File name: Pandora277s1_Nagoya_20251012_L2Fit_fout2c4d20250225p1-8.txt File generation date: 20251012T144513.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 277 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora277_OF_v3d20230817.txt Instrument calibration file used: Pandora277s1_CF_v4d20250225.txt Level 1 file used: Pandora277s1_Nagoya_20251012_L1_smca1c4d20250225p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20251012 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: redo HCHO First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1229 305.2636 305.4043 305.5450 305.6857 305.8264 305.9670 306.1077 306.2483 306.3890 306.5296 306.6702 306.8108 306.9514 307.0920 307.2325 307.3731 307.5136 307.6542 307.7947 307.9352 308.0757 308.2162 308.3567 308.4971 308.6376 308.7780 308.9185 309.0589 309.1993 309.3397 309.4801 309.6205 309.7608 309.9012 310.0415 310.1818 310.3222 310.4625 310.6028 310.7431 310.8833 311.0236 311.1639 311.3041 311.4443 311.5845 311.7247 311.8649 312.0051 312.1453 312.2855 312.4256 312.5658 312.7059 312.8460 312.9861 313.1262 313.2663 313.4064 313.5464 313.6865 313.8265 313.9665 314.1065 314.2465 314.3865 314.5265 314.6665 314.8065 314.9464 315.0863 315.2263 315.3662 315.5061 315.6460 315.7858 315.9257 316.0656 316.2054 316.3452 316.4851 316.6249 316.7647 316.9045 317.0442 317.1840 317.3238 317.4635 317.6032 317.7430 317.8827 318.0224 318.1620 318.3017 318.4414 318.5810 318.7207 318.8603 318.9999 319.1395 319.2791 319.4187 319.5583 319.6978 319.8374 319.9769 320.1164 320.2559 320.3955 320.5349 320.6744 320.8139 320.9533 321.0928 321.2322 321.3716 321.5111 321.6505 321.7898 321.9292 322.0686 322.2079 322.3473 322.4866 322.6259 322.7652 322.9045 323.0438 323.1831 323.3223 323.4616 323.6008 323.7401 323.8793 324.0185 324.1577 324.2968 324.4360 324.5752 324.7143 324.8534 324.9926 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251011T221757.0Z 9415.929132 271 1 54.84 2 74.56 110.96 41.45 274.43 0.00 1 0.00 1 0 17 6.307e-02 5.783e-03 5.768e-02 3.773e-03 3.913182e-01 1.943730e-03 4.512345e-03 -6.000000e+00 3.625882e-02 227.08 -2.00 3.39 -2.00 319.81 0.00e+00 1.552649e-03 5.996916e-04 4.518109e-04 -6.000000e+00 1.634267e-03 288.13 -2.00 20.00 -2.00 319.06 0.00e+00 3.686 0.001 302.00 328.00 3 3.8483e+00 5.6391e-03 4.1268e-02 -6.0000e+00 8.9802e-02 1.6539e-02 6.7914e-03 2.0036e-02 -6.0000e+00 9.7145e-02 -4.2990e-04 5.4894e-03 1.0132e-02 -6.0000e+00 5.8046e-02 -8.0515e-03 2.8739e-03 3.2314e-03 -6.0000e+00 2.5318e-02 1.9318e-04 -3.0171e-04 1.1188e-04 3.5099e-05 -6.0000e+00 1.7048e-03 9.3730e-03 0.0000e+00 11 1 0 11 8 0 99.93 26.01 0.40 0.00937 0.00711 48 5 1 5 0 1142.410 34.75 20.00 26.01 