File name: Pandora227s1_NakhonPathom_20250316_L2Fit_fout2c4d20250216p1-8.txt File generation date: 20260618T202749.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 227 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora227_OF_v1d20220531.txt Instrument calibration file used: Pandora227s1_CF_v4d20250216.txt Level 1 file used: Pandora227s1_NakhonPathom_20250316_L1_smca1c4d20250216p1-8.txt Full location name: Silpakorn University, Sanam Chandra palace campus (Nakhon Pathom) Short location name: NakhonPathom Country of location: Thailand Location latitude [deg]: 13.8200 Location longitude [deg]: 100.0400 Location altitude [m]: 72 Local noon date: 20250316 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0282 305.1693 305.3104 305.4515 305.5925 305.7336 305.8747 306.0157 306.1567 306.2977 306.4387 306.5797 306.7207 306.8617 307.0027 307.1436 307.2846 307.4255 307.5664 307.7073 307.8482 307.9891 308.1300 308.2708 308.4117 308.5525 308.6933 308.8342 308.9750 309.1158 309.2566 309.3973 309.5381 309.6788 309.8196 309.9603 310.1010 310.2417 310.3824 310.5231 310.6638 310.8045 310.9451 311.0857 311.2264 311.3670 311.5076 311.6482 311.7888 311.9293 312.0699 312.2105 312.3510 312.4915 312.6320 312.7725 312.9130 313.0535 313.1940 313.3345 313.4749 313.6153 313.7558 313.8962 314.0366 314.1770 314.3174 314.4577 314.5981 314.7384 314.8788 315.0191 315.1594 315.2997 315.4400 315.5803 315.7206 315.8608 316.0011 316.1413 316.2815 316.4217 316.5619 316.7021 316.8423 316.9825 317.1226 317.2628 317.4029 317.5430 317.6831 317.8232 317.9633 318.1034 318.2435 318.3835 318.5236 318.6636 318.8036 318.9436 319.0836 319.2236 319.3636 319.5035 319.6435 319.7834 319.9233 320.0633 320.2032 320.3431 320.4829 320.6228 320.7627 320.9025 321.0424 321.1822 321.3220 321.4618 321.6016 321.7414 321.8811 322.0209 322.1606 322.3004 322.4401 322.5798 322.7195 322.8592 322.9989 323.1385 323.2782 323.4178 323.5574 323.6971 323.8367 323.9763 324.1158 324.2554 324.3950 324.5345 324.6741 324.8136 324.9531 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250316T001742.2Z 9206.012294 245 1 51.20 2 78.50 94.68 88.29 261.92 0.00 1 0.00 1 0 17 3.840e-01 1.069e-02 2.485e-01 6.016e-03 5.048816e-01 3.143914e-03 5.100455e-03 -6.000000e+00 2.174427e-01 227.45 -2.00 3.09 -2.00 321.05 0.00e+00 7.494221e-04 1.462956e-03 1.023601e-03 -6.000000e+00 1.008261e-02 293.67 -2.00 20.00 -2.00 320.29 0.00e+00 4.848 0.000 302.00 328.00 3 3.0769e+00 1.0990e-02 5.3026e-02 -6.0000e+00 5.3784e-01 -5.4745e-04 1.4484e-02 2.4205e-02 -6.0000e+00 5.8363e-01 -6.5979e-02 1.2738e-02 1.1943e-02 -6.0000e+00 3.5017e-01 1.9838e-02 6.2036e-03 3.3478e-03 -6.0000e+00 1.5001e-01 1.2879e-04 -2.1772e-04 1.8039e-04 4.2741e-05 -6.0000e+00 1.0195e-02 9.9223e-03 0.0000e+00 12 9 8 11 16 0 51.22 26.05 0.70 0.00992 0.00829 56 9 1 5 0 914.260 28.21 20.00 26.05 35.88 1.3 1055.65 -67812 -23512 -145921 161285 -92667 78645 -101249 -120381 -62003 -76199 102908 -107071 220525 -93105 74928 -30539 28680 -16235 -1977 -9533 -15811 65350 -27289 29457 -259 -18846 -44907 -21480 -24530 -6578 -1211 -18739 -14516 -3110 10324 -10565 -5221 -10708 9169 21194 8742 8134 