File name: Pandora277s1_Nagoya_20250704_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20250904T083943.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 277 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora277_OF_v2d20230817.txt Instrument calibration file used: Pandora277s1_CF_v4d20250225.txt Level 1 file used: Pandora277s1_Nagoya_20250704_L1_smca1c4d20250225p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20250704 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo HCHO First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1229 305.2636 305.4043 305.5450 305.6857 305.8264 305.9670 306.1077 306.2483 306.3890 306.5296 306.6702 306.8108 306.9514 307.0920 307.2325 307.3731 307.5136 307.6542 307.7947 307.9352 308.0757 308.2162 308.3567 308.4971 308.6376 308.7780 308.9185 309.0589 309.1993 309.3397 309.4801 309.6205 309.7608 309.9012 310.0415 310.1818 310.3222 310.4625 310.6028 310.7431 310.8833 311.0236 311.1639 311.3041 311.4443 311.5845 311.7247 311.8649 312.0051 312.1453 312.2855 312.4256 312.5658 312.7059 312.8460 312.9861 313.1262 313.2663 313.4064 313.5464 313.6865 313.8265 313.9665 314.1065 314.2465 314.3865 314.5265 314.6665 314.8065 314.9464 315.0863 315.2263 315.3662 315.5061 315.6460 315.7858 315.9257 316.0656 316.2054 316.3452 316.4851 316.6249 316.7647 316.9045 317.0442 317.1840 317.3238 317.4635 317.6032 317.7430 317.8827 318.0224 318.1620 318.3017 318.4414 318.5810 318.7207 318.8603 318.9999 319.1395 319.2791 319.4187 319.5583 319.6978 319.8374 319.9769 320.1164 320.2559 320.3955 320.5349 320.6744 320.8139 320.9533 321.0928 321.2322 321.3716 321.5111 321.6505 321.7898 321.9292 322.0686 322.2079 322.3473 322.4866 322.6259 322.7652 322.9045 323.0438 323.1831 323.3223 323.4616 323.6008 323.7401 323.8793 324.0185 324.1577 324.2968 324.4360 324.5752 324.7143 324.8534 324.9926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250703T214603.5Z 9315.906985 96 1 54.63 2 67.34 77.22 156.83 10.71 0.00 1 0.00 1 0 17 2.141e-02 5.082e-03 9.086e-03 1.400e-03 3.310582e-01 7.257500e-04 3.800735e-03 -6.000000e+00 1.256025e-02 232.45 -2.00 3.39 -2.00 318.65 0.00e+00 1.177357e-03 1.532378e-04 2.011398e-04 -6.000000e+00 5.616717e-04 290.95 -2.00 20.00 -2.00 317.78 0.00e+00 2.574 0.000 302.00 328.00 3 3.5774e+00 2.0007e-03 3.0653e-02 -6.0000e+00 3.1484e-02 1.9649e-02 2.2893e-03 1.7031e-02 -6.0000e+00 3.3905e-02 -6.9546e-03 1.5321e-03 8.3211e-03 -6.0000e+00 2.0203e-02 -2.6775e-03 8.0413e-04 2.4856e-03 -6.0000e+00 8.7358e-03 7.6956e-04 -2.5807e-04 4.0772e-05 2.5413e-05 -6.0000e+00 5.7960e-04 8.2375e-03 0.0000e+00 11 1 0 11 8 0 99.94 26.02 0.37 0.00824 0.00630 73 7 1 5 0 748.240 34.75 20.00 26.02 36.08 0.0 