File name: Pandora227s1_NakhonPathom_20250920_L2Fit_fout2c3d20240531p1-8.txt File generation date: 20250920T172100.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Darunee Promchot Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 227 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora227_OF_v2d20220531.txt Instrument calibration file used: Pandora227s1_CF_v3d20240531.txt Level 1 file used: Pandora227s1_NakhonPathom_20250920_L1_smca1c3d20240531p1-8.txt Full location name: Silpakorn University, Sanam Chandra palace campus (Nakhon Pathom) Short location name: NakhonPathom Country of location: Thailand Location latitude [deg]: 13.8200 Location longitude [deg]: 100.0400 Location altitude [m]: 72 Local noon date: 20250920 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on lab session 1 First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0039 305.1450 305.2862 305.4272 305.5683 305.7094 305.8505 305.9915 306.1326 306.2736 306.4146 306.5556 306.6966 306.8376 306.9786 307.1195 307.2605 307.4014 307.5423 307.6833 307.8242 307.9651 308.1059 308.2468 308.3877 308.5285 308.6694 308.8102 308.9510 309.0918 309.2326 309.3734 309.5142 309.6549 309.7957 309.9364 310.0772 310.2179 310.3586 310.4993 310.6400 310.7806 310.9213 311.0620 311.2026 311.3432 311.4838 311.6244 311.7650 311.9056 312.0462 312.1868 312.3273 312.4678 312.6084 312.7489 312.8894 313.0299 313.1704 313.3108 313.4513 313.5918 313.7322 313.8726 314.0130 314.1534 314.2938 314.4342 314.5746 314.7149 314.8553 314.9956 315.1359 315.2763 315.4166 315.5569 315.6971 315.8374 315.9777 316.1179 316.2581 316.3984 316.5386 316.6788 316.8190 316.9591 317.0993 317.2395 317.3796 317.5197 317.6599 317.8000 317.9401 318.0802 318.2202 318.3603 318.5004 318.6404 318.7804 318.9204 319.0604 319.2004 319.3404 319.4804 319.6204 319.7603 319.9003 320.0402 320.1801 320.3200 320.4599 320.5998 320.7396 320.8795 321.0194 321.1592 321.2990 321.4388 321.5786 321.7184 321.8582 321.9980 322.1377 322.2775 322.4172 322.5569 322.6966 322.8363 322.9760 323.1157 323.2554 323.3950 323.5346 323.6743 323.8139 323.9535 324.0931 324.2327 324.3722 324.5118 324.6514 324.7909 324.9304 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250920T002731.6Z 9394.019116 102 1 51.80 2 71.75 93.49 52.16 87.90 0.00 1 0.00 1 0 17 5.142e-02 8.104e-03 4.420e-02 4.506e-03 3.574251e-01 2.242106e-03 3.784027e-03 -6.000000e+00 2.913799e-02 227.26 -2.00 3.09 -2.00 319.31 0.00e+00 7.992046e-04 6.002513e-04 1.101612e-03 -6.000000e+00 1.356809e-03 294.66 -2.00 20.00 -2.00 318.37 0.00e+00 3.151 0.000 302.00 328.00 3 4.2213e+00 6.3882e-03 3.5155e-02 -6.0000e+00 7.2019e-02 7.4076e-02 7.5591e-03 1.7471e-02 -6.0000e+00 7.8099e-02 -9.1050e-03 5.3793e-03 8.1631e-03 -6.0000e+00 4.6899e-02 -6.3546e-03 2.8394e-03 2.1600e-03 -6.0000e+00 2.0160e-02 2.2419e-04 2.6393e-04 1.3114e-04 2.4461e-05 -6.0000e+00 1.3645e-03 2.0539e-02 0.0000e+00 12 9 1 12 17 1 99.89 23.95 0.22 0.02054 0.02252 20 3 1 5 0 2466.460 26.51 20.01 23.95 36.06 2.1 1045.64 -8586 -18970 -5123 -20428 -2028 -8096 -33760 -16619 -12660 -11751 -2680 3344 11498 -4633 259 -12851 -795 -8859 10 -1930 3762 -1598 -3465 -7493 -171 2585 -4522 126 -4181 9101 4091 -1595 2198 252 -1677 -9872 -3891 -2330 2291 -309 -2584 2409 -364 124 359 -843 -272 -4150 -445 -1211 2518 1709 2762 1135 610 1751 1285 145 -3 862 1563 633 3537 2306 1197 357 -1316 493 524 1505 2256 1086 1496 -195 1381 -2233 -1276 -2251 -2086 -2313 -1140 -2039 -2599 -209 -1339 -183 -227 502 979 346 620 -88 -513 -2426 -571 -867 397 978 219 81 -741 -995 -1303 -204 -1032 -603 -215 -436 278 740 610 800 268 -53 41 -574 -555 264 201 629 212 962 224 514 675 57 -575 360 -77 88 -678 -881 -388 310 -32 151 255 495 232 241 84 -698 -589 -244 -682 -170 -767 -57 -226 -1281 -597 -496 -493 -104 126 455 -255 16 -1037 -61 -782 1 -176 334 -149 -335 -805 -18 282 -538 15 -489 924 473 -217 320 40 -256 -1575 -631 -433 492 -81 -776 728 -118 40 117 -281 -89 -1404 -145 -402 859 640 1095 487 275 801 605 69 -1 393 727 320 1912 1373 737 208 -730 264 298 967 1591 813 1117 -142 922 -1388 -711 -1212 -1182 -1500 -833 -1679 -2323 -192 -1326 -192 -252 571 1114 383 634 -83 -449 -2112 -522 -888 451 1238 300 110 -951 -1170 -1431 -227 -1257 -775 -287 -616 414 1077 951 1277 419 -86 61 -810 -782 385 314 1041 357 1579 360 790 986 81 -774 486 -113 140 -1160 -1566 -704 584 -58 290 502 993 467 472 157 -1390 -1143 SS 20250920T013312.6Z 9394.064729 144 1 51.74 2 55.89 98.27 36.55 92.11 0.00 1 0.00 1 0 17 1.084e-02 6.603e-03 3.947e-03 1.540e-03 2.081813e-01 7.695525e-04 2.204015e-03 -6.000000e+00 6.140762e-03 227.26 -2.00 3.09 -2.00 316.92 0.00e+00 4.937872e-04 1.042717e-04 1.911746e-04 -6.000000e+00 2.859461e-04 294.66 -2.00 20.00 -2.00 315.95 0.00e+00 1.778 0.000 302.00 328.00 3 4.2263e+00 2.0231e-03 1.9797e-02 -6.0000e+00 1.5178e-02 4.6562e-02 2.2821e-03 9.4047e-03 -6.0000e+00 1.6460e-02 1.8749e-05 1.3318e-03 4.5732e-03 -6.0000e+00 9.8841e-03 -7.0276e-03 6.4205e-04 1.2817e-03 -6.0000e+00 4.2483e-03 1.0618e-03 3.5127e-04 4.4306e-05 1.4501e-05 -6.0000e+00 2.8759e-04 2.1009e-02 0.0000e+00 11 9 0 11 16 0 99.98 23.95 0.27 0.02101 0.02365 77 13 1 5 0 671.900 26.51 20.01 23.95 38.10 2.0 1058.40 -2228 -558 -1277 -1284 -4995 -3399 -1447 -1783 -1571 -1680 -1418 -2410 -2545 -1023 715 -534 228 576 506 1581 1507 652 750 908 157 989 116 107 -770 -930 425 269 1874 -789 -2274 -2712 -2136 -1468 -402 56 -683 -97 -731 17 322 318 -130 -652 -889 -361 605 468 854 943 1049 892 770 615 -178 568 740 1302 1911 2015 397 -33 -631 -825 210 238 631 792 587 415 305 -35 -1290 -1951 -1197 -1248 -1337 -1107 -2032 -1627 -1125 -428 54 362 1096 370 365 -88 -658 -460 -368 32 161 763 246 -106 -692 -1108 -1052 -311 -883 -989 -559 -700 104 532 789 651 463 167 -241 -289 -153 15 348 386 75 666 698 437 550 -30 -32 510 253 245 -22 -282 -243 -93 170 13 79 479 8 51 -362 -615 -728 -303 -82 -195 -206 -730 -452 -195 -267 -263 -299 -249 -422 -486 -218 170 -141 62 160 146 465 454 196 226 286 52 339 40 35 -235 -273 127 86 632 -285 -780 -890 -746 -587 -190 31 -419 -62 -438 11 211 208 -83 -407 -539 -215 372 308 588 681 780 674 592 473 -135 425 566 1058 1518 1702 341 -26 -505 -634 167 195 565 742 554 379 261 -30 -995 -1415 -884 -1030 -1238 -1025 -2025 -1685 -1240 -503 66 462 1398 459 419 -92 -627 -459 -383 33 185 960 330 -140 -866 -1283 -1148 -348 -1085 -1287 -756 -990 152 823 1278 977 727 244 -322 -361 -190 19 482 573 114 1005 1027 617 734 -38 -39 612 324 334 -32 -414 -361 -143 276 22 139 860 15 90 -622 -1025 -1188 SS 20250920T014737.4Z 9394.074739 151 1 25.07 2 52.44 99.53 33.12 93.28 0.00 1 0.00 1 0 17 9.475e-03 6.728e-03 1.067e-03 6.029e-04 1.922268e-01 3.034891e-04 2.036958e-03 -6.000000e+00 5.368978e-03 227.26 -2.00 3.09 -2.00 315.72 0.00e+00 4.738621e-04 3.167569e-05 8.731749e-05 -6.000000e+00 2.500073e-04 294.66 -2.00 20.00 -2.00 314.87 0.00e+00 1.636 0.000 302.00 328.00 3 2.4451e+00 7.8215e-04 1.8217e-02 -6.0000e+00 1.3270e-02 3.7072e-02 8.7507e-04 8.6418e-03 -6.0000e+00 1.4391e-02 -1.4986e-03 5.0281e-04 4.2057e-03 -6.0000e+00 8.6419e-03 -4.8485e-03 2.3115e-04 1.1846e-03 -6.0000e+00 3.7144e-03 7.4748e-03 3.0222e-04 1.6849e-05 1.4347e-05 -6.0000e+00 2.5144e-04 2.0907e-02 0.0000e+00 12 9 1 12 17 1 97.18 23.96 0.32 0.02091 0.02318 131 44 1 5 0 189.880 26.51 20.00 23.96 38.49 2.0 1061.12 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