30.01 0.0 987.40 -2535 11792 -10256 -18619 -15956 -23193 -20324 -37524 -7972 -16691 -24770 -8481 -18628 2726 -12676 8172 -880 4401 4203 -6933 -6051 -86 -9302 132 -469 10215 2094 -3027 -2818 216 2313 -262 -1731 -3031 -5351 -5746 3355 -4973 3008 -1582 -1086 1586 115 2064 -742 -1980 -3322 1940 2115 67 -15 1209 2044 1293 119 604 -310 54 226 598 1916 1558 2446 1192 805 170 -169 360 -84 -139 1130 -150 548 289 119 -710 -1174 -1875 -999 -1677 -1104 -2305 -1187 -1127 -324 -220 612 905 894 655 838 124 -8 -410 -362 301 723 905 182 -226 -900 -891 -1011 -520 -1229 -1137 -661 -150 554 655 243 567 172 -119 7 -36 365 29 -1 -296 -53 184 18 309 353 -141 398 407 235 282 -255 -177 66 -10 -267 152 145 -18 38 -24 -512 42 900000 -43 189 -206 -374 -288 -458 -435 -1092 -189 -447 -737 -241 -704 100 -636 369 -46 235 238 -457 -399 -5 -672 9 -39 789 172 -248 -226 18 211 -28 -203 -357 -612 -681 415 -809 544 -343 -254 379 29 512 -191 -519 -880 488 539 18 -4 388 695 468 45 235 -123 21 87 231 772 695 1193 626 416 83 -79 173 -46 -85 736 -101 360 180 68 -365 -567 -923 -545 -1062 -788 -1836 -995 -999 -306 -221 640 961 937 653 769 105 -7 -342 -335 312 840 1162 244 -295 -1088 -984 -1086 -589 -1513 -1470 -895 -214 846 985 389 908 266 -189 11 -52 531 45 -2 -513 -92 307 29 479 525 -200 547 588 374 487 -467 -334 117 -19 -535 317 309 -39 81 -50 -1021 80 900000 SS 20251011T222924.3Z 9415.937086 274 1 54.74 2 72.39 112.87 43.71 275.79 0.00 1 0.00 1 0 17 2.962e-02 5.121e-03 1.772e-02 1.909e-03 3.511668e-01 9.783059e-04 4.081217e-03 -6.000000e+00 1.702772e-02 227.08 -2.00 3.39 -2.00 319.21 0.00e+00 8.029897e-04 2.459889e-04 4.222553e-04 -6.000000e+00 7.674673e-04 288.13 -2.00 20.00 -2.00 318.41 0.00e+00 3.258 0.000 302.00 328.00 3 3.3398e+00 2.7422e-03 3.6610e-02 -6.0000e+00 4.2172e-02 1.5122e-02 3.2017e-03 1.7922e-02 -6.0000e+00 4.5620e-02 7.4714e-04 2.3294e-03 8.8697e-03 -6.0000e+00 2.7259e-02 -7.8283e-03 1.2262e-03 2.5699e-03 -6.0000e+00 1.1890e-02 5.0800e-04 -3.3828e-04 5.6481e-05 2.9003e-05 -6.0000e+00 8.0058e-04 9.1550e-03 0.0000e+00 10 0 0 10 0 0 99.97 26.02 0.38 0.00915 0.00661 106 11 1 5 0 516.330 34.75 20.01 26.02 30.39 0.0 990.71 -14750 -10446 -12363 -6249 -8608 1015 -12786 -3400 1282 -10611 -5689 -4557 -8003 -3405 32 -617 1252 -1216 3180 2393 861 -2647 130 -1322 -2892 -2748 -2307 -2716 -1797 -610 2034 -569 -66 -3524 -2595 -4501 -3042 -2079 -380 -1578 -1298 -495 -171 499 373 555 599 404 -1091 324 1176 1247 0 1038 1158 888 1098 407 372 1013 1346 2015 1871 836 1053 51 -739 -519 332 126 1150 1022 567 713 -256 -628 -1081 -1353 -961 -1453 -1271 -1597 -1436 -1473 -598 18 277 572 501 292 468 -77 -300 -169 302 376 491 159 145 -367 -772 -993 -213 -655 -651 -793 -813 -376 289 408 718 268 172 -257 -44 -118 34 123 193 71 285 163 267 163 202 150 277 475 31 174 -194 -279 -90 138 0 174 108 165 -27 -7 -266 -528 900000 -479 -350 -463 -201 -261 28 -457 -127 50 -478 -248 -217 -466 -225 2 -50 106 -112 293 231 85 -273 14 -152 -359 -349 -285 -318 -202 -71 256 -82 -10 -560 -387 -704 -535 -437 -94 -453 -401 -159 -56 164 124 184 196 132 -363 111 433 496 0 465 535 424 530 195 175 477 667 1088 1110 529 649 29 -411 -295 209 90 872 796 434 516 -171 -378 -606 -764 -599 -1045 -1029 -1426 -1359 -1340 -580 18 298 624 540 299 485 -73 -271 -155 305 387 566 202 191 -471 -917 -1083 -247 -736 -790 -1012 -1090 -529 433 659 1219 458 281 -393 -63 -161 48 181 305 117 470 262 416 244 288 204 364 651 47 282 -333 -493 -163 265 -1 338 216 335 -55 -14 -542 -1038 900000 SS 20251011T225006.2Z 9415.951461 287 1 20.44 2 68.55 116.48 47.78 278.16 0.00 1 0.00 1 0 17 1.954e-02 6.035e-03 1.129e-02 2.529e-03 2.944155e-01 1.287297e-03 3.437674e-03 -6.000000e+00 1.123218e-02 227.08 -2.00 3.39 -2.00 318.01 0.00e+00 6.319891e-04 2.284434e-04 2.507751e-04 -6.000000e+00 5.062343e-04 288.13 -2.00 20.00 -2.00 317.19 0.00e+00 2.709 0.000 302.00 328.00 3 4.0289e+00 3.4450e-03 3.0426e-02 -6.0000e+00 2.7819e-02 1.0560e-02 3.9000e-03 1.4815e-02 -6.0000e+00 3.0092e-02 -8.1002e-04 2.4772e-03 7.2714e-03 -6.0000e+00 1.7981e-02 -3.7445e-03 1.2856e-03 2.0813e-03 -6.0000e+00 7.8437e-03 4.6686e-04 -2.2610e-04 7.3221e-05 2.2550e-05 -6.0000e+00 5.2806e-04 8.6262e-03 0.0000e+00 12 1 1 12 1 1 96.77 26.05 0.26 0.00863 0.00693 13 4 1 5 0 1459.670 34.75 19.98 26.05 31.37 0.0 997.97 97 -5974 -1712 -6766 2238 -6040 -1515 -2227 -7109 -7621 -6947 -9783 -2446 -3896 -1500 -1208 -428 1422 -421 1799 1467 -12 -134 791 2482 -1268 -612 439 323 493 786 1671 161 -1510 -2829 -3114 -2748 -1691 617 1574 -386 -88 -650 563 42 -859 957 -379 -341 252 109 640 2334 762 863 -139 142 271 110 649 1692 2018 1775 1141 91 158 -1216 252 227 575 689 675 1055 -90 -462 -692 -1102 -689 -1488 -1286 -1572 -1556 -1601 -1238 -636 -273 214 483 496 694 19 -162 600 -307 -25 513 104 27 140 -494 -280 -883 -604 -592 -978 -633 -751 -16 461 613 682 466 -148 -105 134 0 98 244 179 77 -61 289 633 437 35 23 473 120 215 426 -380 -48 81 279 138 -12 315 -53 -116 -253 -371 -708 900000 7 -485 -131 -496 137 -404 -107 -181 -659 -724 -656 -1033 -278 -525 -224 -195 -71 244 -77 333 274 -2 -26 166 540 -293 -136 91 64 100 174 403 42 -397 -710 -803 -802 -587 228 653 -175 -42 -315 271 20 -419 450 -178 -159 121 56 352 1341 466 542 -90 93 175 70 413 1124 1458 1282 868 68 108 -870 180 166 472 606 609 930 -76 -359 -527 -777 -481 -1148 -1034 -1423 -1539 -1676 -1259 -691 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