1041.80 -2771 -6202 -2985 -6637 -8876 -11719 -1712 -6440 -4961 -3226 -5526 -6274 -6353 -613 -3816 -717 -3533 -1493 -58 1549 1740 2058 -849 -1603 -707 -797 -358 8 654 1313 2004 640 -567 -805 -1445 -2408 -2990 1 -795 -834 -747 245 -388 -226 559 -226 817 -427 -315 427 663 1123 1390 734 678 1038 127 553 195 771 1325 1713 1848 935 147 -74 -464 -318 640 717 513 220 83 264 25 -763 -1624 -1144 -1504 -948 -1101 -1867 -1634 -1233 -772 -26 286 501 413 812 415 198 175 287 124 500 619 227 87 -334 -680 -690 -268 -617 -680 -789 -704 -262 349 535 347 347 78 -163 50 69 -22 89 160 -73 131 124 183 350 160 214 415 211 -24 234 -170 -362 103 101 70 116 274 95 -30 -158 -436 -366 900000 -131 -326 -151 -317 -397 -544 -80 -358 -296 -193 -342 -429 -510 -55 -404 -80 -428 -187 -7 205 231 273 -121 -246 -114 -131 -57 1 94 194 326 117 -113 -159 -271 -468 -665 0 -249 -298 -287 97 -159 -93 229 -93 329 -172 -127 177 297 539 708 395 376 589 73 314 109 433 780 999 1177 631 97 -46 -298 -208 421 532 409 180 67 201 17 -528 -1048 -733 -1067 -695 -910 -1704 -1575 -1251 -838 -30 344 611 499 924 436 191 158 263 124 560 776 288 114 -426 -876 -815 -307 -754 -897 -1004 -938 -366 518 850 580 580 125 -242 68 99 -29 127 245 -116 210 195 278 507 221 306 573 304 -35 363 -277 -606 177 182 134 215 518 182 -57 -293 -840 -677 900000 SS 20250703T222730.9Z 9315.935774 125 1 54.40 2 59.00 82.44 153.91 33.10 0.00 1 0.00 1 0 17 1.243e-02 5.321e-03 5.792e-03 1.600e-03 2.508875e-01 8.126164e-04 2.832977e-03 -6.000000e+00 7.158002e-03 232.45 -2.00 3.39 -2.00 317.82 0.00e+00 4.985543e-04 1.338176e-04 1.541552e-04 -6.000000e+00 3.239489e-04 290.95 -2.00 20.00 -2.00 316.88 0.00e+00 1.934 0.000 302.00 328.00 3 4.3167e+00 2.1948e-03 2.2984e-02 -6.0000e+00 1.7933e-02 1.7781e-02 2.4863e-03 1.2673e-02 -6.0000e+00 1.9433e-02 2.6790e-04 1.5022e-03 6.0914e-03 -6.0000e+00 1.1583e-02 -5.3668e-03 7.3932e-04 1.6641e-03 -6.0000e+00 4.8686e-03 7.7703e-04 5.8912e-05 4.6777e-05 1.7736e-05 -6.0000e+00 3.3562e-04 5.8820e-03 0.0000e+00 10 0 0 10 0 0 99.99 26.05 0.41 0.00588 0.00632 174 18 1 5 0 312.590 34.75 20.00 26.05 36.49 0.0 1042.97 -1317 -2571 -4444 -6263 -7061 443 -2495 624 876 -2111 -2720 -2741 -71 -405 1069 -90 -177 83 1531 1218 1013 527 979 441 396 -325 -428 -1268 311 -720 149 353 -874 -713 -2332 -2098 -964 -77 -918 -798 -207 -665 -879 -346 171 -170 -686 -348 -368 911 802 1237 526 538 777 870 556 358 -96 737 1579 1576 1717 778 137 -386 -273 -21 760 714 600 579 532 54 -69 -281 -1204 -1284 -1171 -1032 -1157 -2142 -1589 -1115 -934 -59 216 412 502 552 247 140 185 87 -158 202 524 277 -123 -304 -623 -1001 -231 -643 -639 -565 -479 -115 350 567 482 328 13 -34 -155 -117 52 187 -4 71 66 295 103 474 195 59 400 316 199 