File name: Pandora277s1_Nagoya_20250503_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20250904T081836.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 277 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora277_OF_v2d20230817.txt Instrument calibration file used: Pandora277s1_CF_v4d20250225.txt Level 1 file used: Pandora277s1_Nagoya_20250503_L1_smca1c4d20250225p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20250503 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo HCHO First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1229 305.2636 305.4043 305.5450 305.6857 305.8264 305.9670 306.1077 306.2483 306.3890 306.5296 306.6702 306.8108 306.9514 307.0920 307.2325 307.3731 307.5136 307.6542 307.7947 307.9352 308.0757 308.2162 308.3567 308.4971 308.6376 308.7780 308.9185 309.0589 309.1993 309.3397 309.4801 309.6205 309.7608 309.9012 310.0415 310.1818 310.3222 310.4625 310.6028 310.7431 310.8833 311.0236 311.1639 311.3041 311.4443 311.5845 311.7247 311.8649 312.0051 312.1453 312.2855 312.4256 312.5658 312.7059 312.8460 312.9861 313.1262 313.2663 313.4064 313.5464 313.6865 313.8265 313.9665 314.1065 314.2465 314.3865 314.5265 314.6665 314.8065 314.9464 315.0863 315.2263 315.3662 315.5061 315.6460 315.7858 315.9257 316.0656 316.2054 316.3452 316.4851 316.6249 316.7647 316.9045 317.0442 317.1840 317.3238 317.4635 317.6032 317.7430 317.8827 318.0224 318.1620 318.3017 318.4414 318.5810 318.7207 318.8603 318.9999 319.1395 319.2791 319.4187 319.5583 319.6978 319.8374 319.9769 320.1164 320.2559 320.3955 320.5349 320.6744 320.8139 320.9533 321.0928 321.2322 321.3716 321.5111 321.6505 321.7898 321.9292 322.0686 322.2079 322.3473 322.4866 322.6259 322.7652 322.9045 323.0438 323.1831 323.3223 323.4616 323.6008 323.7401 323.8793 324.0185 324.1577 324.2968 324.4360 324.5752 324.7143 324.8534 324.9926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250502T204317.4Z 9253.863396 57 1 53.37 2 82.22 76.31 117.90 14.59 0.00 1 0.00 1 0 17 7.416e-01 4.489e-02 4.803e-01 3.269e-02 8.617973e-01 1.932646e-02 9.135916e-03 -6.000000e+00 4.409976e-01 230.39 -2.00 3.39 -2.00 322.26 0.00e+00 -8.416014e-03 1.088965e-02 4.545878e-03 -6.000000e+00 2.515632e-02 285.30 -2.00 20.00 -2.00 321.76 0.00e+00 6.877 0.005 302.00 328.00 3 3.0071e+00 7.8616e-02 8.4084e-02 -6.0000e+00 1.1083e+00 1.1060e+00 9.6984e-02 5.0770e-02 -6.0000e+00 1.2153e+00 -1.5764e+00 6.5826e-02 2.3102e-02 -6.0000e+00 7.0781e-01 6.3483e-01 3.2273e-02 6.1447e-03 -6.0000e+00 2.9658e-01 1.1991e-05 -1.3074e-03 9.3258e-04 1.3528e-04 -6.0000e+00 2.1417e-02 4.3695e-03 0.0000e+00 12 9 8 11 8 0 2.08 25.74 0.76 0.00437 -0.00545 15 2 1 5 0 3557.790 34.50 20.00 25.74 16.68 0.7 891.92 -70410 -103989 -15073 900000 900000 900000 900000 -73214 7228 900000 900000 900000 900000 900000 -56449 272607 55793 900000 900000 14992 900000 900000 -12509 163372 29468 -63722 900000 35583 8704 115841 900000 900000 900000 287094 -51781 -18614 -13998 124023 57711 265764 8639 135499 341416 59274 -11474 134499 133462 900000 126123 111408 242237 57195 -4396 76495 62947 66424 101182 -7238 39062 37118 79242 19386 21214 1019 38334 86139 7549 31402 70883 37915 52596 36417 24729 4442 20741 -26352 255 -16269 7047 -19005 -2021 -10178 23816 -10394 14734 10907 -16946 1627 716 13557 10235 -4948 -11035 -14701 -7237 1375 15889 -4681 6590 -2513 -10358 914 -1804 -2349 3701 -2286 -672 2063 -5081 -5916 3397 -167 -4854 -1894 -2357 915 3218 1655 -3420 1218 -597 4603 7023 1988 790 4121 3597 -1883 -3347 2637 2400 1668 85 1734 -1748 -1121 -180 1858 1697 -1822 -325 -1960 -1517 -4287 -8809 -479 900000 900000 900000 900000 -3295 230 900000 900000 900000 900000 900000 -3736 8660 1772 900000 900000 516 900000 900000 -530 5190 1021 -5060 900000 1130 276 3680 900000 900000 900000 9120 -4037 -1021 -808 3940 2333 8442 699 4304 10845 2739 -1027 4272 4240 900000 4006 3539 7695 3469 -533 4418 4363 4604 4967 -1003 3158 2894 4119 2015 2450 159 4207 5721 1112 3899 6755 5693 7291 5994 4356 872 3055 -5555 40 -3195 1282 -5378 -566 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4.4675e-03 