File name: Pandora227s1_NakhonPathom_20250411_L2Fit_fout2c4d20250216p1-8.txt File generation date: 20260618T204821.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Darunee Promchot Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 227 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora227_OF_v2d20220531.txt Instrument calibration file used: Pandora227s1_CF_v4d20250216.txt Level 1 file used: Pandora227s1_NakhonPathom_20250411_L1_smca1c4d20250216p1-8.txt Full location name: Silpakorn University, Sanam Chandra palace campus (Nakhon Pathom) Short location name: NakhonPathom Country of location: Thailand Location latitude [deg]: 13.8200 Location longitude [deg]: 100.0400 Location altitude [m]: 72 Local noon date: 20250411 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0282 305.1693 305.3104 305.4515 305.5925 305.7336 305.8747 306.0157 306.1567 306.2977 306.4387 306.5797 306.7207 306.8617 307.0027 307.1436 307.2846 307.4255 307.5664 307.7073 307.8482 307.9891 308.1300 308.2708 308.4117 308.5525 308.6933 308.8342 308.9750 309.1158 309.2566 309.3973 309.5381 309.6788 309.8196 309.9603 310.1010 310.2417 310.3824 310.5231 310.6638 310.8045 310.9451 311.0857 311.2264 311.3670 311.5076 311.6482 311.7888 311.9293 312.0699 312.2105 312.3510 312.4915 312.6320 312.7725 312.9130 313.0535 313.1940 313.3345 313.4749 313.6153 313.7558 313.8962 314.0366 314.1770 314.3174 314.4577 314.5981 314.7384 314.8788 315.0191 315.1594 315.2997 315.4400 315.5803 315.7206 315.8608 316.0011 316.1413 316.2815 316.4217 316.5619 316.7021 316.8423 316.9825 317.1226 317.2628 317.4029 317.5430 317.6831 317.8232 317.9633 318.1034 318.2435 318.3835 318.5236 318.6636 318.8036 318.9436 319.0836 319.2236 319.3636 319.5035 319.6435 319.7834 319.9233 320.0633 320.2032 320.3431 320.4829 320.6228 320.7627 320.9025 321.0424 321.1822 321.3220 321.4618 321.6016 321.7414 321.8811 322.0209 322.1606 322.3004 322.4401 322.5798 322.7195 322.8592 322.9989 323.1385 323.2782 323.4178 323.5574 323.6971 323.8367 323.9763 324.1158 324.2554 324.3950 324.5345 324.6741 324.8136 324.9531 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250411T000039.1Z 9232.000452 211 1 52.11 2 78.46 84.14 120.08 277.99 0.00 1 0.00 1 0 25 3.457e-01 1.367e-02 2.434e-01 9.836e-03 5.186897e-01 5.180384e-03 5.635272e-03 -6.000000e+00 1.972285e-01 229.28 -2.00 3.09 -2.00 321.05 0.00e+00 6.261239e-03 2.405845e-03 2.861465e-03 -6.000000e+00 9.097443e-03 294.11 -2.00 20.00 -2.00 320.30 0.00e+00 4.831 0.000 302.00 328.00 3 3.7074e+00 1.8071e-02 5.4110e-02 -6.0000e+00 4.8992e-01 1.1471e-01 2.3550e-02 2.7305e-02 -6.0000e+00 5.3073e-01 -1.6388e-01 2.0042e-02 1.5321e-02 -6.0000e+00 3.1805e-01 5.9912e-02 9.7860e-03 5.6158e-03 -6.0000e+00 1.3589e-01 6.4424e-05 -1.6764e-04 