File name: Pandora69s1_NewBrunswickNJ_20191020_L2Fit_fwvt1c1d20190909p1-8.txt File generation date: 20250604T122723.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 69 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora69_OF_v1d20190730.txt Instrument calibration file used: Pandora69s1_CF_v1d20190909.txt Level 1 file used: Pandora69s1_NewBrunswickNJ_20191020_L1_smca1c1d20190909p1-8.txt Full location name: Rutgers NJDEP (USEPA AQS ID 34-023-0011) Short location name: NewBrunswickNJ Country of location: USA Location latitude [deg]: 40.4622 Location longitude [deg]: -74.4294 Location altitude [m]: 19 Local noon date: 20191020 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1681 1831 Nominal wavelengths inside fitting window [nm]: 492.1050 492.2262 492.3473 492.4683 492.5894 492.7104 492.8315 492.9525 493.0735 493.1944 493.3154 493.4363 493.5572 493.6781 493.7990 493.9199 494.0407 494.1615 494.2823 494.4031 494.5238 494.6446 494.7653 494.8860 495.0067 495.1273 495.2480 495.3686 495.4892 495.6098 495.7303 495.8509 495.9714 496.0919 496.2124 496.3328 496.4533 496.5737 496.6941 496.8145 496.9348 497.0551 497.1754 497.2957 497.4160 497.5362 497.6565 497.7767 497.8968 498.0170 498.1371 498.2572 498.3773 498.4974 498.6174 498.7374 498.8574 498.9774 499.0973 499.2172 499.3371 499.4570 499.5768 499.6967 499.8165 499.9362 500.0560 500.1757 500.2954 500.4151 500.5347 500.6543 500.7739 500.8935 501.0130 501.1325 501.2520 501.3714 501.4908 501.6102 501.7296 501.8489 501.9682 502.0875 502.2068 502.3260 502.4452 502.5643 502.6834 502.8025 502.9216 503.0406 503.1596 503.2786 503.3975 503.5164 503.6353 503.7541 503.8729 503.9916 504.1104 504.2290 504.3477 504.4663 504.5849 504.7034 504.8219 504.9404 505.0588 505.1772 505.2955 505.4138 505.5321 505.6503 505.7685 505.8867 506.0048 506.1228 506.2408 506.3588 506.4767 506.5946 506.7124 506.8302 506.9479 507.0656 507.1833 507.3009 507.4184 507.5359 507.6533 507.7707 507.8881 508.0054 508.1226 508.2398 508.3569 508.4740 508.5910 508.7079 508.8248 508.9417 509.0585 509.1752 509.2919 509.4085 509.5250 509.6415 509.7579 509.8743 509.9905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191020T111937.0Z 7232.471956 223 1 20.01 2 89.77 103.83 24.33 228.86 0.00 1 0.00 1 0 22 6.970e-02 6.807e-02 6.050e-02 5.970e-02 1.132655e+04 4.582229e+03 5.094533e+02 -6.000000e+00 4.199515e+03 283.98 -2.00 20.00 -2.00 505.36 0.00e+00 1.136018e-03 1.728393e-03 8.650287e-05 -6.000000e+00 2.028117e-03 283.98 -2.00 20.00 -2.00 500.52 0.00e+00 2.413602e+00 1.232557e+00 1.191451e-01 -6.000000e+00 1.425979e+00 225.59 -2.00 3.50 -2.00 502.11 0.00e+00 20.114 0.149 489.00 513.00 1 9.2359e+00 9.5104e-02 3.7143e-02 -6.0000e+00 1.1005e-01 4.1076e-02 2.3402e-02 3.0605e-03 -6.0000e+00 2.7700e-02 8.7438e-06 -2.1963e-02 7.2158e-03 3.6958e-05 -6.0000e+00 9.2119e-03 -8.9871e-03 6.3477e-04 12 8 8 10 0 0 59.24 22.77 6.74 -0.00899 -0.16133 5 5 1 4 0 4000.000 25.90 20.00 22.77 13.29 20.4 1016.00 -15011 16492 -478 -2506 -262 679 -11766 -5966 10175 5927 5671 830 1983 10315 8247 -14940 15956 -6202 3143 -112 -7637 -321 -3274 4432 -10590 4495 -1056 8932 2076 7351 5571 -2662 7262 -6394 758 -1204 2275 3463 894 8680 1597 5570 -1025 15941 -5303 22 -1557 -8063 -6314 -2029 5746 -6823 3023 1683 9385 10309 -3206 -2260 877 14243 920 -654 -7961 -3868 -6757 -570 6922 5999 3291 -163 6799 -11911 17180 2308 8203 -14366 1672 -2132 -1687 -2718 -7120 5285 -5509 -3541 3445 -1143 8244 -7118 7760 6430 -767 -5063 -317 -5623 1841 15481 -4591 7211 -6546 -9608 -7528 -5344 8414 -2073 1372 8150 2154 -3660 1260 -5224 2685 -6896 