File name: Pandora277s1_Nagoya_20250301_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20250904T075547.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 277 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora277_OF_v2d20230817.txt Instrument calibration file used: Pandora277s1_CF_v4d20250225.txt Level 1 file used: Pandora277s1_Nagoya_20250301_L1_smca1c4d20250225p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20250301 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo HCHO First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1229 305.2636 305.4043 305.5450 305.6857 305.8264 305.9670 306.1077 306.2483 306.3890 306.5296 306.6702 306.8108 306.9514 307.0920 307.2325 307.3731 307.5136 307.6542 307.7947 307.9352 308.0757 308.2162 308.3567 308.4971 308.6376 308.7780 308.9185 309.0589 309.1993 309.3397 309.4801 309.6205 309.7608 309.9012 310.0415 310.1818 310.3222 310.4625 310.6028 310.7431 310.8833 311.0236 311.1639 311.3041 311.4443 311.5845 311.7247 311.8649 312.0051 312.1453 312.2855 312.4256 312.5658 312.7059 312.8460 312.9861 313.1262 313.2663 313.4064 313.5464 313.6865 313.8265 313.9665 314.1065 314.2465 314.3865 314.5265 314.6665 314.8065 314.9464 315.0863 315.2263 315.3662 315.5061 315.6460 315.7858 315.9257 316.0656 316.2054 316.3452 316.4851 316.6249 316.7647 316.9045 317.0442 317.1840 317.3238 317.4635 317.6032 317.7430 317.8827 318.0224 318.1620 318.3017 318.4414 318.5810 318.7207 318.8603 318.9999 319.1395 319.2791 319.4187 319.5583 319.6978 319.8374 319.9769 320.1164 320.2559 320.3955 320.5349 320.6744 320.8139 320.9533 321.0928 321.2322 321.3716 321.5111 321.6505 321.7898 321.9292 322.0686 322.2079 322.3473 322.4866 322.6259 322.7652 322.9045 323.0438 323.1831 323.3223 323.4616 323.6008 323.7401 323.8793 324.0185 324.1577 324.2968 324.4360 324.5752 324.7143 324.8534 324.9926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250228T221305.5Z 9190.925758 55 1 5.79 2 80.63 106.27 88.24 95.88 0.00 1 0.00 1 0 17 4.679e-01 2.406e-02 3.641e-01 1.515e-02 6.809442e-01 8.068815e-03 8.477667e-03 -6.000000e+00 2.652208e-01 225.96 -2.00 3.39 -2.00 321.25 0.00e+00 3.607720e-03 3.805803e-03 7.263330e-03 -6.000000e+00 1.295180e-02 280.19 -2.00 20.00 -2.00 320.70 0.00e+00 5.846 0.003 302.00 328.00 3 2.4984e+00 2.6887e-02 7.4928e-02 -6.0000e+00 6.5752e-01 2.9979e-01 3.5890e-02 5.5767e-02 -6.0000e+00 7.1796e-01 -4.1059e-01 3.4587e-02 2.5476e-02 -6.0000e+00 4.2865e-01 1.5848e-01 1.6560e-02 5.8191e-03 -6.0000e+00 1.8348e-01 6.9948e-05 -1.5089e-04 4.1944e-04 1.5317e-04 -6.0000e+00 1.3019e-02 -3.4621e-03 0.0000e+00 12 9 9 12 1 1 -1569.87 26.27 0.57 -0.00346 -0.00460 3 4 1 5 0 1447.080 35.00 19.99 26.27 12.11 1.0 