File name: Pandora277s1_Nagoya_20250819_L2Fit_fout2c1d20231212p1-8.txt File generation date: 20250825T103504.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 277 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora277_OF_v3d20230817.txt Instrument calibration file used: Pandora277s1_CF_v2d20231212.txt Level 1 file used: Pandora277s1_Nagoya_20250819_L1_smca1c1d20231212p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20250819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0170 305.1577 305.2984 305.4391 305.5798 305.7205 305.8611 306.0018 306.1424 306.2831 306.4237 306.5643 306.7049 306.8455 306.9861 307.1266 307.2672 307.4077 307.5483 307.6888 307.8293 307.9698 308.1103 308.2508 308.3913 308.5317 308.6722 308.8126 308.9530 309.0934 309.2338 309.3742 309.5146 309.6550 309.7953 309.9357 310.0760 310.2164 310.3567 310.4970 310.6373 310.7775 310.9178 311.0581 311.1983 311.3386 311.4788 311.6190 311.7592 311.8994 312.0396 312.1797 312.3199 312.4601 312.6002 312.7403 312.8804 313.0205 313.1606 313.3007 313.4408 313.5808 313.7209 313.8609 314.0009 314.1410 314.2810 314.4209 314.5609 314.7009 314.8409 314.9808 315.1207 315.2607 315.4006 315.5405 315.6804 315.8202 315.9601 316.1000 316.2398 316.3796 316.5195 316.6593 316.7991 316.9389 317.0786 317.2184 317.3582 317.4979 317.6376 317.7773 317.9171 318.0568 318.1964 318.3361 318.4758 318.6154 318.7551 318.8947 319.0343 319.1739 319.3135 319.4531 319.5927 319.7322 319.8718 320.0113 320.1508 320.2903 320.4298 320.5693 320.7088 320.8483 320.9877 321.1272 321.2666 321.4060 321.5455 321.6849 321.8242 321.9636 322.1030 322.2423 322.3817 322.5210 322.6603 322.7996 322.9389 323.0782 323.2175 323.3567 323.4960 323.6352 323.7744 323.9137 324.0529 324.1921 324.3312 324.4704 324.6096 324.7487 324.8878 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250818T210743.3Z 9361.880362 209 1 55.01 2 80.29 81.13 26.59 96.20 0.00 1 0.00 1 0 17 4.740e-01 2.562e-02 3.535e-01 1.862e-02 6.300390e-01 1.019432e-02 1.131929e-02 -6.000000e+00 2.773545e-01 231.15 -2.00 3.39 -2.00 321.49 0.00e+00 1.994665e-02 5.363202e-03 1.707723e-02 -6.000000e+00 1.366588e-02 292.41 -2.00 20.00 -2.00 320.84 0.00e+00 5.653 0.003 302.00 328.00 3 3.0214e+00 3.8310e-02 1.0408e-01 -6.0000e+00 6.9334e-01 6.1094e-01 4.9098e-02 1.0526e-01 -6.0000e+00 7.5284e-01 -7.4389e-01 3.8051e-02 3.6277e-02 -6.0000e+00 4.4731e-01 2.8829e-01 1.8319e-02 4.4336e-03 -6.0000e+00 1.9138e-01 4.5932e-05 6.5022e-03 5.4112e-04 2.8752e-04 -6.0000e+00 1.3029e-02 1.8903e-01 0.0000e+00 12 8 8 10 0 0 13.06 27.98 0.77 0.18903 0.23789 16 2 1 5 0 3437.500 36.00 20.00 27.98 36.52 0.0 1040.62 -87080 900000 -120064 -77732 -133760 -55978 -71211 -79322 -129996 -19363 900000 14409 -32589 -33997 78945 -32065 75506 5435 55741 -36926 -3957 305783 -22700 -45823 900000 7595 116079 -83207 19322 70022 900000 35415 7984 900000 37315 -21695 26434 98354 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2979 -2269 3369 2166 2101 -2157 -1999 -340 -920 -2427 -2163 631 -2991 18 -530 1924 -5964 -4972 606 -5210 -4393 -2232 -707 -2475 1037 3440 280 5615 -351 888 518 -2705 -2673 -366 2574 -126 2424 1075 1885 2253 -1094 1885 2749 3845 834 -195 -681 1883 -2042 621 -198 -2217 -492 1479 2123 -19 1265 -2892 -3597 900000 SS 20250818T211541.1Z 9361.885892 213 1 53.61 2 78.68 82.24 25.02 97.71 0.00 1 0.00 1 0 25 3.912e-01 1.440e-02 2.362e-01 8.860e-03 5.737231e-01 4.765095e-03 7.261576e-03 -6.000000e+00 2.279412e-01 231.15 -2.00 3.39 -2.00 321.21 0.00e+00 5.903576e-04 2.397843e-03 8.945814e-03 -6.000000e+00 1.057012e-02 292.41 -2.00 20.00 -2.00 320.52 0.00e+00 4.917 0.002 302.00 328.00 3 3.0332e+00 1.7344e-02 7.4146e-02 -6.0000e+00 5.6898e-01 1.3849e-01 2.2809e-02 6.9759e-02 -6.0000e+00 6.1545e-01 -2.4408e-01 1.9705e-02 1.9629e-02 -6.0000e+00 3.6630e-01 9.8319e-02 9.4465e-03 8.0191e-03 -6.0000e+00 1.5719e-01 1.1340e-04 8.3320e-03 2.6463e-04 7.6073e-05 -6.0000e+00 1.0828e-02 1.8225e-01 0.0000e+00 12 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45 -138 -555 -234 1110 -1568 -247 -1032 -372 1465 -510 -219 72 1609 1150 1166 1385 1968 601 1281 443 1544 184 989 1118 135 161 548 1041 2277 771 1163 1424 950 1847 3460 253 1813 1328 489 853 580 1353 1670 -379 -2448 576 1789 -1795 1112 -1487 -85 -1387 -559 365 -1500 -424 191 -1187 -2202 516 1542 621 -744 982 -1716 -1227 -1700 243 -135 -2387 1067 -1011 -649 -1333 251 -966 -1332 -1283 -1270 322 1055 -797 433 51 -68 70 516 -1686 971 283 773 -235 1386 1365 300 -888 1145 846 1466 1660 877 391 893 -1102 1427 470 1046 -1831 -422 -404 -134 1470 251 -2134 -1556 900000 SS 20250818T212158.3Z 9361.890258 216 1 53.97 2 77.40 83.11 23.78 98.98 0.00 1 0.00 1 0 25 2.623e-01 8.850e-03 1.588e-01 4.579e-03 5.234033e-01 2.394685e-03 7.153431e-03 -6.000000e+00 1.517483e-01 231.15 -2.00 3.39 -2.00 320.85 0.00e+00 3.366892e-03 1.077794e-03 7.905636e-03 -6.000000e+00 6.929890e-03 292.41 -2.00 20.00 -2.00 320.11 0.00e+00 4.457 0.001 302.00 328.00 3 2.6204e+00 8.1478e-03 6.4144e-02 -6.0000e+00 3.7885e-01 4.4863e-02 1.0604e-02 5.8334e-02 -6.0000e+00 4.0954e-01 -8.4840e-02 9.2314e-03 2.0489e-02 -6.0000e+00 2.4463e-01 2.0591e-02 4.5072e-03 4.1555e-03 -6.0000e+00 1.0510e-01 2.7914e-04 8.8223e-03 1.3423e-04 1.0029e-04 -6.0000e+00 7.1054e-03 1.8052e-01 0.0000e+00 11 8 0 10 0 0 -2.74 27.97 0.40 0.18052 0.24682 50 5 1 5 0 1079.210 36.00 20.00 27.97 37.41 0.0 1047.58 10179 -94573 -112377 -103095 -123333 -107740 52216 -36219 -50597 -67424 -40605 -40516 -53418 -39512 -82005 7658 -1427 18318 -18238 -35550 -12096 -23368 2850 1208 -35843 -33314 -15672 -26005 -17797 -18216 1172 5285 12195 -14476 -12339 -18682 3110 -4100 9628 3437 10794 -436 9724 1400 1911 3596 -184 3859 3265 329 1417 6242 5099 3759 3106 -58 258 -2476 1619 5716 3775 2593 5577 2714 -156 -521 2280 1765 1138 3043 651 1026 1963 -931 -2136 -2189 -1737 -2030 -2816 -1167 544 -1938 -614 -1647 -541 1040 911 -50 148 344 -220 -1780 -895 47 -382 254 -878 -193 -457 -820 -1357 -1059 -728 -1194 -263 -661 758 210 385 1121 345 287 196 -873 -434 -161 -99 110 39 529 408 464 690 -183 -33 255 297 200 -227 7 -484 1 27 48 206 226 213 417 80 71 -561 -770 900000 50 -1343 -1779 -1381 -2052 -1705 233 -353 -596 -985 -527 -658 -1236 -962 -3495 146 -32 364 -548 -1284 -349 -797 81 37 -1658 -1487 -566 -1045 -722 -872 54 286 621 -918 -788 -1451 236 -406 963 400 1238 -58 1194 190 263 493 -27 558 509 59 275 1248 1102 859 740 -15 64 -613 387 1391 1045 816 1850 929 -52 -172 763 672 496 1405 315 483 860 -382 -799 -776 -633 -844 -1384 -648 332 -1299 -430 -1253 -434 861 771 -42 119 255 -152 -1206 -630 37 -345 261 -1020 -235 -541 -897 -1349 -1005 -724 -1289 -297 -791 954 292 588 1831 580 471 304 -1285 -617 -234 -152 179 67 885 660 726 1039 -267 -46 346 428 324 -407 13 -973 2 55 104 463 522 497 965 178 149 -1250 -1710 900000 SS 20250818T212724.3Z 9361.894032 219 1 54.87 2 76.30 83.86 22.72 100.15 0.00 1 0.00 1 0 25 1.261e-01 6.048e-03 1.273e-01 3.570e-03 4.899431e-01 1.848558e-03 5.949564e-03 -6.000000e+00 7.292924e-02 231.15 -2.00 3.39 -2.00 320.58 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