File name: Pandora64s1_NewHavenCT_20191029_L2Fit_fwvt1c4d20190911p1-8.txt File generation date: 20260321T220051.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v2d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20191029_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20191029 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 1670 1819 Nominal wavelengths inside fitting window [nm]: 492.0778 492.1987 492.3196 492.4405 492.5613 492.6822 492.8030 492.9238 493.0446 493.1654 493.2861 493.4069 493.5276 493.6483 493.7690 493.8897 494.0104 494.1310 494.2516 494.3722 494.4928 494.6134 494.7340 494.8545 494.9751 495.0956 495.2161 495.3365 495.4570 495.5774 495.6979 495.8183 495.9387 496.0591 496.1794 496.2998 496.4201 496.5404 496.6607 496.7810 496.9012 497.0215 497.1417 497.2619 497.3821 497.5023 497.6225 497.7426 497.8627 497.9829 498.1029 498.2230 498.3431 498.4631 498.5832 498.7032 498.8232 498.9431 499.0631 499.1830 499.3030 499.4229 499.5428 499.6627 499.7825 499.9024 500.0222 500.1420 500.2618 500.3816 500.5013 500.6211 500.7408 500.8605 500.9802 501.0999 501.2195 501.3392 501.4588 501.5784 501.6980 501.8176 501.9371 502.0567 502.1762 502.2957 502.4152 502.5347 502.6541 502.7736 502.8930 503.0124 503.1318 503.2512 503.3705 503.4899 503.6092 503.7285 503.8478 503.9670 504.0863 504.2055 504.3247 504.4439 504.5631 504.6823 504.8015 504.9206 505.0397 505.1588 505.2779 505.3970 505.5160 505.6350 505.7541 505.8731 505.9920 506.1110 506.2299 506.3489 506.4678 506.5867 506.7056 506.8244 506.9433 507.0621 507.1809 507.2997 507.4185 507.5372 507.6560 507.7747 507.8934 508.0121 508.1308 508.2494 508.3681 508.4867 508.6053 508.7239 508.8425 508.9610 509.0796 509.1981 509.3166 509.4351 509.5535 509.6720 509.7904 509.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191029T112518.0Z 7241.475903 464 1 32.01 2 89.74 108.26 105.55 97.42 0.00 1 0.00 1 0 15 1.042e-01 9.749e-02 5.696e-02 5.569e-02 2.727678e+03 3.480648e+03 1.314372e+02 -6.000000e+00 5.909412e+03 282.31 -2.00 20.00 -2.00 505.22 0.00e+00 5.804681e-03 1.546678e-03 2.228382e-04 -6.000000e+00 2.950711e-03 282.31 -2.00 20.00 -2.00 500.33 0.00e+00 -1.760594e+00 1.127944e+00 8.114303e-02 -6.000000e+00 2.078362e+00 224.66 -2.00 3.52 -2.00 501.92 0.00e+00 20.124 0.152 489.00 513.00 1 1.0257e+01 8.6266e-02 3.7076e-02 -6.0000e+00 1.5960e-01 1.9979e-01 2.2559e-02 2.2816e-03 -6.0000e+00 4.1077e-02 4.0341e-06 -1.2163e-02 5.6834e-03 8.9528e-05 -6.0000e+00 1.0911e-02 7.4093e-02 -2.1771e-04 12 8 8 10 0 0 14.32 20.71 -1.19 0.07409 -0.01027 8 2 1 4 0 4000.000 25.90 20.00 20.71 17.15 22.9 958.03 6106 18797 -17581 -6676 1900 4943 -5606 3940 -14060 4531 8034 6115 -15330 1560 2629 -3448 -8642 5823 -13 23692 -5383 -10020 6886 154 -10600 16596 5768 -6253 3129 10292 3327 14429 30151 -4728 2812 3874 -3299 -1694 -3746 -7991 -861 11295 1180 -7091 1311 -2136 -1157 870 3051 5269 11078 -7268 -7694 -15980 6811 17352 13686 -14668 -3233 13416 -400 5910 9270 8177 6750 -1408 6805 2189 15481 4892 -12181 8991 -7714 -1383 -2660 -3832 -18311 -8758 -941 310 6461 10002 7151 5456 1903 4795 16084 -6882 5538 4907 -9014 7067 -1000 -1166 -9438 13599 -7120 8962 -10057 9901 -4008 3945 -5017 12058 3612 -3555 -981 5382 -12114 -6385 3239 5243 25371 -874 -16 2706 13488 6226 -2188 527 -529 3352 -11823 1864 230 -273 -23752 15672 8409 8091 -7469 8160 19436 2042 -9544 15723 -16309 32856 -7472 2643 -22229 6804 5617 -9325 -11201 9367 -7738 -1921 38359 12927 5581 15257 -21065 -7437 1992 5113 -6564 4228 -17307 4759 8000 6131 -17967 1582 2618 -3653 -9336 5758 -14 20307 -5922 -11569 6998 161 -12423 15470 5728 -6947 3100 9547 3245 12630 22758 -4994 2848 3923 -3565 -1785 -3999 -8843 -889 10428 1221 -8079 1391 -2359 -1262 921 3116 5164 9961 -7678 -8077 -18276 6348 14998 12576 -17454 -3585 12591 -431 6024 9186 8192 6821 -1525 6683 2222 13617 4719 -13242 8242 -8095 -1427 -2810 -3932 -21404 -9153 -937 303 5937 8951 6618 5144 1805 4637 13902 -7178 5091 4552 -9667 6526 -1020 -1204 -10518 11872 -7531 7881 -10427 8229 -3785 3460 -4896 10224 3419 -3626 -967 4924 -13068 -6539 3066 4951 19913 -905 -16 2737 12313 6128 -2328 538 -537 3228 -12616 1807 228 -272 -28848 13321 7641 7369 -7623 7261 15174 1877 -9393 12506 -17534 22824 -7550 2529 -26415 6283 5258 -9780 -11952 8394 -7788 -1778 24070 10363 SO 20191029T112906.0Z 7241.478542 468 1 32.01 2 89.07 108.89 104.88 98.01 0.00 1 0.00 1 0 22 6.756e-02 6.626e-02 4.092e-02 4.040e-02 -5.190490e+03 2.320063e+03 7.506598e+02 -6.000000e+00 3.832349e+03 282.31 -2.00 20.00 -2.00 505.23 0.00e+00 2.334507e-03 1.120285e-03 6.284893e-05 -6.000000e+00 1.913294e-03 282.31 -2.00 20.00 -2.00 500.28 0.00e+00 7.281411e-01 8.166292e-01 3.687837e-02 -6.000000e+00 1.346226e+00 224.66 -2.00 3.52 -2.00 501.91 0.00e+00 18.818 0.124 489.00 513.00 1 9.9821e+00 6.2625e-02 3.2432e-02 -6.0000e+00 1.0340e-01 1.4929e-01 1.6230e-02 1.7652e-03 -6.0000e+00 2.6566e-02 5.7120e-06 -6.7378e-03 4.1506e-03 1.2590e-04 -6.0000e+00 7.0347e-03 -2.0328e-01 1.5554e-03 12 8 8 10 0 0 27.49 20.72 -5.13 -0.20328 -0.25001 8 2 1 4 0 4000.000 25.90 20.00 20.72 17.18 22.6 957.86 4775 7733 -14244 -1437 4181 1385 -7677 6164 -3740 -1175 -1398 2825 -9970 2520 4281 -3153 -7189 8019 2389 6468 -4287 -7526 -3957 2990 -2936 11381 3545 2489 -400 -2203 10798 4169 16626 141 -2481 -1383 5296 -7279 -1506 -5986 1666 -1615 8342 -10284 8483 -1960 3405 3472 2341 1601 12473 -6466 -7804 -8670 5337 14312 4557 -11304 2523 12624 -4418 3043 -3280 1774 1862 -5280 1295 2640 20713 4753 -2145 4415 -1462 -851 -3320 2703 -9999 -8883 3373 2552 -1766 8853 2629 -5046 -2356 6390 2179 3403 1918 8523 -4421 -1268 -7393 13699 -11075 2797 -11512 13678 -9049 5855 7941 1815 8819 2941 -248 777 -1386 -131 -7377 -7754 8249 4025 7677 2454 -2879 -21 10118 -1230 988 1658 11552 -2075 -7929 -7284 5472 -335 -13846 6104 7792 1772 809 -4287 10058 4859 -3299 2672 -507 3616 -7583 -7321 -13269 -2851 14911 -7317 1370 452 -739 -1060 11632 4621 4317 7143 -16171 -1488 4191 1454 -8995 6344 -4246 -1283 -1508 2890 -11398 2506 4162 -3315 -7957 7771 2512 6606 -4881 -8878 -4505 3182 -3333 11191 3750 2636 -426 -2309 9797 4060 14453 150 -2778 -1541 5476 -8135 -1636 -6489 1741 -1690 8295 -11978 8596 -2125 3479 3499 2348 1582 11159 -6576 -7961 -8964 4916 12895 4448 -13064 2543 11475 -4762 3062 -3526 1810 1882 -5652 1277 2536 17087 4357 -2087 4040 -1429 -834 -3366 2568 -10611 -9184 3061 2327 -1689 7696 2442 -5079 -2335 5847 2084 3218 1848 7747 -4604 -1297 -7902 12452 -12406 2824 -12828 12038 -9380 5322 7025 1719 7908 2764 -243 746 -1339 -123 -7387 -7856 7245 3759 7058 2414 -3014 -21 9346 -1264 979 1607 10043 -2047 -8265 -7614 5054 -327 -15489 5575 6981 1689 772 -4230 8465 4253 -3105 2389 -478 3335 -7905 -7675 -14805 -2868 12614 -7767 1333 441 -714 -999 9465 4018 SO 20191029T113247.0Z 7241.481100 472 1 32.01 2 88.41 109.50 104.23 98.58 0.00 1 0.00 1 0 22 5.033e-02 4.963e-02 3.038e-02 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