File name: Pandora69s1_NewBrunswickNJ_20200830_L2Fit_fout2c1d20200727p1-8.txt File generation date: 20250604T171652.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 69 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora69_OF_v3d20190730.txt Instrument calibration file used: Pandora69s1_CF_v1d20200727.txt Level 1 file used: Pandora69s1_NewBrunswickNJ_20200830_L1_smca1c1d20200727p1-8.txt Full location name: Rutgers NJDEP (USEPA AQS ID 34-023-0011) Short location name: NewBrunswickNJ Country of location: USA Location latitude [deg]: 40.4622 Location longitude [deg]: -74.4294 Location altitude [m]: 19 Local noon date: 20200830 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 259 400 Nominal wavelengths inside fitting window [nm]: 305.1058 305.2474 305.3889 305.5305 305.6719 305.8134 305.9548 306.0962 306.2376 306.3789 306.5202 306.6615 306.8027 306.9440 307.0852 307.2263 307.3675 307.5086 307.6497 307.7907 307.9318 308.0728 308.2138 308.3548 308.4957 308.6366 308.7775 308.9184 309.0593 309.2001 309.3409 309.4817 309.6224 309.7632 309.9039 310.0446 310.1853 310.3260 310.4666 310.6072 310.7478 310.8884 311.0290 311.1695 311.3100 311.4505 311.5910 311.7315 311.8719 312.0124 312.1528 312.2932 312.4336 312.5739 312.7143 312.8546 312.9949 313.1352 313.2755 313.4158 313.5560 313.6962 313.8364 313.9766 314.1168 314.2570 314.3971 314.5373 314.6774 314.8175 314.9576 315.0977 315.2377 315.3778 315.5178 315.6578 315.7978 315.9378 316.0778 316.2178 316.3577 316.4976 316.6375 316.7774 316.9173 317.0572 317.1971 317.3369 317.4768 317.6166 317.7564 317.8962 318.0360 318.1757 318.3155 318.4552 318.5950 318.7347 318.8744 319.0141 319.1537 319.2934 319.4331 319.5727 319.7123 319.8519 319.9915 320.1311 320.2707 320.4103 320.5498 320.6893 320.8289 320.9684 321.1079 321.2474 321.3868 321.5263 321.6657 321.8052 321.9446 322.0840 322.2234 322.3628 322.5022 322.6416 322.7809 322.9203 323.0596 323.1989 323.3382 323.4775 323.6168 323.7560 323.8953 324.0345 324.1738 324.3130 324.4522 324.5914 324.7306 324.8698 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200830T110008.8Z 7547.458435 233 1 49.53 2 83.98 83.63 128.00 271.81 0.00 1 0.00 1 0 17 5.552e-01 2.792e-02 3.816e-01 1.752e-02 8.921820e-01 1.094711e-02 9.553816e-03 -6.000000e+00 3.402373e-01 230.50 -2.00 3.50 -2.00 322.31 0.00e+00 9.710171e-03 4.795109e-03 1.309975e-03 -6.000000e+00 1.455697e-02 289.35 -2.00 20.00 -2.00 321.97 0.00e+00 8.503 0.011 302.00 328.00 3 1.8585e-01 3.6576e-02 9.8364e-02 -6.0000e+00 8.6070e-01 1.2109e+00 4.5208e-02 4.8285e-02 -6.0000e+00 9.3959e-01 -1.6307e+00 4.2911e-02 2.5830e-02 -6.0000e+00 5.4585e-01 6.6895e-01 2.2024e-02 8.9143e-03 -6.0000e+00 2.2872e-01 3.7163e-05 -9.7831e-04 5.6835e-04 1.3990e-04 -6.0000e+00 1.6452e-02 -6.2761e-06 2.3384e-04 12 8 8 10 0 0 91.46 22.73 0.74 -0.00001 -0.00736 43 9 1 5 0 1151.700 25.90 20.00 22.73 24.28 13.8 964.26 900000 -93354 900000 -102243 900000 87531 900000 -21775 -40340 -44122 -88310 900000 -67127 900000 -39296 900000 -8152 900000 179588 -14991 306816 119766 900000 -51669 900000 -33058 34913 81554 57033 900000 -25376 900000 27526 900000 -57426 