File name: Pandora69s1_NewBrunswickNJ_20200804_L2Fit_fout2c1d20200727p1-8.txt File generation date: 20250604T165207.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 69 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora69_OF_v3d20190730.txt Instrument calibration file used: Pandora69s1_CF_v1d20200727.txt Level 1 file used: Pandora69s1_NewBrunswickNJ_20200804_L1_smca1c1d20200727p1-8.txt Full location name: Rutgers NJDEP (USEPA AQS ID 34-023-0011) Short location name: NewBrunswickNJ Country of location: USA Location latitude [deg]: 40.4622 Location longitude [deg]: -74.4294 Location altitude [m]: 19 Local noon date: 20200804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 259 400 Nominal wavelengths inside fitting window [nm]: 305.1058 305.2474 305.3889 305.5305 305.6719 305.8134 305.9548 306.0962 306.2376 306.3789 306.5202 306.6615 306.8027 306.9440 307.0852 307.2263 307.3675 307.5086 307.6497 307.7907 307.9318 308.0728 308.2138 308.3548 308.4957 308.6366 308.7775 308.9184 309.0593 309.2001 309.3409 309.4817 309.6224 309.7632 309.9039 310.0446 310.1853 310.3260 310.4666 310.6072 310.7478 310.8884 311.0290 311.1695 311.3100 311.4505 311.5910 311.7315 311.8719 312.0124 312.1528 312.2932 312.4336 312.5739 312.7143 312.8546 312.9949 313.1352 313.2755 313.4158 313.5560 313.6962 313.8364 313.9766 314.1168 314.2570 314.3971 314.5373 314.6774 314.8175 314.9576 315.0977 315.2377 315.3778 315.5178 315.6578 315.7978 315.9378 316.0778 316.2178 316.3577 316.4976 316.6375 316.7774 316.9173 317.0572 317.1971 317.3369 317.4768 317.6166 317.7564 317.8962 318.0360 318.1757 318.3155 318.4552 318.5950 318.7347 318.8744 319.0141 319.1537 319.2934 319.4331 319.5727 319.7123 319.8519 319.9915 320.1311 320.2707 320.4103 320.5498 320.6893 320.8289 320.9684 321.1079 321.2474 321.3868 321.5263 321.6657 321.8052 321.9446 322.0840 322.2234 322.3628 322.5022 322.6416 322.7809 322.9203 323.0596 323.1989 323.3382 323.4775 323.6168 323.7560 323.8953 324.0345 324.1738 324.3130 324.4522 324.5914 324.7306 324.8698 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200804T194212.9Z 7521.820983 4 1 51.82 2 41.42 247.19 148.61 49.22 0.00 1 0.00 1 0 17 7.104e-03 6.082e-03 1.619e-04 9.863e-05 1.673980e-01 5.231653e-05 2.046722e-03 -6.000000e+00 4.234737e-03 232.13 -2.00 3.50 -2.00 315.46 0.00e+00 9.231711e-05 4.373073e-06 1.862223e-05 -6.000000e+00 1.660780e-04 290.28 -2.00 20.00 -2.00 315.16 0.00e+00 1.332 0.000 302.00 328.00 3 -1.0804e-01 1.3644e-04 1.6000e-02 -6.0000e+00 1.0713e-02 1.1506e-02 1.5059e-04 8.7877e-03 -6.0000e+00 1.1591e-02 -1.6883e-03 8.6168e-05 4.2843e-03 -6.0000e+00 6.7877e-03 -2.1185e-03 3.8304e-05 1.1946e-03 -6.0000e+00 2.8417e-03 1.3362e-01 -1.2284e-05 2.9284e-06 1.6315e-05 -6.0000e+00 2.0190e-04 -1.4140e-02 2.0794e-05 12 1 1 12 512 512 97.03 25.46 0.29 -0.01414 -0.01423 3563 719 1 5 0 13.830 27.67 19.68 25.46 27.27 13.1 976.01 -1859 -889 -555 -640 -324 -726 -274 92 212 -281 -94 -301 -927 -469 -207 -381 249 410 710 851 455 1081 988 599 577 545 367 558 896 1330 1151 1513 622 -1408 -1067 -1150 -1582 -722 -743 -1093 -1143 -697 -982 -674 -383 -683 -643 -420 -512 534 566 546 927 711 769 1072 500 449 611 873 1124 1218 1205 478 -468 22 -140 492 1097 224 70 -16 7 47 -83 -5 -47 158 204 -734 -953 -1593 -1828 -950 -824 -708 -249 22 10 58 330 127 578 1120 746 528 835 243 -410 -406 -491 -501 415 207 -1079 -748 -698 -631 62 66 -63 -215 -53 -125 329 698 502 471 203 -388 -325 80 39 449 797 339 1154 1342 430 369 -55 -86 169 408 -90 -296 137 -154 -493 -259 -375 -572 -539 -270 -167 -175 -78 -173 -69 25 64 -88 -28 -94 -319 -178 -80 -156 103 174 308 378 204 477 450 