5012 3692 2714 5323 -6965 -1518 10572 3511 5195 2613 6509 3683 405 1990 3272 824 2657 5446 1150 4504 1476 6418 2509 1668 993 -1120 -1237 2753 3684 -1657 2200 1484 -1024 -3092 -517 -4175 -1192 -4182 -3050 -1189 -3480 -1333 -1533 251 223 965 1388 -1206 1193 -149 567 -2915 -557 -496 -255 822 711 -34 -302 -1198 -1417 -812 -1012 -324 -180 -1214 1651 893 1082 601 1279 -1045 188 -551 -653 -266 -754 33 -547 352 274 930 -16 209 -225 523 607 -215 -5 -161 -608 -238 83 -341 549 742 333 586 -635 -311 -897 -530 -138 -3139 946 -1137 461 -1404 -2311 -761 -1179 604 -2513 1294 -2830 520 -717 413 -398 -45 -249 -455 836 -917 613 -8 -734 -2323 -848 -955 -221 -44 -939 -797 -164 457 -563 -290 -742 641 1583 835 837 559 470 352 684 -1022 -214 1352 505 805 461 1203 758 91 459 770 199 616 1211 275 1139 432 1988 841 540 312 -364 -439 1084 1593 -793 1011 656 -428 -1185 -178 -1475 -447 -1892 -1580 -685 -2240 -888 -1100 190 178 791 1137 -978 878 -103 369 -1982 -407 -415 -243 881 825 -39 -329 -1200 -1317 -768 -1044 -352 -206 -1493 2135 1285 1695 986 2059 -1639 272 -767 -918 -391 -1192 54 -910 565 429 1392 -23 290 -302 723 933 -370 -10 -314 -1240 -512 191 -828 1353 1867 842 1424 -1486 -691 -1961 SS 20250316T002331.7Z 9206.016339 248 1 51.54 2 77.09 95.05 89.66 262.24 0.00 1 0.00 1 0 25 1.618e-01 7.882e-03 8.787e-02 3.322e-03 4.641219e-01 1.698004e-03 4.859662e-03 -6.000000e+00 9.165573e-02 227.45 -2.00 3.09 -2.00 320.57 0.00e+00 1.741464e-03 6.881882e-04 2.152271e-03 -6.000000e+00 4.267451e-03 293.67 -2.00 20.00 -2.00 319.77 0.00e+00 4.356 0.000 302.00 328.00 3 2.7425e+00 5.4536e-03 4.8618e-02 -6.0000e+00 2.2670e-01 -2.0835e-02 6.9852e-03 2.5123e-02 -6.0000e+00 2.4609e-01 -2.1914e-02 5.9992e-03 1.1680e-02 -6.0000e+00 1.4760e-01 4.2677e-04 3.0162e-03 2.9913e-03 -6.0000e+00 6.3611e-02 2.9526e-04 -4.8049e-04 9.7452e-05 3.7780e-05 -6.0000e+00 4.3297e-03 1.0219e-02 0.0000e+00 11 9 0 11 16 0 62.79 26.05 0.49 0.01022 0.00661 96 16 1 5 0 536.800 28.21 20.00 26.05 36.30 1.3 1058.23 900000 -78238 -3237 -40708 -39953 -52057 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298 481 1376 1178 1062 468 -427 -61 -303 889 537 966 1331 401 311 -628 -907 -1010 -82 -628 -547 -991 -1330 -1791 -464 -107 1027 545 940 1373 185 588 -590 -848 -1270 -699 506 -139 96 -997 -396 -2119 -1369 -351 -1450 -1461 -1366 -109 287 1760 1175 1182 379 336 -285 -598 -343 648 372 9 914 628 1321 468 259 60 -719 230 -267 809 -594 -578 -969 -316 -372 195 961 1498 596 -89 -291 -1241 -1092 SS 20250316T002854.8Z 9206.020079 251 1 51.61 2 75.79 95.40 90.93 262.53 0.00 1 0.00 1 0 17 1.062e-01 6.260e-03 4.778e-02 2.258e-03 4.305343e-01 1.159481e-03 4.486269e-03 -6.000000e+00 6.011947e-02 227.45 -2.00 3.09 -2.00 320.27 0.00e+00 1.674203e-03 4.173842e-04 1.478204e-03 -6.000000e+00 2.787639e-03 293.67 -2.00 20.00 -2.00 319.41 0.00e+00 3.983 0.000 302.00 328.00 3 2.5420e+00 3.6013e-03 4.4156e-02 -6.0000e+00 1.4870e-01 -2.8775e-02 4.4621e-03 2.1477e-02 -6.0000e+00 1.6136e-01 -7.3792e-03 3.6277e-03 1.0428e-02 -6.0000e+00 9.6816e-02 -5.7009e-03 1.8561e-03 2.8310e-03 -6.0000e+00 4.1475e-02 5.3115e-04 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