File name: Pandora277s1_Nagoya_20250816_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20250904T085352.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 277 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora277_OF_v3d20230817.txt Instrument calibration file used: Pandora277s1_CF_v4d20250225.txt Level 1 file used: Pandora277s1_Nagoya_20250816_L1_smca1c4d20250225p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20250816 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo HCHO First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1229 305.2636 305.4043 305.5450 305.6857 305.8264 305.9670 306.1077 306.2483 306.3890 306.5296 306.6702 306.8108 306.9514 307.0920 307.2325 307.3731 307.5136 307.6542 307.7947 307.9352 308.0757 308.2162 308.3567 308.4971 308.6376 308.7780 308.9185 309.0589 309.1993 309.3397 309.4801 309.6205 309.7608 309.9012 310.0415 310.1818 310.3222 310.4625 310.6028 310.7431 310.8833 311.0236 311.1639 311.3041 311.4443 311.5845 311.7247 311.8649 312.0051 312.1453 312.2855 312.4256 312.5658 312.7059 312.8460 312.9861 313.1262 313.2663 313.4064 313.5464 313.6865 313.8265 313.9665 314.1065 314.2465 314.3865 314.5265 314.6665 314.8065 314.9464 315.0863 315.2263 315.3662 315.5061 315.6460 315.7858 315.9257 316.0656 316.2054 316.3452 316.4851 316.6249 316.7647 316.9045 317.0442 317.1840 317.3238 317.4635 317.6032 317.7430 317.8827 318.0224 318.1620 318.3017 318.4414 318.5810 318.7207 318.8603 318.9999 319.1395 319.2791 319.4187 319.5583 319.6978 319.8374 319.9769 320.1164 320.2559 320.3955 320.5349 320.6744 320.8139 320.9533 321.0928 321.2322 321.3716 321.5111 321.6505 321.7898 321.9292 322.0686 322.2079 322.3473 322.4866 322.6259 322.7652 322.9045 323.0438 323.1831 323.3223 323.4616 323.6008 323.7401 323.8793 324.0185 324.1577 324.2968 324.4360 324.5752 324.7143 324.8534 324.9926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250815T211351.4Z 9358.884622 222 1 54.11 2 78.64 81.08 18.96 228.19 0.00 1 0.00 1 0 17 3.796e-01 1.278e-02 2.370e-01 7.624e-03 5.687359e-01 4.105074e-03 6.143447e-03 -6.000000e+00 2.186079e-01 231.34 -2.00 3.39 -2.00 321.24 0.00e+00 -3.104432e-04 2.029170e-03 5.546597e-04 -6.000000e+00 1.056763e-02 292.57 -2.00 20.00 -2.00 320.51 0.00e+00 4.904 0.002 302.00 328.00 3 3.5053e+00 1.4808e-02 5.6429e-02 -6.0000e+00 5.4508e-01 8.8744e-02 1.9778e-02 2.9506e-02 -6.0000e+00 5.9104e-01 -1.3840e-01 1.7577e-02 1.4378e-02 -6.0000e+00 3.5288e-01 5.0363e-02 8.3920e-03 3.9348e-03 -6.0000e+00 1.5039e-01 7.1192e-05 -6.1252e-04 2.2787e-04 4.6823e-05 -6.0000e+00 1.0344e-02 2.5537e-03 0.0000e+00 12 8 8 10 0 0 67.47 27.78 0.52 0.00255 -0.00205 25 3 1 5 0 2164.240 36.00 20.00 27.78 36.13 0.0 1038.56 -101186 900000 900000 -147170 900000 -210329 -47437 -85427 -61796 -107177 59116 -105420 -90426 -62285 186588 -33645 -101541 -12832 34016 -44691 -13185 -22790 -4592 -22676 -34762 20290 59428 -14425 10669 25473 -14343 29707 36299 9933 30795 23262 -4864 -3714 -14768 -2442 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961 -563 -1463 -1111 -238 714 914 367 44 326 195 -639 187 -108 -231 51 391 -638 -1115 1670 1662 -101 421 1130 122 -326 900 547 -314 -252 -291 577 328 -587 1570 -250 690 111 -995 -850 -1321 SS 20250815T212039.6Z 9358.889347 225 1 53.50 2 77.27 82.01 19.99 231.66 0.00 1 0.00 1 0 25 3.411e-01 1.594e-02 2.581e-01 9.861e-03 5.064025e-01 5.234518e-03 5.631711e-03 -6.000000e+00 1.968377e-01 231.34 -2.00 3.39 -2.00 320.93 0.00e+00 1.532475e-03 2.318245e-03 1.640853e-03 -6.000000e+00 9.098851e-03 292.57 -2.00 20.00 -2.00 