File name: Pandora277s1_Nagoya_20250703_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20250904T083951.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 277 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora277_OF_v2d20230817.txt Instrument calibration file used: Pandora277s1_CF_v4d20250225.txt Level 1 file used: Pandora277s1_Nagoya_20250703_L1_smca1c4d20250225p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20250703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo HCHO First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1229 305.2636 305.4043 305.5450 305.6857 305.8264 305.9670 306.1077 306.2483 306.3890 306.5296 306.6702 306.8108 306.9514 307.0920 307.2325 307.3731 307.5136 307.6542 307.7947 307.9352 308.0757 308.2162 308.3567 308.4971 308.6376 308.7780 308.9185 309.0589 309.1993 309.3397 309.4801 309.6205 309.7608 309.9012 310.0415 310.1818 310.3222 310.4625 310.6028 310.7431 310.8833 311.0236 311.1639 311.3041 311.4443 311.5845 311.7247 311.8649 312.0051 312.1453 312.2855 312.4256 312.5658 312.7059 312.8460 312.9861 313.1262 313.2663 313.4064 313.5464 313.6865 313.8265 313.9665 314.1065 314.2465 314.3865 314.5265 314.6665 314.8065 314.9464 315.0863 315.2263 315.3662 315.5061 315.6460 315.7858 315.9257 316.0656 316.2054 316.3452 316.4851 316.6249 316.7647 316.9045 317.0442 317.1840 317.3238 317.4635 317.6032 317.7430 317.8827 318.0224 318.1620 318.3017 318.4414 318.5810 318.7207 318.8603 318.9999 319.1395 319.2791 319.4187 319.5583 319.6978 319.8374 319.9769 320.1164 320.2559 320.3955 320.5349 320.6744 320.8139 320.9533 321.0928 321.2322 321.3716 321.5111 321.6505 321.7898 321.9292 322.0686 322.2079 322.3473 322.4866 322.6259 322.7652 322.9045 323.0438 323.1831 323.3223 323.4616 323.6008 323.7401 323.8793 324.0185 324.1577 324.2968 324.4360 324.5752 324.7143 324.8534 324.9926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250702T213025.9Z 9314.896133 87 1 54.95 2 70.36 75.21 150.27 20.77 0.00 1 0.00 1 0 17 4.761e-02 5.929e-03 3.275e-02 2.892e-03 3.759719e-01 1.482380e-03 4.165269e-03 -6.000000e+00 2.742077e-02 232.47 -2.00 3.39 -2.00 319.47 0.00e+00 9.995688e-04 4.020769e-04 4.224551e-04 -6.000000e+00 1.240586e-03 290.87 -2.00 20.00 -2.00 318.58 0.00e+00 2.942 0.000 302.00 328.00 3 4.1961e+00 4.2626e-03 3.4830e-02 -6.0000e+00 6.8700e-02 2.4617e-02 5.0174e-03 1.9149e-02 -6.0000e+00 7.4453e-02 5.3790e-03 3.6484e-03 9.3112e-03 -6.0000e+00 4.4377e-02 -1.1850e-02 1.8919e-03 2.6274e-03 -6.0000e+00 1.8645e-02 2.7571e-04 -1.3990e-04 8.4929e-05 2.6506e-05 -6.0000e+00 1.2859e-03 7.3167e-03 0.0000e+00 10 0 0 10 0 0 52.73 26.06 0.46 0.00732 0.00627 31 3 1 5 0 1772.420 34.75 20.00 26.06 33.70 0.0 1023.41 -17136 -1293 -24184 -2284 -23795 -8754 -15925 -7713 -5223 -5384 -18087 -18963 -12047 932 3557 1925 -3580 -5504 -2401 -3402 -1208 -5486 1131 330 -2451 3502 -3310 -1979 -4150 -4362 19 154 -4682 -1441 -5778 -1209 3245 -4812 -670 564 -1633 991 2135 134 294 -1254 -219 633 -540 1392 303 1513 410 3124 2323 257 500 -573 -667 -464 1027 1618 2249 1530 1209 -451 -576 239 1230 687 1337 1138 187 847 -447 -1768 -1052 -1426 -2046 -930 -648 -1962 -1343 -969 -296 -92 -271 180 954 1049 -394 24 -977 415 -473 427 547 328 -267 -390 -539 -643 -87 -771 -818 -386 -557 182 202 677 112 390 -41 9 212 25 59 44 -203 -300 120 110 286 515 4 324 736 526 246 241 -227 -926 153 230 -337 124 292 364 84 115 -387 -318 -541 -461 -32 -756 -53 -628 -202 -441 -225 -163 -174 -677 -877 -618 50 217 131 -275 -458 -204 -304 -107 -509 103 33 -266 368 -364 -203 -424 -469 2 20 -691 -204 -810 -167 489 -950 -153 145 -465 288 630 41 90 -390 -67 191 -166 441 105 564 165 1291 1000 117 229 -262 -299 -209 481 828 1257 911 706 -249 -305 129 737 468 970 847 138 585 -285 -1026 -563 -772 -1237 -639 -502 -1694 -1224 -931 -303 -100 -282 190 984 1127 -395 22 -854 366 -464 467 610 405 -344 -486 -681 -744 -97 -920 -1053 -472 -717 245 292 1054 186 644 -66 13 291 33 79 63 -312 -482 192 171 429 738 6 465 1018 764 391 378 -377 -1592 270 426 -669 255 614 777 179 235 -762 -599 -1018 SS 20250702T213558.6Z 9314.899983 90 1 53.90 2 69.26 75.91 149.88 23.30 0.00 1 0.00 1 0 17 5.402e-02 7.275e-03 4.232e-02 4.113e-03 3.574586e-01 2.139105e-03 4.120470e-03 -6.000000e+00 3.168653e-02 232.47 -2.00 3.39 -2.00 319.33 0.00e+00 7.148011e-04 5.532113e-04 5.820118e-04 -6.000000e+00 1.416328e-03 290.87 -2.00 20.00 -2.00 318.48 0.00e+00 2.796 0.000 302.00 328.00 3 4.7386e+00 6.0673e-03 3.3329e-02 -6.0000e+00 7.9432e-02 3.3956e-02 7.0949e-03 1.8701e-02 -6.0000e+00 8.5537e-02 -9.8044e-03 5.1517e-03 9.0866e-03 -6.0000e+00 5.0965e-02 -2.5185e-03 2.7095e-03 2.4991e-03 -6.0000e+00 2.2038e-02 1.8682e-04 -3.7461e-04 1.2134e-04 2.6954e-05 -6.0000e+00 1.4620e-03 7.6015e-03 0.0000e+00 11 9 0 11 8 0 99.98 26.06 0.18 0.00760 0.00479 23 2 1 5 0 2343.120 34.75 20.00 26.06 34.08 0.0 1026.67 -13857 -5316 -20438 -24293 23988 8408 -15577 -13440 -15377 -21761 12165 -8948 11607 -5839 -1739 -3760 -45 -1596 -2351 -41 4050 -830 -2991 5769 -4930 1604 -4582 -7939 -7917 1075 -7692 870 -5500 -3241 -215 -6677 -134 -2298 -3271 1112 -800 -609 3006 2742 -780 -1353 1124 746 -88 435 2224 848 35 1780 1665 980 496 -493 1187 996 2492 1519 2611 2117 1085 226 -57 671 -256 0 1457 932 -58 951 471 -1201 -1194 377 -2834 -1524 -2093 -3036 -2245 -984 215 269 384 245 79 690 -244 295 -569 304 -1844 723 1036 74 83 111 -584 -1079 -540 -737 -474 -1137 -572 -484 336 