2.9221e-04 8.7893e-05 -6.0000e+00 9.1820e-03 5.1131e-03 0.0000e+00 12 9 8 11 16 0 63.00 23.66 0.70 0.00511 0.00385 29 5 1 5 0 1796.850 26.32 19.99 23.66 35.01 1.4 1047.50 -136360 -92503 -139820 -86390 -85707 -172004 -81780 -131695 -61887 -17908 -59686 -109289 -95683 -25064 -17136 -3863 -815 50286 -20009 -6484 59842 10994 -9030 29232 27132 51053 -20696 -37210 4986 -27961 -40809 4312 -12858 5533 -8354 -16081 7288 22655 2304 443 -1165 4647 10593 12142 938 6124 -706 346 -355 7929 12133 12661 10840 -1577 6446 8012 7000 -159 1417 4198 2759 1948 8545 5575 3226 2384 5530 -2921 -908 3907 -228 1893 182 2930 2446 3244 -6496 1253 -3768 -768 -3681 -1520 -1542 -2263 -251 161 662 -67 15 1649 50 950 -943 -1659 -1543 -2340 138 -1724 1026 399 976 -4015 -1197 -1408 -2523 -1588 -568 -347 504 530 447 836 5 313 206 -1172 -548 -759 -201 1254 -283 69 1794 749 725 146 954 -22 609 1299 -411 -24 -1035 588 259 606 -77 494 179 -633 -456 -487 -696 -2725 -1405 -3688 -1312 -1165 -5225 -1046 -3053 -791 -172 -885 -2859 -2670 -437 -344 -81 -18 745 -646 -192 939 278 -283 663 662 1024 -866 -1785 152 -1243 -2384 188 -762 294 -488 -982 381 1185 179 42 -125 503 1136 1324 116 737 -92 46 -48 1037 1661 1910 1805 -320 1270 1600 1447 -35 332 946 654 510 2361 1770 1096 784 1697 -983 -325 1533 -103 879 85 1276 985 1164 -2368 418 -1449 -337 -1928 -884 -977 -1526 -178 122 525 -55 12 1298 37 649 -620 -1108 -1134 -1986 131 -1904 1196 466 1064 -4170 -1115 -1337 -2631 -1738 -649 -422 658 765 707 1374 7 487 300 -1652 -773 -1128 -317 2056 -472 112 2764 1124 1041 203 1264 -31 934 2195 -764 -47 -2125 1253 594 1456 -191 1243 452 -1553 -1061 -1077 -1504 SS 20250411T000639.9Z 9232.004629 214 1 52.01 2 77.00 84.47 121.48 278.43 0.00 1 0.00 1 0 17 2.264e-01 1.186e-02 1.416e-01 6.884e-03 4.790587e-01 3.581792e-03 5.256710e-03 -6.000000e+00 1.291508e-01 229.28 -2.00 3.09 -2.00 320.71 0.00e+00 2.273855e-03 1.463132e-03 3.376231e-03 -6.000000e+00 5.957462e-03 294.11 -2.00 20.00 -2.00 319.90 0.00e+00 4.329 0.000 302.00 328.00 3 3.7641e+00 1.1769e-02 5.0600e-02 -6.0000e+00 3.2081e-01 8.6708e-02 1.4830e-02 3.1140e-02 -6.0000e+00 3.4755e-01 -1.1796e-01 1.2100e-02 1.2700e-02 -6.0000e+00 2.0827e-01 3.7103e-02 6.0835e-03 3.1150e-03 -6.0000e+00 8.8980e-02 1.0294e-04 -2.7420e-04 2.0543e-04 4.9033e-05 -6.0000e+00 6.0131e-03 5.6678e-03 0.0000e+00 12 9 8 11 16 0 98.74 23.67 0.33 0.00567 0.00361 32 5 1 5 0 1625.170 26.32 19.99 23.67 35.39 1.4 1049.76 -59976 -98465 -45936 -72074 -104306 -81541 -58578 -64529 13754 -50873 -20984 -102555 -28336 -53842 -24519 -10686 -20855 -6517 -18737 5291 15520 -22469 4970 -10170 -22669 19251 -12302 -1454 4901 -8948 -30562 -18251 8440 -23976 -4876 -5471 -5687 -6295 -3683 -2291 6840 13753 2261 4621 1295 3565 -3137 -5675 6219 7175 2432 4203 