285 284 275 181 253 409 601 496 681 298 -679 -477 -524 -806 -424 -478 -803 -893 -559 -806 -551 -310 -546 -497 -312 -369 383 427 433 766 613 627 882 418 371 536 770 959 1111 1174 483 -455 19 -124 428 950 219 73 -16 8 48 -78 -4 -39 126 173 -648 -932 -1703 -1925 -1046 -975 -892 -306 27 13 73 380 143 594 1122 795 577 1004 299 -520 -496 -603 -575 460 244 -1388 -944 -921 -868 89 92 -91 -309 -77 -166 424 853 622 616 270 -548 -466 113 54 585 1044 424 1377 1627 554 499 -72 -116 231 579 -136 -440 209 -240 -768 -393 -553 -876 SU 20200804T194336.5Z 7521.821951 6 1 5.07 2 41.67 247.53 148.41 49.70 0.00 1 0.00 1 0 17 7.004e-03 6.207e-03 4.352e-04 3.135e-04 1.681919e-01 1.674749e-04 2.063066e-03 -6.000000e+00 4.174679e-03 232.13 -2.00 3.50 -2.00 314.68 0.00e+00 1.331835e-04 1.206084e-05 1.393654e-05 -6.000000e+00 1.637480e-04 290.28 -2.00 20.00 -2.00 314.43 0.00e+00 1.337 0.000 302.00 328.00 3 1.7846e-01 4.3381e-04 1.6060e-02 -6.0000e+00 1.0561e-02 1.3007e-02 4.7784e-04 8.8155e-03 -6.0000e+00 1.1427e-02 -2.0965e-03 2.7235e-04 4.2973e-03 -6.0000e+00 6.6916e-03 -1.5033e-03 1.1827e-04 1.1967e-03 -6.0000e+00 2.8011e-03 9.9606e-02 -6.0285e-05 9.1957e-06 1.7248e-05 -6.0000e+00 1.9907e-04 -1.3305e-02 1.2780e-05 12 1 1 12 513 513 99.56 25.28 0.28 -0.01330 -0.01376 241 508 1 5 0 19.660 27.67 19.92 25.28 27.81 13.0 978.58 -1640 -885 -397 -552 54 -691 -255 155 204 -188 -240 -205 -1009 -425 -225 -295 263 521 651 837 505 1019 1039 596 541 432 351 547 816 1341 1219 1551 519 -1266 -1052 -1140 -1568 -733 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967 387 1439 1561 539 433 -91 -110 195 588 -107 -441 136 -239 -762 -410 -538 -868 SU 20200804T194521.5Z 7521.823166 8 1 3.02 2 41.98 247.95 148.17 50.30 0.00 1 0.00 1 0 17 7.248e-03 6.333e-03 1.049e-03 7.674e-04 1.697807e-01 4.101312e-04 2.082447e-03 -6.000000e+00 4.319727e-03 232.13 -2.00 3.50 -2.00 314.61 0.00e+00 1.752088e-04 2.912765e-05 1.379631e-05 -6.000000e+00 1.694439e-04 290.28 -2.00 20.00 -2.00 314.36 0.00e+00 1.344 0.000 302.00 328.00 3 1.4354e+00 1.0616e-03 1.6160e-02 -6.0000e+00 1.0928e-02 1.8543e-02 1.1685e-03 8.8983e-03 -6.0000e+00 1.1825e-02 -2.5289e-03 6.6628e-04 4.3375e-03 -6.0000e+00 6.9242e-03 -1.1351e-03 2.8885e-04 1.2063e-03 -6.0000e+00 2.8982e-03 2.8006e-02 1.2583e-05 2.2531e-05 1.7344e-05 -6.0000e+00 2.0600e-04 -1.2710e-02 2.2014e-05 12 1 1 12 513 513 97.24 24.96 0.29 -0.01271 -0.01262 39 142 1 5 0 71.000 27.45 19.95 24.96 28.90 12.8 982.03 -1780 -825 -242 -277 141 -815 19 126 365 -256 -354 -357 -1158 -597 0 -294 35 683 584 1044 593 1109 936 811 748 658 245 594 777 1113 1041 1474 499 -1396 -1242 -1418 -1704 -945 -993 -998 -1122 -766 -1110 -822 -389 -657 -588 -559 -657 562 642 667 809 744 755 1172 514 355 715 967 1249 1303 1147 421 -358 -32 -164 497 1069 170 215 56 -66 -44 -124 -24 -314 106 -81 -619 -966 -1563 -1972 -1048 -737 -762 -263 113 11 -35 277 -34 524 1088 553 522 883 286 -332 -329 -562 -453 343 199 -1119 -733 -601 -574 181 110 47 -152 27 -110 311 733 397 384 195 -336 -311 66 8 315 727 316 1114 1299 522 419 -197 -56 116 315 -80 -322 93 -90 -435 -174 -451 -683 -680 -330 -95 -99 48 -274 7 46 145 -105 -142 -147 -495 -282 0 -153 18 367 323 557 318 623 513 464 442 398 145 323 414 589 573 847 289 -810 -709 -782 -1050 -636 -718 -783 -936 -628 -932 -687 -321 -561 -485 -444 -531 451 517 565 685 656 678 1062 473 324 640 871 1123 1255 1134 431 -352 -30 -149 442 979 168 220 59 -69 -46 -123 -22 -280 90 -71 -577 -960 -1631 -2174 -1163 -846 -900 -323 142 13 -43 320 -37 546 1106 577 575 1031 353 -421 -401 -669 -522 383 236 -1349 -924 -764 -762 241 149 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