854.49 -139454 900000 900000 900000 -245262 -153788 -116126 -104519 13777 -181249 900000 -89048 -137850 -48116 -42794 97330 900000 -34428 3669 -69963 -59187 -90356 59457 55484 -103820 -29646 11447 1341 2679 130846 91225 28488 -21082 -11395 87434 -5849 -16502 13327 7607 39386 54107 8794 63455 31837 -580 5834 17640 7797 8810 1900 7471 18084 18248 32858 10710 12597 6683 770 15974 8382 11447 -628 13317 13110 20203 8627 4149 8787 1584 5578 19987 1407 -4715 -1938 2325 6940 -1865 -7571 -3813 -1644 -3175 -4110 -3048 -466 -3778 2001 2282 55 1492 -1672 -4633 -3144 -2408 60 -4642 -2968 2215 -1064 -803 581 -1955 -2781 -3478 -2172 -1456 -3265 -814 1686 -401 2858 546 494 449 -1649 327 -1817 -62 2211 -1190 90 2588 1747 1301 1370 986 2480 -1724 912 919 44 -431 -754 456 -459 -1096 1713 -57 666 732 -7 -1074 -290 -1799 -2059 900000 900000 900000 -9874 -2477 -1714 -1543 203 -5351 900000 -1315 -4255 -852 -884 1437 900000 -915 70 -2892 -2184 -4535 878 819 -7203 -1007 253 32 63 1932 1347 841 -1152 -572 1549 -268 -950 689 505 2209 2875 779 3372 2350 -60 577 1588 806 949 238 993 2403 2640 4414 1881 2250 1283 153 2641 1485 2079 -145 3047 3329 4891 2280 1145 2452 540 2083 6963 602 -2074 -770 796 2049 -578 -2626 -1480 -745 -1701 -2284 -1812 -286 -2565 1362 1620 40 1069 -1176 -3127 -1970 -1621 38 -3576 -2625 2156 -1213 -891 678 -2149 -2754 -3262 -2090 -1499 -3610 -933 2037 -506 3934 846 797 720 -2586 476 -2636 -91 3338 -1971 151 4130 2693 1948 1983 1382 3295 -2354 1312 1514 75 -815 -1513 956 -1038 -2473 3915 -135 1586 1721 -16 -2463 -621 -3875 SS 20250228T222247.7Z 9190.932497 60 1 54.46 2 78.73 107.77 86.31 97.20 0.00 1 0.00 1 0 25 3.311e-01 5.954e-03 6.441e-02 1.607e-03 6.032551e-01 8.404715e-04 6.514161e-03 -6.000000e+00 1.862680e-01 225.96 -2.00 3.39 -2.00 321.07 0.00e+00 2.447607e-03 3.867066e-04 9.924654e-04 -6.000000e+00 8.249662e-03 280.19 -2.00 20.00 -2.00 320.51 0.00e+00 4.944 0.002 302.00 328.00 3 1.2006e+00 2.7867e-03 5.7362e-02 -6.0000e+00 4.6114e-01 3.6724e-02 3.7583e-03 3.1011e-02 -6.0000e+00 5.0298e-01 -7.2683e-02 3.8158e-03 1.6464e-02 -6.0000e+00 2.9948e-01 2.1454e-02 1.8389e-03 5.7256e-03 -6.0000e+00 1.2641e-01 6.7181e-04 -4.9042e-04 4.5810e-05 6.9328e-05 -6.0000e+00 8.9233e-03 5.1990e-04 0.0000e+00 11 1 0 11 8 0 -1.88 26.27 0.41 0.00052 -0.00317 258 26 1 5 0 211.060 34.75 19.99 26.27 13.21 0.9 866.35 -116678 -113529 -84725 -122865 -129506 -107481 -97670 -90606 -118992 -116406 -83204 -70417 -61796 -50998 -13679 -34154 -3847 -25408 -4855 -25194 -14193 -27008 -34476 -12708 -17829 -8828 -25346 -21906 -24274 -16288 -12646 -4188 -1114 -9267 -9010 -14375 -11987 -3478 -2713 -1278 864 2537 5514 3731 -27 211 1051 -1666 1011 1980 1072 3424 2984 3302 1850 