117 -159 -210 108 245 -18 157 270 168 97 -22 -349 -463 -646 -129 -270 -466 -604 -624 36 -232 64 97 -243 -312 -336 -10 -64 186 -17 -34 17 316 261 218 114 218 105 99 -83 -106 -295 68 -160 35 91 -243 -193 -603 -553 -285 -27 -386 -379 -105 -349 -471 -185 91 -90 -355 -175 -183 458 430 706 319 340 501 573 371 236 -63 480 1071 1160 1364 649 110 -285 -189 -15 582 615 554 498 495 48 -56 -205 -813 -853 -844 -842 -1055 -2147 -1669 -1118 -1005 -68 257 499 599 625 257 146 178 84 -165 235 612 355 -163 -389 -738 -1207 -271 -807 -788 -731 -647 -162 518 892 789 532 20 -48 -203 -147 66 252 -6 109 101 446 151 661 260 82 532 435 267 167 -239 -320 168 401 -31 284 500 316 182 -39 -617 -789 -1097 SS 20250703T231030.5Z 9315.965631 157 1 1.19 2 50.25 88.13 148.37 50.68 0.00 1 0.00 1 0 17 1.205e-02 8.245e-03 8.009e-03 5.303e-03 1.990933e-01 2.724568e-03 2.294331e-03 -6.000000e+00 6.942415e-03 232.45 -2.00 3.39 -2.00 315.21 0.00e+00 2.837349e-05 2.483831e-04 8.625886e-05 -6.000000e+00 3.142155e-04 290.96 -2.00 20.00 -2.00 314.44 0.00e+00 1.561 0.000 302.00 328.00 3 3.7169e+00 7.0630e-03 1.8415e-02 -6.0000e+00 1.7393e-02 8.7538e-04 7.8640e-03 9.9828e-03 -6.0000e+00 1.8848e-02 1.1112e-02 4.4756e-03 4.8086e-03 -6.0000e+00 1.1235e-02 -9.4974e-03 1.9597e-03 1.3041e-03 -6.0000e+00 4.7216e-03 2.2409e-03 2.9221e-04 1.4880e-04 1.6514e-05 -6.0000e+00 3.2555e-04 6.7276e-03 0.0000e+00 12 9 1 12 1 1 999.00 26.06 0.34 0.00673 0.00892 1 9 1 5 0 592.350 34.75 20.00 26.06 37.30 0.0 1050.66 -1309 1260 -3207 -1987 -4757 2745 -753 1480 -1094 -2742 -1856 29 2569 875 -1052 1311 -350 248 2829 -154 2763 2621 413 -446 -4 1709 -1219 1055 346 -497 -397 743 -211 -2361 -3024 -2502 -2986 417 -98 -1161 -180 -1072 -700 -770 451 -331 -1363 -873 -272 1164 415 1235 2268 409 1237 1627 793 436 1161 432 268 803 1454 273 353 678 136 382 822 354 924 -236 -389 945 -379 -207 -1757 -1148 -1098 -537 -2110 -1604 -1562 -919 -935 262 -223 341 328 1329 -426 -801 -416 660 -313 1049 478 424 -280 -535 -818 -978 -77 -613 -877 -987 -835 -573 550 1320 -88 370 -242 269 544 -48 43 278 212 205 447 270 556 879 1107 174 594 821 -178 127 734 -577 -251 -1018 302 315 -5 -106 46 -308 -395 -779 -124 -428 419 -1012 -595 -1327 763 -222 482 -369 -944 -620 10 971 357 -456 585 -162 118 1354 -74 1366 1292 203 -234 -2 933 -659 515 170 -245 -196 390 -118 -1308 -1579 -1329 -1708 261 -67 -858 -140 -831 -550 -605 349 -255 -1069 -659 -199 855 326 979 1867 342 1045 1397 692 377 980 371 232 749 1392 263 335 603 118 330 754 352 943 -241 -406 928 -359 -189 -1540 -976 -966 -508 -2094 -1657 -1695 -1011 -1070 306 -275 413 405 1587 -490 -863 -426 667 -331 1168 573 536 -356 -675 -987 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