9897 7931 1987 -1307 6260 3369 -2162 4629 -1571 443 5748 4793 3514 3433 -845 2570 775 4554 392 1501 2262 -637 2440 348 -2353 -5203 -3065 -656 -1453 -1955 -949 -3333 -509 764 579 -795 3294 -104 -1066 186 -1914 -2198 -2171 -695 271 -1121 52 -484 -960 -2178 -1749 -1659 -1525 -1377 361 -528 398 713 1428 1409 143 8 -596 75 -440 190 -213 932 -116 1274 1026 234 55 425 113 233 310 -93 -401 -181 -421 -860 420 411 506 109 355 130 -328 -409 -1000 -805 -2259 -668 -1331 -2610 -1543 -930 -1221 134 -1025 -320 -3755 -588 -1774 -733 -326 -776 -227 -789 184 502 -1056 182 -465 -1259 740 -661 -67 203 -437 -2089 -1270 510 -2151 -345 -377 -427 -557 -387 -284 868 1737 335 685 200 601 -569 -1063 1052 1248 482 903 2173 1911 535 -376 1715 950 -629 1240 -461 139 1906 1776 1368 1277 -314 925 307 1997 199 788 1175 -326 1116 146 -929 -2071 -1294 -315 -812 -1240 -649 -2461 -392 623 499 -718 2864 -90 -868 138 -1366 -1573 -1698 -609 268 -1276 63 -588 -1100 -2297 -1700 -1644 -1640 -1566 425 -666 535 1051 2274 2332 237 12 -878 104 -618 279 -334 1528 -194 2040 1599 355 79 589 151 320 471 -156 -730 -344 -833 -1801 930 957 1208 266 868 308 -743 -881 -2117 SS 20250411T001206.6Z 9232.008410 217 1 51.69 2 75.69 84.76 122.75 278.84 0.00 1 0.00 1 0 17 1.498e-01 7.402e-03 7.282e-02 3.448e-03 4.443480e-01 1.765273e-03 4.533541e-03 -6.000000e+00 8.544159e-02 229.28 -2.00 3.09 -2.00 320.30 0.00e+00 1.644119e-03 6.477432e-04 1.147858e-03 -6.000000e+00 3.941273e-03 294.11 -2.00 20.00 -2.00 319.45 0.00e+00 3.957 0.000 302.00 328.00 3 3.2080e+00 5.4750e-03 4.4046e-02 -6.0000e+00 2.1224e-01 -7.8184e-04 6.8227e-03 2.1259e-02 -6.0000e+00 2.2993e-01 -1.3499e-02 5.6318e-03 1.0510e-02 -6.0000e+00 1.3779e-01 -4.2781e-03 2.8816e-03 2.9716e-03 -6.0000e+00 5.8865e-02 2.6918e-04 -2.1995e-04 1.0132e-04 3.4104e-05 -6.0000e+00 3.9781e-03 5.7964e-03 0.0000e+00 11 9 0 11 16 0 95.48 23.67 0.49 0.00580 0.00414 63 10 1 5 0 820.420 26.32 20.00 23.67 35.62 1.4 1051.02 -45581 -47094 -57393 -62421 -70791 -34737 -65857 -27227 24224 -19658 -47317 -31370 -34921 -29567 2123 -4796 3831 -1975 -7395 2468 -2845 -8365 -11805 -9036 -12931 2187 -8192 -14367 7082 -4938 8703 -6827 3390 -6279 -3205 -5676 -7359 -1191 4057 9401 -873 212 -831 -913 1275 -553 -2008 -208 2353 -2209 2693 -1503 1756 2655 2176 1847 662 1102 -1408 2647 -808 3085 2621 2834 2124 1202 -1059 -880 869 -195 1705 1027 1248 278 -144 -404 -2078 -1610 -1641 -1331 -2088 -336 -1841 -1969 -1264 319 479 962 1465 791 118 219 -508 -693 -668 -344 -88 693 659 170 -980 -1210 -833 -782 -1321 -1011 -737 -509 -118 609 1149 844 104 15 -228 -378 -288 296 -638 46 -12 575 885 455 710 -519 277 375 150 0 -114 -278 -380 -97 -113 290 166 647 170 23 -539 -439 -379 -613 -749 -1088 -1221 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