2770 1183 -384 131 346 628 2252 2935 3737 1697 1378 778 1792 959 1686 982 1308 954 -464 352 -1227 -2403 -2188 -1369 -1475 -900 -1699 -1356 -772 -716 409 366 1060 462 1242 311 -64 -557 -757 -403 15 843 122 307 -517 -711 -1201 -622 -1115 -990 -1154 -730 -325 412 479 440 561 133 -90 -256 -228 -118 -21 70 -193 251 395 177 513 160 -1 428 248 230 76 -105 -286 -108 -94 -130 -70 289 281 177 35 -285 -171 -414 -881 -938 -543 -1085 -1144 -781 -724 -723 -1407 -1427 -783 -692 -713 -676 -154 -550 -51 -460 -84 -565 -289 -635 -935 -305 -486 -230 -775 -628 -723 -500 -450 -162 -47 -436 -405 -703 -656 -214 -203 -110 81 248 546 384 -3 23 119 -200 124 261 160 555 531 631 377 583 258 -84 28 73 141 556 819 1138 536 422 238 571 350 698 442 602 429 -198 135 -431 -817 -775 -553 -707 -497 -1063 -912 -548 -544 327 279 817 389 986 232 -45 -382 -551 -332 13 830 136 363 -600 -761 -1159 -566 -1064 -1017 -1251 -835 -397 552 715 716 941 220 -142 -382 -329 -175 -33 115 -329 420 633 275 768 231 -2 580 361 379 141 -193 -551 -219 -202 -297 -168 702 692 431 82 -628 -357 -858 SS 20250228T222851.7Z 9190.936709 63 1 54.55 2 77.56 108.72 85.10 98.04 0.00 1 0.00 1 0 25 2.366e-01 5.475e-03 3.752e-02 1.144e-03 5.585820e-01 5.862959e-04 6.030362e-03 -6.000000e+00 1.330988e-01 225.97 -2.00 3.39 -2.00 320.73 0.00e+00 2.612059e-03 2.414781e-04 4.668623e-04 -6.000000e+00 5.894883e-03 280.19 -2.00 20.00 -2.00 320.13 0.00e+00 4.510 0.001 302.00 328.00 3 1.1282e+00 1.8189e-03 5.2349e-02 -6.0000e+00 3.2951e-01 2.1470e-02 2.3652e-03 2.8236e-02 -6.0000e+00 3.5941e-01 -3.9414e-02 2.3255e-03 1.4668e-02 -6.0000e+00 2.1400e-01 6.4653e-03 1.1521e-03 5.3794e-03 -6.0000e+00 9.0328e-02 1.1277e-03 -4.8238e-04 3.2570e-05 5.5189e-05 -6.0000e+00 6.3763e-03 6.6296e-04 0.0000e+00 10 0 0 10 0 0 39.00 26.27 0.39 0.00066 -0.00296 341 35 1 5 0 159.960 34.75 19.99 26.27 14.06 0.9 873.63 -76723 -86823 -65691 -80294 -103888 -94772 -46345 -83495 -50965 -77389 -62198 -56132 -46683 -39017 -25710 -12808 -15874 -2878 -16142 -18238 -14489 -15850 -16064 -8138 -7137 -12983 -16188 -14652 -9553 -7989 -3336 -4417 -10357 -5012 -9761 -7269 539 -2883 -1920 -1350 -1327 -59 1858 764 1893 1376 840 1782 552 1001 1078 1353 2343 1797 2078 2236 1114 -324 322 1158 1117 2366 2853 1971 1635 543 222 695 940 1143 977 466 740 62 -11 -1056 -1222 -1972 -1874 -1406 -866 -1311 -1812 -999 -716 -94 529 794 953 1152 726 47 -191 -614 -217 63 439 329 310 -282 -868 -882 -426 -976 -988 -1031 -699 -141 464 407 464 270 197 -71 -117 -212 -135 87 -213 -154 55 317 223 324 208 51 510 486 238 133 -151 -238 18 6 -105 38 278 132 130 82 -251 -214 -436 -607 -854 -540 -717 -1096 -933 -347 -1044 -512 -1071 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