File name: Pandora277s1_Nagoya_20250916_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20250925T082702.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 277 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora277_OF_v3d20230817.txt Instrument calibration file used: Pandora277s1_CF_v4d20250225.txt Level 1 file used: Pandora277s1_Nagoya_20250916_L1_smca1c4d20250225p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20250916 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo HCHO First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1229 305.2636 305.4043 305.5450 305.6857 305.8264 305.9670 306.1077 306.2483 306.3890 306.5296 306.6702 306.8108 306.9514 307.0920 307.2325 307.3731 307.5136 307.6542 307.7947 307.9352 308.0757 308.2162 308.3567 308.4971 308.6376 308.7780 308.9185 309.0589 309.1993 309.3397 309.4801 309.6205 309.7608 309.9012 310.0415 310.1818 310.3222 310.4625 310.6028 310.7431 310.8833 311.0236 311.1639 311.3041 311.4443 311.5845 311.7247 311.8649 312.0051 312.1453 312.2855 312.4256 312.5658 312.7059 312.8460 312.9861 313.1262 313.2663 313.4064 313.5464 313.6865 313.8265 313.9665 314.1065 314.2465 314.3865 314.5265 314.6665 314.8065 314.9464 315.0863 315.2263 315.3662 315.5061 315.6460 315.7858 315.9257 316.0656 316.2054 316.3452 316.4851 316.6249 316.7647 316.9045 317.0442 317.1840 317.3238 317.4635 317.6032 317.7430 317.8827 318.0224 318.1620 318.3017 318.4414 318.5810 318.7207 318.8603 318.9999 319.1395 319.2791 319.4187 319.5583 319.6978 319.8374 319.9769 320.1164 320.2559 320.3955 320.5349 320.6744 320.8139 320.9533 321.0928 321.2322 321.3716 321.5111 321.6505 321.7898 321.9292 322.0686 322.2079 322.3473 322.4866 322.6259 322.7652 322.9045 323.0438 323.1831 323.3223 323.4616 323.6008 323.7401 323.8793 324.0185 324.1577 324.2968 324.4360 324.5752 324.7143 324.8534 324.9926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250915T211731.7Z 9389.887173 238 1 54.69 2 82.25 92.20 12.87 122.59 0.00 1 0.00 1 0 17 4.445e-01 2.021e-02 3.933e-01 1.416e-02 7.024745e-01 8.123735e-03 8.331644e-03 -6.000000e+00 2.594000e-01 229.34 -2.00 3.39 -2.00 321.89 0.00e+00 1.351372e-02 4.684145e-03 2.872755e-03 -6.000000e+00 1.265378e-02 290.79 -2.00 20.00 -2.00 321.35 0.00e+00 6.899 0.005 302.00 328.00 3 2.0596e+00 3.2304e-02 7.7102e-02 -6.0000e+00 6.4576e-01 6.2850e-01 4.2787e-02 3.7550e-02 -6.0000e+00 6.9923e-01 -8.4970e-01 3.6286e-02 2.2106e-02 -6.0000e+00 4.1595e-01 3.3854e-01 1.7149e-02 1.3738e-02 -6.0000e+00 1.8020e-01 3.6838e-05 -1.3359e-03 4.1531e-04 2.2041e-04 -6.0000e+00 1.2189e-02 1.8017e-02 0.0000e+00 12 8 8 10 0 0 -11.05 26.01 0.56 0.01802 0.00798 37 4 1 5 0 1478.040 34.75 20.00 26.01 