2080 742 5810 9084 1590 -5478 719 12466 -11655 7482 -3159 3834 9572 14548 -1193 3869 7065 1155 -2195 -7628 13958 5298 11383 2007 706 -673 874 4162 -9068 3105 -7183 -3539 -10727 -4515 8060 -5207 2498 -1246 900000 -16167 13267 -461 -2523 -265 695 -13802 -6680 9773 5878 5579 846 1977 9426 7650 -17307 13955 -6804 3208 -119 -8814 -346 -3649 4603 -12695 4671 -1151 8763 2136 7067 5383 -2775 6968 -7122 803 -1311 2400 3595 945 8470 1665 5614 -1106 14771 -6049 24 -1711 -9319 -7049 -2129 5480 -7194 2878 1626 8557 9498 -3419 -2416 914 13100 960 -693 -9059 -4217 -7516 -591 6604 5695 3162 -160 6213 -12979 14277 2220 7480 -16144 1597 -2084 -1624 -2625 -7154 4735 -5489 -3487 3203 -1116 7394 -7374 6977 5859 -751 -5181 -311 -5757 1732 12519 -4368 5978 -6052 -9035 -6944 -4895 6947 -1952 1285 7275 2044 -3655 1199 -5297 2548 -7230 2020 733 5494 8375 1583 -5860 728 11213 -13012 6873 -3184 3601 8505 12354 -1177 3651 6472 1115 -2175 -7894 11674 4777 9696 1884 681 -668 867 4057 -10142 3125 -8016 -3828 -12432 -4913 7720 -5588 2463 -1262 900000 SO 20191020T112121.0Z 7232.473160 225 1 20.01 2 89.45 104.11 24.57 229.60 0.00 1 0.00 1 0 15 5.678e-02 5.612e-02 5.141e-02 5.087e-02 1.222422e+04 3.988383e+03 9.858687e+02 -6.000000e+00 3.418596e+03 283.98 -2.00 20.00 -2.00 505.26 0.00e+00 1.639702e-03 1.458300e-03 2.673159e-05 -6.000000e+00 1.664457e-03 283.98 -2.00 20.00 -2.00 500.21 0.00e+00 -1.449042e-01 1.063744e+00 3.147687e-02 -6.000000e+00 1.184943e+00 225.59 -2.00 3.50 -2.00 501.82 0.00e+00 19.586 0.138 489.00 513.00 1 9.3254e+00 8.1586e-02 3.4425e-02 -6.0000e+00 9.0926e-02 1.0473e-01 2.0580e-02 2.2841e-03 -6.0000e+00 2.3732e-02 1.0336e-05 2.0362e-02 6.0939e-03 9.6194e-05 -6.0000e+00 7.5150e-03 1.3103e-02 -2.0424e-03 12 9 8 11 8 0 -215.76 22.77 4.51 0.01310 0.15434 5 5 1 4 0 4000.000 25.90 20.00 22.77 13.61 20.1 1016.19 900000 900000 -681 -5794 -5741 6676 8375 -5856 -442 -5338 3647 -7224 9623 -966 8829 21 12580 918 287 10752 1304 3757 -9856 1541 -570 -2442 3944 -4587 478 1432 4940 4431 -293 -819 4922 7019 -3509 -6118 -6139 -2991 -7702 6774 -84 856 -5085 7375 946 -11324 953 -715 5722 -2106 12810 -9944 924 -1510 -4316 -2532 6287 4357 2016 10155 185 5690 -9853 2069 -7250 -3219 2426 3049 -1526 -7180 17598 -3845 10678 1477 7129 1773 -1394 2067 -6049 -2312 -9977 8270 -1586 9406 1816 2430 -5578 2641 5985 1534 6552 -4984 1097 -2195 -1663 3577 1186 8898 -7961 5201 5526 -4328 -1769 -186 -1027 -2847 5347 -6269 6527 -11765 797 -4483 8412 -5838 -2824 2115 88 6184 1411 -394 4231 4026 -378 2867 -2845 -1828 2816 -7354 -247 -4439 4540 1705 2765 -4113 2048 1549 -2480 6836 -10640 3401 -2290 8926 -4601 4402 3153 -8946 6042 -3097 11698 900000 900000 -664 -6060 -6154 6514 8202 -6634 -477 -6000 3730 -8097 9085 -997 8228 22 11346 937 300 10309 1379 3897 -11667 1640 -620 -2706 4105 -5136 502 1466 4807 4286 -297 -848 4922 6981 -3880 -6923 -6903 -3241 -8695 6674 -89 903 -5722 7420 1013 -13509 998 -747 5507 -2136 11116 -10634 898 -1529 -4583 -2687 6196 4387 2079 9709 195 5682 -11354 2112 -8001 -3375 2378 2936 -1521 -7515 14591 -3924 9554 1443 6567 1699 -1360 1933 -6075 -2241 -10420 7315 -1553 8365 1746 2326 -5757 2521 5537 1486 6071 -5155 1064 -2161 -1589 3162 1046 7158 -7437 4298 4626 -4092 -1685 -179 -1010 -2854 4947 -6467 5992 -12931 785 -4663 7772 -6197 -2927 2105 90 5948 1407 -394 4000 3772 -366 2694 -2825 -1802 2658 -7621 -238 -4423 4113 1569 2501 -3971 1880 1446 -2438 6233 -11591 3277 -2345 8258 -4849 4252 3063 -9650 5579 -3072 10010 SO 20191020T112303.0Z 7232.474340 227 1 20.00 2 89.13 104.39 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