File name: Pandora277s1_Nagoya_20250501_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20250904T081432.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 277 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora277_OF_v2d20230817.txt Instrument calibration file used: Pandora277s1_CF_v4d20250225.txt Level 1 file used: Pandora277s1_Nagoya_20250501_L1_smca1c4d20250225p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20250501 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo HCHO First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1229 305.2636 305.4043 305.5450 305.6857 305.8264 305.9670 306.1077 306.2483 306.3890 306.5296 306.6702 306.8108 306.9514 307.0920 307.2325 307.3731 307.5136 307.6542 307.7947 307.9352 308.0757 308.2162 308.3567 308.4971 308.6376 308.7780 308.9185 309.0589 309.1993 309.3397 309.4801 309.6205 309.7608 309.9012 310.0415 310.1818 310.3222 310.4625 310.6028 310.7431 310.8833 311.0236 311.1639 311.3041 311.4443 311.5845 311.7247 311.8649 312.0051 312.1453 312.2855 312.4256 312.5658 312.7059 312.8460 312.9861 313.1262 313.2663 313.4064 313.5464 313.6865 313.8265 313.9665 314.1065 314.2465 314.3865 314.5265 314.6665 314.8065 314.9464 315.0863 315.2263 315.3662 315.5061 315.6460 315.7858 315.9257 316.0656 316.2054 316.3452 316.4851 316.6249 316.7647 316.9045 317.0442 317.1840 317.3238 317.4635 317.6032 317.7430 317.8827 318.0224 318.1620 318.3017 318.4414 318.5810 318.7207 318.8603 318.9999 319.1395 319.2791 319.4187 319.5583 319.6978 319.8374 319.9769 320.1164 320.2559 320.3955 320.5349 320.6744 320.8139 320.9533 321.0928 321.2322 321.3716 321.5111 321.6505 321.7898 321.9292 322.0686 322.2079 322.3473 322.4866 322.6259 322.7652 322.9045 323.0438 323.1831 323.3223 323.4616 323.6008 323.7401 323.8793 324.0185 324.1577 324.2968 324.4360 324.5752 324.7143 324.8534 324.9926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250430T210251.4Z 9251.876984 61 1 54.15 2 78.68 79.45 102.48 42.46 0.00 1 0.00 1 0 17 5.520e-01 1.483e-02 2.783e-01 6.896e-03 7.566230e-01 3.784291e-03 8.176150e-03 -6.000000e+00 3.176353e-01 230.26 -2.00 3.39 -2.00 321.79 0.00e+00 6.078313e-03 2.155117e-03 1.304737e-03 -6.000000e+00 1.404071e-02 285.11 -2.00 20.00 -2.00 321.24 0.00e+00 4.922 0.002 302.00 328.00 3 3.0133e+00 1.4408e-02 6.2905e-02 -6.0000e+00 7.9378e-01 2.9920e-01 2.0488e-02 4.0627e-02 -6.0000e+00 8.6305e-01 -4.6766e-01 2.0171e-02 2.1425e-02 -6.0000e+00 5.1135e-01 1.8514e-01 9.2078e-03 9.2053e-03 -6.0000e+00 2.1376e-01 8.7855e-05 -9.9070e-04 1.8838e-04 1.1967e-04 -6.0000e+00 1.5156e-02 5.9277e-03 0.0000e+00 12 9 8 11 8 0 43.79 25.84 0.53 0.00593 -0.00152 49 5 1 5 0 1105.070 34.50 19.99 25.84 20.48 0.5 924.26 -153357 -193032 -99424 -253395 -208180 -204650 900000 -132402 -80652 -96637 -193311 -163418 -124381 -58806 7217 -69952 -110395 -68649 -46846 -11505 -37505 -34398 -64983 3534 44433 -84416 -37236 -104270 -39415 -33510 63055 -17996 11057 -4159 -39267 49321 18579 30277 23073 41419 22001 39807 26573 -2178 13080 9328 22581 9743 17935 2902 20398 16349 24646 13640 14870 20522 3732 20794 10470 -7935 3641 14137 14192 12803 14000 10624 7705 7309 7011 164 5425 1084 2943 1496 443 3094 1907 -4142 -1288 855 -758 -1126 -4333 -1923 1061 557 -658 1346 940 1973 162 386 -3849 -1791 -2501 413 -1032 -1317 -1552 -1380 -192 -470 -1396 -835 -2305 -1741 -1125 -204 -564 -66 179 -55 -346 -738 365 -13 113 385 315 171 960 261 790 758 1201 214 759 1166 387 253 734 -35 327 308 -880 323 272 30 -215 -105 -221 -154 -1033 -1406 -2950 -669 -6661 -3181 -3002 900000 -1133 -542 -650 -3663 -2797 -1901 -611 49 -1197 -3172 -1427 -830 -148 -619 -547 -1470 43 380 -2683 -728 -3888 -795 -737 655 -506 264 -117 -1488 784 454 796 790 1367 968 1557 1235 -137 720 547 1201 619 1118 254 1687 1572 2386 1587 1790 2415 525 2405 1295 -1174 509 2015 2329 2376 2645 2036 1534 1558 1711 49 1649 350 896 426 114 703 426 -1053 -374 292 -308 -520 -2238 -1028 587 328 -410 833 574 1133 88 199 -2052 -1014 -1653 312 -922 -1343 -1690 -1467 -184 -402 -1129 -695 -2092 -1657 -1132 -221 -688 -90 272 -89 -552 -1136 529 -19 165 591 512 283 1527 398 1157 1074 1634 283 987 1648 637 472 1491 -77 751 759 -2130 803 687 76 -541 -276 -539 -352 -2352 SS 20250430T210940.6Z 9251.881720 64 1 54.87 2 77.31 80.38 101.57 43.59 0.00 1 0.00 1 0 25 4.592e-01 8.232e-03 2.733e-01 4.273e-03 6.996914e-01 2.303725e-03 7.610654e-03 -6.000000e+00 2.623620e-01 230.26 -2.00 3.39 -2.00 321.46 0.00e+00 4.951396e-03 1.224648e-03 2.476999e-03 -6.000000e+00 1.222890e-02 285.11 -2.00 20.00 -2.00 320.90 0.00e+00 4.428 0.001 302.00 328.00 3 2.9544e+00 8.3311e-03 5.7450e-02 -6.0000e+00 6.5502e-01 8.2711e-02 1.2027e-02 3.7958e-02 -6.0000e+00 7.1186e-01 -1.3812e-01 1.2492e-02 2.1729e-02 -6.0000e+00 4.2357e-01 4.1956e-02 5.7930e-03 8.3407e-03 -6.0000e+00 1.7834e-01 1.6073e-04 -4.5106e-04 1.1699e-04 1.1352e-04 -6.0000e+00 1.2446e-02 5.5793e-03 0.0000e+00 11 9 0 11 8 0 56.67 25.84 0.51 0.00558 0.00219 69 7 1 5 0 795.110 34.50 19.99 25.84 21.32 0.5 930.33 -236620 -93387 -64205 -95097 -170663 -173580 -151406 -111130 -100953 -218892 900000 -92336 -121019 -79227 13290 -2155 79595 -70638 -19145 -27061 -54699 11586 -14773 -5876 -10555 -834 8325 -21181 -37053 -53218 -17672 -3956 -4407 -930 -34386 -32142 -8336 -10900 4839 -10550 6283 9643 2901 7712 -8741 9749 15774 3090 -4356 283 2096 -2098 -286 8027 5246 1154 -2313 -2063 5440 239 299 2227 3139 1983 