320.16 0.00e+00 4.413 0.001 302.00 328.00 3 4.2256e+00 1.7734e-02 5.1100e-02 -6.0000e+00 4.9236e-01 7.4257e-02 2.2906e-02 2.7827e-02 -6.0000e+00 5.3455e-01 -1.1527e-01 1.9244e-02 1.3202e-02 -6.0000e+00 3.1916e-01 4.5751e-02 9.3887e-03 3.4535e-03 -6.0000e+00 1.3468e-01 5.8212e-05 -8.2713e-04 2.9553e-04 4.7468e-05 -6.0000e+00 9.2115e-03 2.5228e-03 0.0000e+00 12 9 8 11 8 0 96.80 27.78 0.23 0.00252 -0.00369 19 2 1 5 0 2815.580 36.00 20.00 27.78 36.66 0.0 1042.78 -174272 900000 105703 -86467 -149668 -82040 -92311 -83229 -12676 101620 -60295 -103604 83469 91051 17247 -26237 -17895 900000 56776 -22864 -40464 48195 37118 18654 17059 -19153 -35818 28949 -59972 8279 16214 -19281 -3188 -25249 -18175 985 21909 1324 31303 -7470 89 2767 -7842 18297 -5467 4502 9208 12884 -10199 6805 10329 5898 -1063 5058 7332 3502 1520 6612 10602 1280 7088 9871 7414 1182 7618 9164 2492 1822 3886 -1584 -156 6232 6792 -1527 4445 -1113 5398 -2942 722 -373 -4039 -6876 -2260 -2442 -2894 291 478 -479 -685 3358 -819 -528 -3081 -1471 1101 -1517 -798 -1006 -607 863 -440 -2479 -792 -2834 128 -710 -950 924 1109 -449 1050 672 113 -1705 360 548 -671 -15 590 -404 1505 966 20 926 -386 -404 626 92 -25 411 1242 405 579 318 -633 -92 633 -463 710 -792 -363 -962 -193 -6143 900000 1016 -1316 -3957 -1219 -1694 -1600 -133 977 -1107 -3350 802 875 301 -803 -547 900000 943 -879 -1874 927 843 554 552 -921 -2003 810 -4036 304 638 -1247 -195 -1942 -1239 57 1168 105 2243 -914 11 353 -1151 2095 -803 606 1191 1633 -1676 1005 1625 1067 -223 1065 1576 811 365 1491 2242 298 1642 2467 2125 391 2364 2925 829 634 1494 -732 -77 2954 3128 -719 1795 -428 1832 -1111 297 -181 -2337 -4568 -1538 -1765 -2256 234 404 -417 -589 2641 -623 -372 -2133 -1043 852 -1378 -820 -1160 -735 1002 -476 -2484 -746 -2861 136 -798 -1131 1149 1502 -680 1685 1107 182 -2646 512 753 -953 -22 935 -670 2431 1519 30 1356 -549 -550 822 128 -39 702 2253 772 1149 672 -1440 -216 1518 -1140 1713 -1863 -805 -2042 -403 SS 20250815T213922.3Z 9358.902341 234 1 51.75 2 73.47 84.60 23.04 239.74 0.00 1 0.00 1 0 17 7.421e-02 5.989e-03 4.799e-02 2.946e-03 4.140468e-01 1.515206e-03 4.588335e-03 -6.000000e+00 4.259157e-02 231.34 -2.00 3.39 -2.00 319.95 0.00e+00 1.732491e-03 4.837022e-04 4.586526e-04 -6.000000e+00 1.948363e-03 292.57 -2.00 20.00 -2.00 319.06 0.00e+00 3.458 0.001 302.00 328.00 3 3.6920e+00 4.5421e-03 4.0054e-02 -6.0000e+00 1.0635e-01 1.5350e-02 5.4721e-03 2.1069e-02 -6.0000e+00 1.1529e-01 -1.4837e-02 4.2099e-03 1.0365e-02 -6.0000e+00 6.8859e-02 -9.2705e-04 2.1700e-03 3.1809e-03 -6.0000e+00 2.9073e-02 2.7158e-04 -4.1671e-04 8.7669e-05 3.4172e-05 -6.0000e+00 2.0037e-03 3.0928e-03 0.0000e+00 12 1 1 12 1 1 99.95 27.80 0.42 0.00309 -0.00004 45 5 1 5 0 1124.730 36.00 20.00 27.80 37.40 0.0 1046.05 -33676 -3661 -7280 981 -12208 -41046 -17165 -32708 -12029 4123 -30628 -11381 -32920 -11732 -3317 -6880 -7583 1793 -1504 -5240 -2820 -7287 3347 -4519 9707 575 -3703 3295 -1874 -6622 -2245 2022 -2560 -8986 -2549 -233 -5096 -2354 4937 548 -1055 465 -1141 -422 1183 352 529 1000 -804 1764 -531 2383 823 1218 -298 148 600 -380 385 1135 1635 2048 2752 2020 1175 -166 37 -305 953 646 618 362 336 495 -485 -879 -1169 -1568 -1394 -496 -1351 -1686 -1424 -1360 -736 -293 616 86 542 1297 1425 266 214 -187 -202 -563 709 604 -437 25 -866 -796 -178 -822 -898 -757 -1028 -63 497 745 693 301 220 -123 -385 -602 323 295 -78 -279 122 203 -164 211 321 193 492 456 -211 279 -372 -449 -28 125 180 8 429 355 159 -122 -315 -459 -381 -695 -61 -127 15 -191 -868 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