File name: Pandora277s1_Nagoya_20250309_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20250904T075642.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 277 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora277_OF_v2d20230817.txt Instrument calibration file used: Pandora277s1_CF_v4d20250225.txt Level 1 file used: Pandora277s1_Nagoya_20250309_L1_smca1c4d20250225p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20250309 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo HCHO First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1229 305.2636 305.4043 305.5450 305.6857 305.8264 305.9670 306.1077 306.2483 306.3890 306.5296 306.6702 306.8108 306.9514 307.0920 307.2325 307.3731 307.5136 307.6542 307.7947 307.9352 308.0757 308.2162 308.3567 308.4971 308.6376 308.7780 308.9185 309.0589 309.1993 309.3397 309.4801 309.6205 309.7608 309.9012 310.0415 310.1818 310.3222 310.4625 310.6028 310.7431 310.8833 311.0236 311.1639 311.3041 311.4443 311.5845 311.7247 311.8649 312.0051 312.1453 312.2855 312.4256 312.5658 312.7059 312.8460 312.9861 313.1262 313.2663 313.4064 313.5464 313.6865 313.8265 313.9665 314.1065 314.2465 314.3865 314.5265 314.6665 314.8065 314.9464 315.0863 315.2263 315.3662 315.5061 315.6460 315.7858 315.9257 316.0656 316.2054 316.3452 316.4851 316.6249 316.7647 316.9045 317.0442 317.1840 317.3238 317.4635 317.6032 317.7430 317.8827 318.0224 318.1620 318.3017 318.4414 318.5810 318.7207 318.8603 318.9999 319.1395 319.2791 319.4187 319.5583 319.6978 319.8374 319.9769 320.1164 320.2559 320.3955 320.5349 320.6744 320.8139 320.9533 321.0928 321.2322 321.3716 321.5111 321.6505 321.7898 321.9292 322.0686 322.2079 322.3473 322.4866 322.6259 322.7652 322.9045 323.0438 323.1831 323.3223 323.4616 323.6008 323.7401 323.8793 324.0185 324.1577 324.2968 324.4360 324.5752 324.7143 324.8534 324.9926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250308T220243.4Z 9198.918558 165 1 54.47 2 80.47 102.47 116.92 346.16 0.00 1 0.00 1 0 17 5.794e-01 8.713e-03 2.729e-01 3.956e-03 7.631814e-01 2.149444e-03 8.098670e-03 -6.000000e+00 3.264617e-01 226.41 -2.00 3.39 -2.00 321.77 0.00e+00 7.001297e-03 1.216844e-03 1.252558e-03 -6.000000e+00 1.531429e-02 280.57 -2.00 20.00 -2.00 321.28 0.00e+00 5.755 0.003 302.00 328.00 3 1.5069e+00 8.0347e-03 6.9191e-02 -6.0000e+00 8.0887e-01 2.0853e-01 1.2204e-02 4.1488e-02 -6.0000e+00 8.8214e-01 -2.7808e-01 1.3376e-02 2.3079e-02 -6.0000e+00 5.2553e-01 1.0105e-01 6.0900e-03 1.1347e-02 -6.0000e+00 2.2343e-01 1.8763e-04 -6.7246e-04 1.0790e-04 1.3654e-04 -6.0000e+00 1.5690e-02 2.6214e-03 0.0000e+00 11 8 0 10 0 0 90.30 26.16 0.53 0.00262 -0.00243 130 13 1 5 0 418.970 34.75 19.98 26.16 9.62 1.1 