2735 1403 1114 -1370 6095 2695 5270 528 2299 483 -599 -340 -1137 -675 -2370 1232 -1083 -930 -1766 -613 -305 197 673 1102 653 728 551 219 -864 142 369 -24 510 -610 -35 -283 -597 -829 -2032 -1746 -1647 -1811 -769 -719 207 501 766 514 49 -473 -222 -204 -14 177 -160 517 111 928 759 86 -274 476 769 436 197 -53 -74 -490 -185 350 -71 -290 25 555 28 -35 -149 -1 -681 -2958 -389 -268 -396 -1164 -1249 -975 -547 -497 -3731 900000 -595 -1375 -780 65 -15 332 -1204 -210 -338 -912 101 -179 -71 -144 -11 98 -329 -702 -1371 -395 -93 -119 -25 -1224 -1272 -299 -491 228 -677 377 599 202 524 -717 687 1085 254 -410 28 230 -268 -39 1100 778 186 -391 -342 814 38 50 417 668 474 666 338 271 -364 1717 896 1840 197 814 162 -182 -94 -305 -192 -802 480 -504 -488 -1008 -367 -195 133 471 780 456 483 341 128 -504 88 263 -20 492 -674 -41 -321 -622 -772 -1804 -1608 -1628 -1887 -842 -850 270 736 1229 780 82 -755 -335 -300 -22 281 -270 880 184 1464 1158 127 -393 649 1034 638 330 -101 -139 -974 -388 780 -171 -722 63 1408 70 -83 -333 -3 -1428 SS 20250430T211511.7Z 9251.885552 67 1 54.32 2 76.20 81.13 100.82 44.49 0.00 1 0.00 1 0 17 4.026e-01 7.474e-03 1.614e-01 3.012e-03 6.485307e-01 1.610249e-03 7.068466e-03 -6.000000e+00 2.299724e-01 230.26 -2.00 3.39 -2.00 321.26 0.00e+00 4.936534e-03 7.946582e-04 2.147336e-03 -6.000000e+00 1.023593e-02 285.11 -2.00 20.00 -2.00 320.64 0.00e+00 4.094 0.001 302.00 328.00 3 2.8410e+00 5.5618e-03 5.2816e-02 -6.0000e+00 5.7418e-01 5.1177e-02 7.6112e-03 3.4286e-02 -6.0000e+00 6.2390e-01 -9.5037e-02 7.5713e-03 1.9602e-02 -6.0000e+00 3.7127e-01 2.4659e-02 3.6005e-03 7.7469e-03 -6.0000e+00 1.5588e-01 2.6029e-04 -4.6138e-04 8.4256e-05 9.5025e-05 -6.0000e+00 1.0863e-02 5.7257e-03 0.0000e+00 11 8 0 10 0 0 7.99 25.84 0.52 0.00573 0.00226 90 9 1 5 0 603.500 34.50 19.99 25.84 21.86 0.4 935.18 -156306 -146544 -126357 -177493 -127405 -102853 -163766 -68094 36334 -72426 -152686 -54051 -113659 -8751 -61400 -53835 -29702 -38330 -30972 -44448 -44545 -39338 -23263 -24552 -33653 -37417 -12653 -26006 -21577 -28105 -13875 -11787 -3179 -16501 858 -24469 -10753 -2490 1210 -2314 2948 -4026 4504 942 2388 1552 -3540 3603 5433 4843 6161 4348 3337 967 3644 -785 2098 769 2203 -1400 1863 3776 3744 3301 2448 2898 1643 328 1908 2570 3109 1340 1713 194 -188 -1076 -2722 -2099 -1376 -1234 -797 -1382 -1736 -1321 -759 -208 -261 1449 1067 1624 304 -73 -492 544 -995 -96 189 346 -49 -319 -1137 -1232 -298 -753 -1598 -1359 -855 178 238 347 122 334 25 -208 -277 -76 -37 229 195 391 625 266 678 477 203 -224 284 524 184 337 -42 -692 -351 -179 -19 52 563 340 24 62 -303 -296 -532 -1335 -1291 -945 -2085 -850 -549 -1793 -327 107 -425 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