File name: Pandora64s1_NewHavenCT_20200420_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260322T183147.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v2d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20200420_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20200420 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200420T132910.6Z 7415.561929 1698 1 47.30 2 52.81 108.97 51.44 144.96 0.00 1 0.00 1 0 17 1.538e-02 9.448e-03 4.639e-03 1.964e-03 2.517121e-01 1.053304e-03 3.041181e-03 -6.000000e+00 9.341384e-03 229.06 -2.00 3.52 -2.00 316.57 0.00e+00 3.845093e-04 1.263012e-04 1.272052e-04 -6.000000e+00 4.068098e-04 280.76 -2.00 20.00 -2.00 315.91 0.00e+00 1.650 0.000 302.00 328.00 3 5.5610e+00 2.7510e-03 2.1149e-02 -6.0000e+00 2.3288e-02 3.0983e-02 3.0645e-03 1.3001e-02 -6.0000e+00 2.5165e-02 -3.1177e-03 1.7885e-03 6.3767e-03 -6.0000e+00 1.4956e-02 -3.3866e-03 8.4090e-04 1.7880e-03 -6.0000e+00 6.3282e-03 2.8276e-04 -6.1903e-05 6.0860e-05 2.2526e-05 -6.0000e+00 4.5755e-04 -1.7542e-03 6.8788e-06 12 9 8 11 32 0 99.79 21.08 0.04 -0.00175 -0.00222 13 3 1 5 0 3637.770 26.00 20.01 21.08 14.72 24.2 988.27 -285 -4210 -1352 -4890 -1958 -4511 -3601 -1328 1983 -176 -6680 261 -2424 -2233 1693 0 544 1711 352 1967 1598 -128 1560 1257 1480 1411 -480 -961 -1005 -882 860 46 3772 266 -5883 -1236 -2555 -962 889 -206 -515 -729 207 -404 -958 148 -97 -797 -765 -358 2122 725 613 1037 552 1097 1345 134 365 263 354 1125 1528 2369 1346 -1499 -823 -1884 679 1759 951 923 -174 473 112 -1317 -1326 -2508 -1643 -676 -1365 -871 -1911 -2028 -573 -425 389 287 1017 541 -36 466 -2202 -580 476 655 -124 1593 893 -441 -647 -1545 -1617 290 48 -1441 -174 221 -164 708 1214 514 418 74 -675 -882 44 -477 504 657 143 14 758 427 1343 520 -1487 391 917 775 445 -614 -835 -363 669 -323 -192 559 360 -504 -369 -968 -44 -707 -221 -748 -283 -675 -576 -219 343 -32 -1279 50 -543 -564 462 0 157 512 110 626 512 -42 521 442 539 526 -177 -332 -333 -297 304 17 1476 106 -2345 -494 -1105 -480 491 -124 -330 -486 140 -274 -654 99 -63 -515 -488 -233 1437 504 448 792 430 869 1074 107 287 210 283 962 1334 2131 1171 -1286 -676 -1565 606 1657 919 913 -170 456 103 -1113 -1088 -2051 -1390 -609 -1366 -913 -2048 -2301 -667 -521 477 357 1240 646 -42 508 -2304 -604 530 769 -151 2066 1149 -570 -814 -1831 -1886 354 61 -1923 -234 308 -234 1030 1816 760 607 103 -911 -1152 59 -643 721 947 208 19 1078 577 1783 664 -1936 503 1250 1080 627 -892 -1250 -550 1063 -520 -315 927 593 -810 -575 -1518 SU 20200420T133107.9Z 7415.563286 1700 1 47.87 2 52.46 109.39 51.22 145.51 0.00 1 0.00 1 0 25 1.326e-02 8.819e-03 3.693e-03 1.649e-03 2.490142e-01 8.876094e-04 3.002789e-03 -6.000000e+00 8.051563e-03 229.06 -2.00 3.52 -2.00 316.42 0.00e+00 3.804562e-04 1.023412e-04 1.173112e-04 -6.000000e+00 3.506437e-04 280.76 -2.00 20.00 -2.00 315.76 0.00e+00 1.637 0.000 302.00 328.00 3 5.2310e+00 2.3126e-03 2.0941e-02 -6.0000e+00 2.0073e-02 2.3771e-02 2.5728e-03 1.2835e-02 -6.0000e+00 2.1691e-02 -2.4316e-03 1.4946e-03 6.2950e-03 -6.0000e+00 1.2892e-02 -3.2591e-03 6.9646e-04 1.7619e-03 -6.0000e+00 5.4542e-03 4.0140e-04 -3.0785e-04 5.1030e-05 2.2743e-05 -6.0000e+00 3.9440e-04 -2.0095e-03 -1.9652e-05 12 9 1 12 1 1 98.18 21.08 0.12 -0.00201 -0.00432 16 4 1 5 0 2815.240 