33.12 0.0 1012.95 -54612 -116203 -30647 -76491 -45712 -103242 99038 -111705 -91476 900000 -120344 83019 150847 -43019 -55457 23559 -172 -73316 27848 104203 -109806 -43292 -24250 151497 12920 900000 -82838 -10891 -34262 82610 -3097 90586 49354 -47919 900000 120224 32360 7723 41660 26863 100593 13779 44778 7648 31414 -8953 139936 -949 877 29125 46773 22629 25884 43596 31008 33585 9996 14132 503 9398 4224 15804 9647 12627 2576 26806 6853 2052 20510 12302 8353 2596 2298 8857 5315 -1014 4628 -2321 1624 -1540 -2160 -550 -5075 -223 -6209 -2645 -209 4470 -757 958 3237 104 -3237 1469 455 -1633 695 -88 -1329 -85 -1637 -582 -638 -2809 -1631 -4350 -3014 775 -2522 -193 -632 1378 -2489 -1334 206 -1266 941 1221 1761 -253 1231 964 1394 1179 2328 349 1414 -884 1104 1097 1498 305 -1251 -2 -1205 744 421 -286 919 153 -922 -1674 900000 -754 -3207 -423 -1231 -631 -1781 1367 -2183 -1473 900000 -2629 1145 2081 -890 -1739 384 -4 -3679 524 1438 -7851 -1520 -700 2090 259 900000 -4156 -260 -1074 1140 -101 1364 1238 -3126 900000 1659 974 349 1568 1314 2524 864 2134 537 1773 -775 2808 -81 77 2082 3110 2100 2500 3719 3073 3286 1229 1613 64 1096 556 2101 1561 2186 501 3968 1238 412 3885 2855 2148 713 605 2212 1232 -227 951 -551 437 -512 -840 -237 -2458 -109 -3435 -1496 -120 2498 -439 518 1594 50 -1595 750 272 -1176 571 -82 -1342 -83 -1477 -464 -483 -2271 -1405 -4070 -2974 802 -3035 -257 -929 2067 -3846 -1955 284 -1737 1309 1800 2741 -410 1915 1442 2012 1652 3115 459 1832 -1286 1813 2032 3012 658 -2906 -6 -3202 2014 1164 -805 2520 401 -2284 -3939 900000 SS 20250915T213458.8Z 9389.899291 243 1 54.55 2 78.69 94.76 10.18 135.92 0.00 1 0.00 1 0 17 2.667e-01 6.516e-03 6.506e-02 2.149e-03 5.480408e-01 1.160648e-03 6.271278e-03 -6.000000e+00 1.545170e-01 229.34 -2.00 3.39 -2.00 320.81 0.00e+00 2.390683e-03 5.043373e-04 1.800201e-03 -6.000000e+00 6.991039e-03 290.78 -2.00 20.00 -2.00 320.11 0.00e+00 4.924 0.002 302.00 328.00 3 1.6646e+00 3.8528e-03 5.6472e-02 -6.0000e+00 3.8436e-01 4.0254e-02 5.0293e-03 3.0040e-02 -6.0000e+00 4.1507e-01 -8.2123e-02 4.5613e-03 1.5524e-02 -6.0000e+00 2.4798e-01 2.5392e-02 2.2461e-03 4.6798e-03 -6.0000e+00 1.0776e-01 4.5284e-04 -2.2391e-04 6.2476e-05 6.4266e-05 -6.0000e+00 7.2182e-03 1.7904e-02 0.0000e+00 11 9 0 11 8 0 25.60 25.98 0.42 0.01790 0.01622 169 17 1 5 0 322.720 34.75 20.00 25.98 34.67 0.0 1026.51 -108217 -102922 -69188 -90551 -80791 -93389 -105740 -74490 -69827 -71484 -89708 -52825 -43459 -31774 -32656 -16578 -18139 11656 -20023 -20514 -14564 -13571 -7466 -8975 -14939 -48 -8994 -17072 -20703 -16723 -7619 -5553 -344 -6462 -13854 -6578 -8457 -487 4737 -2255 -950 940 1062 861 -387 185 20 -949 1938 574 3341 1232 935 3040 