834.31 -219547 900000 -132299 -254132 -264218 -112910 -195376 -193174 -131570 -117864 900000 -86899 -176959 -121982 107502 -72301 -93730 -102540 32126 92446 -94406 -7963 -82333 -48963 -34508 -4999 -4954 -9504 -29528 -35501 -50588 -52309 9027 -31002 21949 3930 -19820 -12281 -13749 6475 -5578 -846 3377 11375 3639 17798 -8679 11596 7404 -1036 2182 411 11216 13692 6724 634 7271 -1540 2435 3357 1528 5496 7099 7700 7789 6001 3358 3917 5126 2762 2858 2800 5326 548 343 -1574 -3455 -2093 -3719 342 -30 -1839 -1485 -1722 256 -1307 285 893 12 468 -841 -777 -678 -581 -1066 -1089 53 1015 -188 -312 -597 -1342 63 -582 -1269 -1754 -275 -186 298 178 318 422 264 -244 -406 -356 -318 -459 60 236 418 518 738 573 292 111 -333 637 105 380 -237 -459 -7 9 -79 251 210 120 131 73 -292 -260 -551 -1693 900000 -510 -3118 -3335 -435 -1370 -1490 -600 -496 900000 -366 -2482 -1326 415 -735 -1347 -1798 158 357 -1721 -61 -1414 -652 -423 -47 -47 -93 -373 -560 -1171 -1504 161 -848 339 74 -542 -379 -525 260 -280 -43 174 557 198 872 -579 671 480 -81 187 40 1086 1399 775 81 878 -199 293 400 198 780 1150 1393 1460 1129 658 817 1210 763 850 849 1516 151 85 -361 -786 -506 -1080 115 -12 -842 -735 -907 141 -775 174 550 7 271 -460 -403 -349 -325 -697 -840 47 1021 -204 -332 -583 -1169 50 -486 -1146 -1678 -276 -203 364 247 490 681 426 -381 -604 -517 -474 -724 100 397 679 800 1097 826 408 150 -446 925 178 727 -455 -940 -15 21 -197 645 548 316 340 180 -671 -561 -1181 SS 20250308T221129.2Z 9198.924643 170 1 54.55 2 78.72 103.80 117.32 348.20 0.00 1 0.00 1 0 17 4.224e-01 6.075e-03 8.021e-02 1.660e-03 6.667091e-01 8.807265e-04 7.102665e-03 -6.000000e+00 2.379722e-01 226.41 -2.00 3.39 -2.00 321.26 0.00e+00 2.331682e-03 4.316139e-04 6.259436e-04 -6.000000e+00 1.053996e-02 280.57 -2.00 20.00 -2.00 320.71 0.00e+00 4.939 0.002 302.00 328.00 3 1.1694e+00 3.0184e-03 5.9295e-02 -6.0000e+00 5.8967e-01 6.4804e-02 4.2085e-03 3.4623e-02 -6.0000e+00 6.4298e-01 -1.0604e-01 4.3915e-03 1.8093e-02 -6.0000e+00 3.8279e-01 3.3893e-02 2.0789e-03 6.4639e-03 -6.0000e+00 1.6144e-01 6.4026e-04 -5.3005e-04 4.6305e-05 7.3615e-05 -6.0000e+00 1.1386e-02 2.4624e-03 0.0000e+00 11 1 0 11 8 0 6.46 26.16 0.41 0.00246 -0.00152 266 27 1 5 0 205.050 34.75 20.00 26.16 10.51 1.0 843.44 -175887 -159690 -169040 -128797 -154863 -126957 -131256 -89174 -88703 -108725 -113599 -119055 -64992 -96035 -55068 -33746 -27019 -22714 -24154 -19137 -35955 -27848 -45868 -28277 -12909 -14965 -27114 -20103 -32715 -14553 -16504 -6597 -10295 -4897 -9748 -19959 -11794 -10452 -2057 -2220 -1110 2244 1626 5130 2307 406 451 -282 3114 2336 2130 2970 3643 3431 2183 3080 2647 2143 -355 1412 521 3642 4332 2472 1999 1327 1193 1657 1023 1871 1911 