26.00 19.98 21.08 14.76 24.2 988.48 2209 -3294 2027 -3639 -4576 -1820 -952 -1047 1678 -303 -3725 -1908 -1156 -2164 1239 -413 -804 875 -150 1557 1372 -174 2831 773 153 1398 1118 -1495 -598 -378 1936 640 2434 -80 -5134 -996 -1655 -1871 601 263 -679 -689 -590 -797 -652 -329 -545 -169 -1319 -23 1721 1237 526 1465 154 936 1203 522 -147 516 372 1433 1310 2249 1208 -1237 -1033 -1678 555 1946 721 478 -245 1078 -171 -1025 -1218 -2739 -1030 -326 -1325 -861 -1977 -1702 -621 -736 303 421 1173 509 166 474 -1426 -392 921 565 70 1300 759 -489 -587 -1606 -1936 -40 423 -1321 -149 -416 -195 662 1027 485 353 -56 -493 -599 433 -412 572 525 324 -88 1002 160 968 433 -1028 236 610 281 579 -573 -894 -152 516 -122 -245 509 359 -434 -9 -1075 365 -601 351 -603 -704 -275 -154 -188 319 -60 -758 -411 -279 -567 352 -128 -257 288 -49 517 458 -59 969 284 58 541 422 -540 -215 -138 702 248 1000 -33 -2103 -411 -735 -975 346 164 -454 -459 -402 -543 -443 -221 -372 -113 -880 -16 1167 892 401 1114 120 744 963 415 -116 411 311 1227 1197 2040 1099 -1063 -886 -1448 497 1839 705 480 -242 1040 -159 -901 -1000 -2245 -901 -305 -1334 -910 -2143 -1882 -732 -890 378 532 1453 599 186 505 -1495 -411 994 649 86 1664 996 -623 -726 -1932 -2297 -48 543 -1736 -198 -578 -278 958 1528 715 508 -77 -654 -769 562 -564 808 751 466 -125 1407 222 1273 564 -1310 309 822 388 832 -824 -1327 -229 793 -196 -402 819 574 -696 -14 -1680 SU 20200420T133302.4Z 7415.564611 1702 1 48.80 2 52.12 109.79 51.02 146.05 0.00 1 0.00 1 0 17 1.290e-02 8.439e-03 2.551e-03 1.199e-03 2.457317e-01 6.453583e-04 2.970624e-03 -6.000000e+00 7.836539e-03 229.06 -2.00 3.52 -2.00 316.28 0.00e+00 4.130670e-04 7.234746e-05 7.073187e-05 -6.000000e+00 3.412726e-04 280.76 -2.00 20.00 -2.00 315.64 0.00e+00 1.625 0.000 302.00 328.00 3 4.7402e+00 1.6789e-03 2.0747e-02 -6.0000e+00 1.9536e-02 1.5858e-02 1.8668e-03 1.2684e-02 -6.0000e+00 2.1111e-02 -1.7652e-03 1.0803e-03 6.2147e-03 -6.0000e+00 1.2547e-02 -2.9164e-03 4.9999e-04 1.7468e-03 -6.0000e+00 5.3088e-03 6.6989e-04 -1.9006e-04 3.7090e-05 2.2622e-05 -6.0000e+00 3.8385e-04 -2.1631e-03 -9.9007e-06 11 8 0 10 0 0 99.66 21.08 0.02 -0.00216 -0.00359 29 7 1 5 0 1682.320 26.00 19.99 21.08 14.81 24.3 988.97 754 -2506 680 -2416 -5676 -3756 -1509 154 954 -65 -3440 -1739 -1796 -1120 982 702 -162 1395 365 1344 1643 -255 1740 1339 917 1376 189 -810 -825 41 1751 396 2760 83 -5400 -2158 -2237 -1255 473 681 -928 -892 -378 -866 -304 -141 -402 -403 -977 -286 1458 645 770 1195 313 978 1101 322 296 207 156 1260 1414 2404 839 -1647 -502 -1887 506 1578 594 678 -228 568 250 -924 -976 -2111 -724 -299 -1152 -523 -2046 -1881 -531 -500 200 184 1028 388 295 459 -1406 -463 567 347 95 1396 834 -331 -299 -1559 -1875 343 352 -1316 -366 -220 -152 628 844 510 276 -145 -444 -532 209 -300 487 529 -77 -82 806 121 1134 601 -1170 507 775 361 469 -474 -653 -357 514 -114 -294 611 175 -427 -63 -962 132 -472 124 -433 -967 -634 -268 30 190 -13 -725 -388 -453 -317 291 223 -53 474 129 487 595 -94 625 507 362 553 75 -301 -308 15 659 160 1169 35 -2295 -932 -1036 -646 272 440 -622 -619 -268 -615 -214 -99 -274 -270 -649 -193 1032 468 586 949 246 779 885 258 234 166 131 1088 1300 2196 770 -1429 -429 -1636 456 1508 587 686 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