1701 1063 500 1658 1202 1828 2197 2398 2406 2240 2019 3009 1222 1548 1686 1933 339 1776 688 873 -131 -484 -2723 -1862 -2644 -1171 -1412 -1854 -1956 -723 -773 -115 1071 1075 692 1034 -115 368 -501 -442 -777 -264 941 -82 -174 26 -1028 -1069 -1037 -1304 -1055 -711 -779 -56 315 595 376 351 217 -335 -254 152 -186 224 239 -124 503 427 471 229 -25 141 378 287 112 246 -247 -531 -34 95 -99 156 331 257 22 -73 -432 -413 900000 -1278 -1274 -619 -932 -708 -961 -1390 -823 -811 -885 -1418 -684 -646 -527 -659 -325 -397 207 -519 -559 -415 -390 -216 -288 -545 -2 -315 -626 -798 -690 -340 -283 -18 -368 -816 -376 -571 -37 417 -246 -112 115 134 111 -51 25 3 -135 279 91 572 238 197 669 397 259 124 401 286 436 558 682 770 777 700 989 405 541 672 871 167 877 333 394 -54 -182 -1002 -713 -1175 -603 -836 -1229 -1391 -540 -620 -97 940 958 608 859 -90 267 -357 -335 -670 -260 954 -93 -208 30 -1096 -1136 -1064 -1421 -1123 -794 -922 -71 436 908 618 588 355 -521 -371 216 -274 347 395 -210 837 687 734 344 -36 196 515 422 185 450 -485 -1094 -74 199 -222 363 785 618 53 -165 -933 -928 900000 SS 20250915T214105.3Z 9389.903534 246 1 54.59 2 77.45 95.66 9.38 142.13 0.00 1 0.00 1 0 17 1.608e-01 5.141e-03 4.071e-02 1.428e-03 5.053862e-01 7.565558e-04 5.710851e-03 -6.000000e+00 9.313803e-02 229.34 -2.00 3.39 -2.00 320.53 0.00e+00 2.362697e-03 2.969937e-04 1.166610e-03 -6.000000e+00 4.213723e-03 290.78 -2.00 20.00 -2.00 319.80 0.00e+00 4.473 0.001 302.00 328.00 3 1.5583e+00 2.3940e-03 5.1101e-02 -6.0000e+00 2.3168e-01 1.4331e-02 3.0496e-03 2.6432e-02 -6.0000e+00 2.5019e-01 -3.6605e-02 2.7098e-03 1.3725e-02 -6.0000e+00 1.4947e-01 4.9594e-03 1.3619e-03 4.4346e-03 -6.0000e+00 6.4959e-02 8.0281e-04 -1.4912e-04 4.1532e-05 5.3060e-05 -6.0000e+00 4.3506e-03 1.7464e-02 0.0000e+00 10 0 0 10 0 0 21.16 25.99 0.39 0.01746 0.01634 236 24 1 5 0 231.290 34.75 20.00 25.99 35.36 0.0 1031.57 -42228 -52206 -72437 -67746 -58890 -40612 -71023 -24467 -67538 -7818 -39614 -33535 -21190 -9036 -17895 -3180 -14603 80 -13610 -16222 -10730 -13939 535 -7589 -5082 -8023 -4375 -8366 -7302 -8041 -6499 1313 -6438 68 -6029 -3310 -4500 -5370 -509 -74 -1289 -2955 1412 1994 -1544 -888 -94 660 2342 749 1435 936 1407 1971 558 1679 1183 122 171 1713 2417 2558 3010 1791 1517 1338 -125 938 652 1165 1427 318 385 260 -69 -855 -1651 -1943 -2479 -1176 -1437 -1221 -1266 -1349 -389 -15 614 731 731 799 196 -160 27 -24 -324 -6 324 126 -299 -414 -575 -535 -415 -1190 -780 -749 -790 -56 409 524 563 356 321 -83 -220 62 177 182 -123 -179 110 216 209 278 100 -79 412 254 174 126 -249 -232 9 39 -157 68 220 203 -105 -11 -309 -255 900000 -369 -555 -953 -789 -589 -349 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