0.0000e+00 12 8 8 10 0 0 39.57 25.73 0.44 0.00447 0.00263 72 7 1 5 0 753.080 34.50 20.00 25.73 18.41 0.7 907.17 -183808 -201445 -157617 125112 900000 -142179 -149713 -210590 -228732 -157128 -21644 13295 -98751 -11346 -91071 -72016 -51318 900000 -27536 -26054 -25014 10901 -61907 -29400 -80284 -29848 -54558 -49614 -38712 -16464 -2557 -22847 -5660 2421 6794 -18574 -5816 14683 -12435 1680 1222 3513 15535 3583 -685 5065 3990 13001 13050 -1115 15835 8848 9268 6177 7912 5646 -972 2696 865 -116 4271 2287 9148 2673 3017 -220 1537 2908 3439 1920 1387 -1242 -361 1520 404 -2505 -360 -2420 -1685 -2174 17 -1258 -1619 -1325 -1321 1314 450 2642 1578 1980 402 -43 -850 -89 -353 -181 187 -757 -870 -693 -1057 -937 -376 -1084 -793 -1817 -875 -703 434 246 1035 320 168 -463 -169 1 299 -249 -281 -394 599 170 865 434 -18 676 191 -140 190 220 244 -33 58 -203 -434 156 606 355 -6 75 -505 -276 -538 -1514 -2240 -1168 567 900000 -820 -1048 -3122 -4522 -1618 -98 60 -976 -61 -1350 -1038 -676 900000 -340 -333 -319 99 -1249 -472 -2315 -541 -1258 -1063 -765 -298 -49 -649 -154 62 159 -581 -184 512 -699 96 77 232 950 252 -51 367 302 942 1005 -109 1471 986 1129 840 1115 849 -159 418 133 -18 671 415 1774 613 705 -52 358 713 960 621 486 -456 -127 488 118 -682 -93 -678 -547 -846 7 -639 -891 -772 -824 848 306 1786 1060 1258 242 -25 -482 -54 -247 -148 175 -812 -991 -768 -1075 -851 -321 -970 -761 -1855 -940 -814 555 356 1624 526 274 -727 -251 1 441 -391 -466 -667 981 267 1305 636 -26 913 257 -205 317 412 498 -64 121 -452 -1035 384 1516 900 -14 179 -1128 -581 -1238 SS 20250502T210730.8Z 9253.880218 65 1 54.50 2 77.37 79.61 116.53 20.21 0.00 1 0.00 1 0 17 3.770e-01 6.781e-03 1.402e-01 2.724e-03 6.290415e-01 1.456130e-03 6.781200e-03 -6.000000e+00 2.154855e-01 230.40 -2.00 3.39 -2.00 321.17 0.00e+00 2.692967e-03 7.005507e-04 1.132070e-03 -6.000000e+00 9.593304e-03 285.30 -2.00 20.00 -2.00 320.53 0.00e+00 4.448 0.001 302.00 328.00 3 2.4101e+00 4.9620e-03 5.4675e-02 -6.0000e+00 5.3816e-01 3.9247e-02 6.7621e-03 3.2833e-02 -6.0000e+00 5.8465e-01 -9.3541e-02 6.6669e-03 1.7474e-02 -6.0000e+00 3.4792e-01 2.9066e-02 3.1743e-03 6.2430e-03 -6.0000e+00 1.4608e-01 3.0097e-04 -2.3289e-04 7.6408e-05 7.0881e-05 -6.0000e+00 1.0173e-02 4.7960e-03 0.0000e+00 11 8 0 10 0 0 19.35 25.73 0.39 0.00480 0.00305 106 11 1 5 0 514.080 34.50 20.00 25.73 19.31 0.6 914.37 -144505 -110820 -104117 3150 -164065 -193088 -111752 -143155 -147574 -59094 -98777 -55097 -55367 -44422 -29588 11217 -7159 -29055 -23333 -32726 -21101 -9451 -27374 -13165 -20302 -27188 -26830 -15239 -263 -5368 -26575 -16290 -69 -10709 3111 -14232 -5867 -8693 -6079 -4061 -3163 2306 3592 -5255 3857 -1367 5910 -314 -20 7596 5607 4264 6923 2576 2350 2519 1280 -363 -909 387 2342 5906 3528 2806 1613 -375 -260 1156 1546 2610 1162 780 1955 -438 237 -789 -99 -2680 -1785 -757 -1095 -1902 -1492 -1046 -625 436 472 518 690 904 614 157 196 -1083 -318 -264 457 67 89 -427 -984 -775 -318 -558 -850 -807 -809 24 515 329 54 237 258 -136 -213 -534 -186 -126 440 -147 339 611 519 178 124 32 602 72 -164 250 -298 -207 -85 226 -77 138 453 274 -97 -74 -203 -97 -543 -1256 -776 -704 8 -1783 -2891 -837 -1694 -2032 -357 -954 -413 -535 -494 -350 103 -88 -491 -400 -648 -377 -153 -569 -261 -466 -696 -748 -368 -6 -135 -1003 -658 -3 -469 114 -643 -281 -524 -438 -334 -285 209 336 -547 374 -143 590 -35 -2 890 752 646 1116 467 450 501 263 -75 -183 77 486 1331 926 816 482 -111 -76 354 538 1025 499 344 826 -177 86 -261 -31 -913 -697 -347 -583 -1148 -966 -716 -457 335 380 423 554 687 435 105 128 -764 -254 -244 484 73 103 -479 -1118 -789 -306 -563 -926 -924 -983 28 668 477 86 387 413 -209 -308 -755 -268 -192 708 -244 547 945 776 258 173 43 866 102 -264 448 -580 -423 -184 516 -174 322 1073 657 -230 -182 -473 -212 -1191 SS 20250502T211311.1Z 9253.884156 68 1 54.59 2 76.23 80.38 116.15 21.50 0.00 1 0.00 1 0 25 2.769e-01 5.776e-03 7.166e-02 1.906e-03 5.855617e-01 1.005793e-03 6.363627e-03 -6.000000e+00 1.582982e-01 230.40 -2.00 3.39 -2.00 320.90 0.00e+00 2.563549e-03 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