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-1254 987 1356 -1292 2681 -2715 3615 -869 3185 -212 1012 1596 -1387 2902 -1805 1981 -3606 1573 -3563 -1392 -3420 1958 -13 -2609 1313 -4182 1195 -6216 1078 -2285 728 -625 -5744 -3491 -5663 2946 -7144 1136 -2621 844 -2094 1101 3563 2191 3826 -95 3659 1944 5992 -829 3071 519 1740 1985 2011 1640 -756 2679 -4978 5673 -1021 41 -1023 -963 -506 -5301 SU 20200830T110159.0Z 7547.459710 235 1 49.92 2 83.64 83.93 128.34 272.11 0.00 1 0.00 1 0 17 5.841e-01 2.217e-02 3.983e-01 1.325e-02 8.828372e-01 8.059863e-03 9.401523e-03 -6.000000e+00 3.529242e-01 230.50 -2.00 3.50 -2.00 322.24 0.00e+00 7.647888e-03 3.594608e-03 1.331848e-03 -6.000000e+00 1.496459e-02 289.35 -2.00 20.00 -2.00 321.89 0.00e+00 8.130 0.010 302.00 328.00 3 1.5474e-01 2.7031e-02 9.4910e-02 -6.0000e+00 8.9143e-01 8.9941e-01 3.8220e-02 4.9125e-02 -6.0000e+00 9.6968e-01 -1.1507e+00 4.2121e-02 2.7676e-02 -6.0000e+00 5.6394e-01 4.5926e-01 2.0394e-02 9.7202e-03 -6.0000e+00 2.3654e-01 5.6932e-05 -3.0964e-04 4.1898e-04 1.4254e-04 -6.0000e+00 1.7245e-02 -1.9728e-03 3.3427e-04 12 9 8 11 8 0 4.10 22.73 0.59 -0.00197 -0.00430 63 13 1 5 0 792.230 25.90 20.00 22.73 24.34 13.8 965.16 900000 -16535 -66966 -206139 -139483 -197687 900000 -73238 900000 -100829 -77955 90026 -122604 900000 -78520 140954 -22368 900000 271781 -11849 900000 -41701 103338 -76754 900000 -106253 900000 -80637 31375 900000 -18493 137326 -32303 46221 -21119 900000 193408 116365 64006 82990 55692 26055 121956 54 76041 10801 49268 19117 11839 61826 25911 86414 29937 64499 7166 37193 26396 15410 5021 -1771 19438 -10552 39686 16210 29950 8685 19711 26591 -1755 17377 13611 19850 11982 11625 7014 17288 -17427 -2656 -4070 -989 -1741 1648 927 -1196 8294 553 5706 1753 3546 -587 2942 721 -1156 -6410 -6609 1258 -2265 504 -248 -2088 222 -5773 1112 -3967 -2793 -1960 -3701 -2599 -2019 -1606 -3721 -223 -814 725 -1334 1051 593 220 364 -160 1525 323 2741 413 3679 1294 3164 753 404 1279 933 498 95 269 -677 171 30 291 -754 -342 32 -1507 900000 -213 -864 -7976 -2399 -5736 900000 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-2.00 20.00 -2.00 321.86 0.00e+00 7.784 0.009 302.00 328.00 3 1.6241e-01 2.0523e-02 9.1356e-02 -6.0000e+00 7.2897e-01 7.7495e-01 2.8900e-02 4.8275e-02 -6.0000e+00 7.8991e-01 -9.8618e-01 3.2146e-02 2.7462e-02 -6.0000e+00 4.6316e-01 3.9390e-01 1.5650e-02 9.6806e-03 -6.0000e+00 1.9434e-01 8.1304e-05 -6.8160e-05 3.2461e-04 1.3924e-04 -6.0000e+00 1.3879e-02 -1.3244e-03 2.8598e-04 12 8 8 10 0 0 5.26 22.73 0.46 -0.00132 -0.00184 77 16 1 5 0 651.800 25.90 19.97 22.73 24.41 13.9 966.24 -135146 76822 -146955 -151722 -152800 51395 -213523 -51115 -96941 -200920 30113 -136243 -123853 -37345 -30308 -111507 -76575 -75155 -80372 -44983 49752 -37930 -29896 -15397 -76995 6201 3954 -39283 1338 -29318 32428 32452 62126 14573 -18810 46134 89225 -14774 18110 60419 40854 37977 20816 67203 12482 44588 29578 23120 37596 39674 46318 7590 53758 7207 37235 34002 3850 19376 11104 13874 6367 18268 4114 30118 5062 13340 4014 14399 16132 12420 8794 8745 5304 1232 4197 4935 3475 7618 -3754 1121 1795 483 -1383 -1889 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