857 390 354 -89 -18 -96 -492 790 -351 630 163 -50 433 66 289 510 -157 905 801 -199 48 -428 -201 93 4 235 -16 544 -158 45 -247 -468 -343 900000 -450 -171 -760 -859 481 199 -522 -505 -645 -1000 404 -405 504 -358 -118 -285 -3 -133 -207 -4 350 -76 -292 555 -561 175 -571 -965 -930 120 -1046 121 -885 -504 -31 -1044 -22 -473 -817 304 -240 -191 932 858 -254 -443 355 235 -28 144 783 328 15 764 739 451 232 -230 533 451 1172 791 1473 1268 641 125 -30 360 -155 0 1052 692 -43 655 297 -692 -638 199 -1702 -1037 -1615 -2598 -2022 -925 214 286 428 278 89 729 -239 264 -483 261 -1775 762 1220 98 113 146 -712 -1209 -586 -849 -587 -1489 -782 -695 513 1404 615 560 -149 -29 -139 -684 1106 -527 1002 272 -84 704 105 436 732 -216 1190 1099 -301 79 -737 -354 170 8 478 -31 1068 -317 90 -524 -954 -668 900000 SS 20250702T214134.2Z 9314.903868 93 1 54.46 2 68.15 76.61 149.44 25.80 0.00 1 0.00 1 0 25 2.610e-02 5.221e-03 1.325e-02 1.808e-03 3.428781e-01 9.373614e-04 3.945280e-03 -6.000000e+00 1.531268e-02 232.47 -2.00 3.39 -2.00 318.89 0.00e+00 1.116735e-03 2.104152e-04 3.771576e-04 -6.000000e+00 6.844462e-04 290.87 -2.00 20.00 -2.00 318.02 0.00e+00 2.663 0.000 302.00 328.00 3 3.8695e+00 2.5992e-03 3.1753e-02 -6.0000e+00 3.8386e-02 2.7095e-02 2.9900e-03 1.7705e-02 -6.0000e+00 4.1336e-02 -1.0272e-02 2.0643e-03 8.6367e-03 -6.0000e+00 2.4629e-02 -1.1840e-03 1.0866e-03 2.4830e-03 -6.0000e+00 1.0650e-02 5.1721e-04 -2.0714e-04 5.2769e-05 2.6862e-05 -6.0000e+00 7.0650e-04 7.5377e-03 0.0000e+00 10 0 0 10 0 0 70.04 26.06 0.24 0.00754 0.00598 50 5 1 5 0 1089.070 34.75 20.00 26.06 34.42 0.0 1029.55 -8079 -11388 -7868 -12658 -9414 -7189 2320 -3888 -3062 -4085 -11631 -5337 -5958 -1381 -2734 -1370 1557 -529 207 -1022 1084 48 108 502 364 -2852 -2103 -2772 -1742 196 96 -510 720 -1343 -2645 -2720 -3406 594 -1177 -70 -440 -152 -731 151 757 35 -535 -130 309 812 -11 1283 1583 648 744 927 715 1027 873 1070 775 1478 1382 743 405 430 -327 400 5 763 927 686 55 -80 33 -1174 -750 -1714 -1496 -1078 -1440 -1263 -1839 -1589 -700 -84 208 544 695 599 315 133 156 -230 -221 247 437 175 191 -224 -878 -842 -302 -635 -730 -993 -565 -56 597 481 643 387 60 -179 141 -138 52 422 168 -163 51 222 257 481 -104 31 350 209 243 248 -141 -428 96 47 -31 118 267 -92 11 -24 -463 -346 900000 -349 -546 -362 -558 -368 -277 90 -184 -157 -216 -670 -318 -420 -110 -254 -137 160 -59 24 -124 129 6 14 68 52 -431 -307 -384 -231 27 14 -86 129 -243 -458 -484 -694 140 -339 -23 -154 -55 -275 57 284 13 -201 -48 114 311 -5 570 747 324 383 490 383 541 452 557 427 885 906 516 275 270 -197 244 3 532 693 526 42 -63 24 -766 -451 -1041 -1002 -823 -1130 -1085 -1684 -1534 -719 -92 237 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