1111 982 -123 -1374 -1501 -3085 -1942 -1463 -1270 -872 -1777 -1007 -1261 -820 -124 553 1081 799 1017 638 -127 -402 -651 -268 90 650 359 175 -188 -929 -805 -399 -1251 -1171 -1112 -805 -223 277 274 525 457 51 -291 -105 -178 -81 -45 -214 -181 80 590 321 413 319 66 516 286 85 57 -4 -294 41 -52 -104 99 213 141 87 17 -221 -244 -343 -1527 -1340 -1617 -777 -1140 -729 -889 -459 -509 -816 -970 -1297 -536 -1399 -665 -387 -326 -291 -338 -268 -603 -482 -1025 -586 -249 -308 -628 -423 -800 -337 -476 -206 -380 -175 -352 -824 -516 -553 -123 -156 -86 179 136 424 200 37 42 -28 314 260 268 414 554 565 385 561 494 396 -65 255 101 769 1039 670 557 363 327 480 340 705 778 466 400 -47 -481 -476 -956 -629 -547 -565 -450 -1044 -635 -846 -586 -94 433 857 624 754 442 -83 -260 -453 -213 83 624 391 203 -212 -971 -751 -385 -1151 -1158 -1158 -886 -263 361 401 841 760 84 -460 -157 -259 -120 -71 -356 -308 132 930 490 609 453 90 692 416 140 106 -7 -577 84 -115 -246 243 530 357 217 40 -491 -512 -715 SS 20250308T221731.0Z 9198.928831 173 1 54.47 2 77.52 104.73 117.55 349.62 0.00 1 0.00 1 0 17 3.312e-01 5.860e-03 4.400e-02 1.172e-03 6.133951e-01 6.072629e-04 6.550932e-03 -6.000000e+00 1.865857e-01 226.41 -2.00 3.39 -2.00 320.93 0.00e+00 2.881342e-03 2.688790e-04 5.554564e-04 -6.000000e+00 8.263878e-03 280.57 -2.00 20.00 -2.00 320.35 0.00e+00 4.500 0.001 302.00 328.00 3 1.0767e+00 1.9404e-03 5.3937e-02 -6.0000e+00 4.6234e-01 3.6418e-02 2.6001e-03 3.1222e-02 -6.0000e+00 5.0413e-01 -5.7896e-02 2.6425e-03 1.6403e-02 -6.0000e+00 3.0013e-01 1.3127e-02 1.2867e-03 6.1944e-03 -6.0000e+00 1.2658e-01 1.1132e-03 -4.3850e-04 3.2823e-05 6.3266e-05 -6.0000e+00 8.9270e-03 2.1578e-03 0.0000e+00 11 1 0 11 8 0 -6.90 26.16 0.38 0.00216 -0.00114 366 37 1 5 0 148.820 34.75 19.99 26.16 11.28 1.0 850.05 -128771 -124492 -110403 -100353 -126472 -128499 -98075 -98922 -94875 -80700 -97822 -65949 -41796 -47598 -44110 -34876 -40174 -22822 -13370 -8909 -30346 -22710 -16864 -15312 -11585 -13124 -11048 -8214 -24606 -13329 -10876 -6162 -5756 -6437 -7237 -12268 -9567 -1648 -4731 -771 138 1809 609 2200 2348 2236 1118 1269 1662 1331 2449 2778 1422 2092 2158 1289 1121 732 716 274 551 3057 3592 2355 1944 1662 572 726 1340 939 1207 724 863 42 -417 -1203 -2252 -1719 -1847 -1245 -1199 -1625 -1534 -1200 -642 42 607 1135 914 1104 787 -48 -478 -460 -214 -58 433 345 170 -179 -859 -745 -483 -862 -1259 -981 -639 -107 189 605 523 406 192 -205 -223 -149 -197 -8 -153 -124 96 320 291 388 15 114 540 349 150 180 -50 -222 9 -101 -134 -2 361 262 73 69 -277 -276 -374 -1110 -1164 -929 -719 -1104 -1175 -744 -873 -897 -704 -1196 -701 -449 -696 -771 -650 -881 -464 -266 -178 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