File name: Pandora277s1_Nagoya_20250327_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20250904T080124.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 277 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora277_OF_v2d20230817.txt Instrument calibration file used: Pandora277s1_CF_v4d20250225.txt Level 1 file used: Pandora277s1_Nagoya_20250327_L1_smca1c4d20250225p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20250327 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo HCHO First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1229 305.2636 305.4043 305.5450 305.6857 305.8264 305.9670 306.1077 306.2483 306.3890 306.5296 306.6702 306.8108 306.9514 307.0920 307.2325 307.3731 307.5136 307.6542 307.7947 307.9352 308.0757 308.2162 308.3567 308.4971 308.6376 308.7780 308.9185 309.0589 309.1993 309.3397 309.4801 309.6205 309.7608 309.9012 310.0415 310.1818 310.3222 310.4625 310.6028 310.7431 310.8833 311.0236 311.1639 311.3041 311.4443 311.5845 311.7247 311.8649 312.0051 312.1453 312.2855 312.4256 312.5658 312.7059 312.8460 312.9861 313.1262 313.2663 313.4064 313.5464 313.6865 313.8265 313.9665 314.1065 314.2465 314.3865 314.5265 314.6665 314.8065 314.9464 315.0863 315.2263 315.3662 315.5061 315.6460 315.7858 315.9257 316.0656 316.2054 316.3452 316.4851 316.6249 316.7647 316.9045 317.0442 317.1840 317.3238 317.4635 317.6032 317.7430 317.8827 318.0224 318.1620 318.3017 318.4414 318.5810 318.7207 318.8603 318.9999 319.1395 319.2791 319.4187 319.5583 319.6978 319.8374 319.9769 320.1164 320.2559 320.3955 320.5349 320.6744 320.8139 320.9533 321.0928 321.2322 321.3716 321.5111 321.6505 321.7898 321.9292 322.0686 322.2079 322.3473 322.4866 322.6259 322.7652 322.9045 323.0438 323.1831 323.3223 323.4616 323.6008 323.7401 323.8793 324.0185 324.1577 324.2968 324.4360 324.5752 324.7143 324.8534 324.9926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250326T214600.9Z 9216.906955 87 1 55.47 2 78.63 94.91 66.01 129.27 0.00 1 0.00 1 0 25 6.538e-01 1.492e-02 4.089e-01 1.201e-02 6.309969e-01 6.599968e-03 6.728666e-03 -6.000000e+00 3.774636e-01 227.66 -2.00 3.39 -2.00 321.49 0.00e+00 -5.442819e-03 3.468658e-03 5.816253e-04 -6.000000e+00 1.831669e-02 281.89 -2.00 20.00 -2.00 320.94 0.00e+00 4.902 0.002 302.00 328.00 3 3.9850e+00 2.3767e-02 5.8439e-02 -6.0000e+00 9.4117e-01 9.9388e-03 3.3704e-02 3.4019e-02 -6.0000e+00 1.0283e+00 -9.2068e-02 3.4502e-02 1.7437e-02 -6.0000e+00 6.0656e-01 3.8803e-02 1.6028e-02 7.4046e-03 -6.0000e+00 2.5413e-01 4.2837e-05 -5.6240e-04 3.6155e-04 7.9213e-05 -6.0000e+00 1.8259e-02 1.4270e-03 0.0000e+00 12 8 8 10 0 0 12.39 26.30 0.84 0.00143 -0.00280 20 2 1 5 0 2773.280 35.00 20.02 26.30 18.83 0.6 909.36 -190352 -179618 -177178 900000 -197942 900000 -66258 900000 -158644 -126051 900000 900000 -152052 -61346 900000 211307 900000 -18356 167612 -52451 -77814 -57173 -51699 63048 281749 126166 -69743 3214 -15378 -48882 235333 141644 138409 86673 -15147 -11403 -11093 192685 6955 12266 22900 27103 30121 2224 -24780 -12646 -9942 9949 4483 23610 -6971 17875 7605 3921 11029 12727 8456 3193 -4092 11871 -7937 4734 -10769 3800 7913 5641 1552 4704 4681 7202 2415 9701 -2706 5887 -4452 -2408 346 4600 -6101 877 132 -1917 590 -3240 -4643 -2014 1284 -1951 743 -1821 1356 -1101 -67 1512 -2625 1675 -1106 333 -236 1197 -615 739 -2549 240 -139 -1569 65 773 -310 658 1659 866 807 -1123 -277 -1069 18 -1541 1760 -697 -506 643 -414 483 216 52 681 671 352 490 -64 -752 -431 -371 260 182 434 356 -1133 913 615 -160 -1034 -2226 -2101 -2072 900000 -2315 900000 -775 900000 -2164 -1474 900000 900000 -3556 -717 900000 2471 900000 -234 1960 -1059 -2068 -1276 -1209 737 3295 1475 -2595 55 -311 -1507 2752 1656 1619 1106 -515 -388 -436 2253 355 704 1315 1585 1761 173 -2529 -1156 -898 762 381 1807 -815 1824 946 550 1536 1840 1313 516 -687 1678 -1435 841 -2530 848 1725 1217 348 1085 1234 2121 809 3415 -1051 1962 -1489 -713 95 1264 -2140 340 60 -1000 325 -1974 -3079 -1385 895 -1428 521 -1245 837 -655 -39 913 -1876 1324 -1033 345 -260 1270 -611 651 -2200 211 -132 -1593 68 872 -390 918 2503 1365 1256 -1698 -392 -1479 25 -2309 2707 -1127 -802 967 -609 681 293 68 867 916 546 848 -121 -1504 -905 -829 618 450 1094 910 -2900 2183 1385 -342 -2217 SS 20250326T215239.4Z 9216.911567 90 1 55.05 2 77.28 95.89 64.98 130.57 0.00 1 0.00 1 0 17 2.378e-01 7.471e-03 2.443e-01 6.365e-03 5.697762e-01 3.427328e-03 6.115157e-03 -6.000000e+00 1.349961e-01 227.66 -2.00 3.39 -2.00 321.17 0.00e+00 -9.864119e-04 1.590080e-03 1.082961e-03 -6.000000e+00 6.558640e-03 281.89 -2.00 20.00 -2.00 320.57 0.00e+00 4.418 0.001 302.00 328.00 3 3.6563e+00 1.1522e-02 5.2559e-02 -6.0000e+00 3.3590e-01 2.8293e-02 1.5509e-02 3.0208e-02 -6.0000e+00 3.6624e-01 -6.3071e-02 1.5557e-02 1.5122e-02 -6.0000e+00 2.1776e-01 1.1490e-02 7.4967e-03 4.3336e-03 -6.0000e+00 9.4411e-02 9.7288e-05 -4.2633e-04 1.9138e-04 5.3036e-05 -6.0000e+00 6.5793e-03 -6.3054e-04 0.0000e+00 11 9 0 11 8 0 0.92 26.32 0.42 -0.00063 -0.00383 34 3 1 5 0 1618.900 35.00 20.00 26.32 19.09 0.6 911.56 900000 900000 900000 900000 -135719 -76351 -54330 22327 900000 -19556 -82909 -29665 -108489 -19527 -62325 53956 -41410 -22135 6146 -18552 27620 -24634 -29984 6188 -29093 39799 -9041 25141 93785 19518 15066 -19152 -6218 7773 9483 20559 1953 2859 -17847 1392 6037 7601 1744 -3089 -474 471 -3326 -2662 -6179 12497 5541 -2758 3816 51 -748 3069 -3390 551 2022 -2177 -849 79 -1291 4790 -3183 2346 3300 3883 419 2779 1228 714 14 2362 529 -92 740 -2743 -1033 -2088 -1839 -1136 -1067 -664 -551 648 1552 1567 472 824 90 -1387 -147 -946 8 191 578 -685 835 110 -805 -1404 -1274 -1374 -376 116 -366 677 -180 221 236 706 -77 -497 -429 -857 -514 -657 -227 313 602 -363 22 762 -32 611 401 694 -89 -341 -178 784 -21 102 -93 288 -14 378 111 89 -466 67 -871 900000 900000 900000 900000 -1607 -517 -337 138 900000 -121 -1028 -251 -2508 -231 -1370 426 -934 -449 100 -408 389 -597 -828 133 -968 696 -255 482 899 429 408 -853 -273 302 347 695 91 163 -1539 116 531 698 176 -331 -50 50 -371 -303 -759 1511 801 -481 679 10 -158 653 -786 121 426 -477 -193 20 -371 1414 -1028 688 945 1161 147 1087 528 317 6 942 195 -31 233 -923 -389 -936 -949 -653 -660 -434 -386 478 1189 1222 367 606 62 -906 -92 -626 6 163 559 -754 956 124 -839 -1326 -1143 -1290 -377 122 -409 800 -235 320 370 1134 -122 -752 -610 -1185 -722 -977 -358 505 957 -562 32 1088 -44 803 517 950 -138 -589 -330 1513 -43 221 -217 693 -34 943 276 211 -1050 142 -1853 SS 20250326T215809.7Z 9216.915390 93 1 54.74 2 76.16 96.71 64.13 131.67 0.00 1 0.00 1 0 17 2.453e-01 7.439e-03 1.312e-01 3.957e-03 5.309514e-01 2.041674e-03 5.763115e-03 -6.000000e+00 1.388916e-01 227.66 -2.00 3.39 -2.00 320.77 0.00e+00 2.141808e-03 8.471299e-04 8.185296e-04 -6.000000e+00 6.155411e-03 281.89 -2.00 20.00 -2.00 320.16 0.00e+00 4.085 0.001 302.00 328.00 3 3.3931e+00 6.4717e-03 4.8341e-02 -6.0000e+00 3.4500e-01 3.8771e-02 8.3291e-03 2.7007e-02 -6.0000e+00 3.7570e-01 -8.2264e-02 7.8222e-03 1.4012e-02 -6.0000e+00 2.2362e-01 2.6200e-02 3.8615e-03 4.7583e-03 -6.0000e+00 9.4225e-02 1.7816e-04 -2.9433e-04 1.1419e-04 5.4055e-05 -6.0000e+00 6.6126e-03 -1.3280e-03 0.0000e+00 11 8 0 10 0 0 -11.75 26.33 0.39 -0.00133 -0.00354 51 5 1 5 0 1073.210 35.00 19.99 26.33 19.41 0.6 915.43 -101207 -99825 -77999 -108977 -8817 13467 -52323 -66373 -92133 -112140 -82436 -29122 -43876 15146 -16999 -29796 -861 -29942 -23688 -24405 -13647 -11632 -10250 -9061 5291 -2322 7864 -25912 -17751 -10763 -726 -3492 -244 -6917 5376 -5031 -5537 -3918 4506 1735 -2035 2569 -2248 5523 643 1491 661 4157 -884 1008 1848 3328 4232 1808 3364 3594 2725 -556 1855 1508 607 2623 4260 149 1468 4155 -322 863 2635 1227 1660 23 451 588 -2066 -599 -516 -993 -3987 -269 -697 -2602 -3026 -808 -332 -143 9 639 1029 705 1204 318 -589 -1193 -614 -411 483 602 -388 -238 -681 -1189 -539 -393 -1323 -900 -347 482 414 604 -34 -46 386 -107 231 -490 -428 337 68 -224 851 207 237 118 -90 339 272 112 34 295 -240 0 64 66 6 114 -14 303 87 -55 -378 -62 -580 -1456 -1576 -1012 -1797 -49 61 -514 -861 -1713 -2675 -1533 -368 -800 191 -358 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