 -869 -9004 -16856 -25345 -26912 -20574 -14164 -9837 -9328 -9187 -4996 2502 8529 11569 14438 14796 10851 5597 -142 -3534 SS 20250127T010743.7Z 9158.047033 164 1 4.38 2 60.36 147.74 64.44 183.39 0.00 1 0.00 1 7 257 1.344e-01 1.256e-01 4.213e-03 3.361e-03 1.197912e-01 1.672078e-03 3.358210e-03 -6.000000e+00 7.490604e-02 224.61 -2.00 3.39 -2.00 314.18 0.00e+00 4.720284e-03 1.257544e-04 6.176466e-04 -6.000000e+00 3.308782e-03 279.69 -2.00 20.00 -2.00 313.66 0.00e+00 2.013 0.000 302.00 328.00 3 3.4502e+00 4.1918e-03 2.0855e-02 -6.0000e+00 1.8500e-01 1.0475e-01 4.6871e-03 9.4032e-03 -6.0000e+00 2.0175e-01 -1.8114e-01 2.7097e-03 2.5324e-03 -6.0000e+00 1.2028e-01 6.4997e-02 1.1688e-03 1.0851e-03 -6.0000e+00 5.1066e-02 2.3383e-03 -7.5281e-04 9.0100e-05 3.2430e-05 -6.0000e+00 3.5112e-03 2.2411e-03 0.0000e+00 12 11 11 12 1 1 99.35 16.96 17.25 0.00224 -0.00342 3 10 1 5 0 1091.730 22.19 15.03 16.96 16.58 24.5 995.14 15765 22728 22636 13211 -2366 -15841 -17158 -12971 -7581 -5588 -10914 -19041 -12431 -2469 6975 12462 12997 12320 13063 11866 11855 8480 4522 3564 4182 3850 2414 -6032 -16039 -22597 -21633 -19087 -15662 -14539 -23403 -32033 -28100 -15746 -2534 11206 17071 19662 20565 20088 18666 16927 13560 7447 2319 -2452 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