File name: Pandora64s1_NewHavenCT_20200529_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260322T183703.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v2d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20200529_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20200529 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200529T155805.3Z 7454.665340 5651 1 28.69 2 22.31 147.28 89.83 70.97 0.00 1 0.00 1 0 17 1.268e-02 1.028e-02 2.901e-03 2.116e-03 1.543269e-01 1.168030e-03 1.860545e-03 -6.000000e+00 7.784253e-03 232.00 -2.00 3.52 -2.00 314.60 0.00e+00 5.533990e-04 9.255474e-05 4.393711e-05 -6.000000e+00 3.411182e-04 284.91 -2.00 20.00 -2.00 314.02 0.00e+00 1.081 0.000 302.00 328.00 3 5.8629e+00 3.0087e-03 1.3549e-02 -6.0000e+00 1.9519e-02 5.7967e-02 3.3119e-03 8.0350e-03 -6.0000e+00 2.1029e-02 -3.2055e-03 1.8919e-03 3.8748e-03 -6.0000e+00 1.2499e-02 -3.0501e-03 8.1656e-04 1.0846e-03 -6.0000e+00 5.2786e-03 4.3950e-04 3.0007e-05 6.4864e-05 1.5693e-05 -6.0000e+00 3.7740e-04 -2.4011e-03 4.9833e-05 12 9 9 12 1 1 99.92 21.12 0.07 -0.00240 -0.00218 8 4 1 5 0 3167.610 26.00 20.01 21.12 28.86 26.7 1064.95 1099 -316 654 -2117 -4235 -2195 342 -271 1834 185 -3335 -1409 72 -489 1457 670 -1405 639 854 788 1689 580 1573 1151 621 1501 318 -1424 -773 -63 1693 249 3374 -499 -5021 -2071 -2143 -1191 606 368 -841 -1070 -460 -1096 -253 -362 -502 -484 -1042 -441 1380 523 341 1677 344 902 1251 374 -255 -70 595 1363 1317 2600 1071 -1371 -1178 -2501 361 2373 1278 833 459 602 0 -910 -1464 -2585 -1421 -209 -1410 -793 -1836 -1915 -533 -499 481 619 1266 619 309 157 -2088 -809 136 635 -231 1485 874 -568 -233 -2006 -2160 -190 149 -1344 -303 37 25 503 1218 808 195 -69 -542 -758 202 -387 403 899 621 316 785 266 1347 565 -1434 45 864 339 561 -429 -746 -271 405 -26 -229 416 294 -424 39 -1450 408 -122 247 -775 -1439 -728 117 -103 695 72 -1302 -564 31 -235 715 347 -749 344 467 444 941 323 894 681 361 877 190 -800 -406 -33 895 138 1920 -287 -2817 -1176 -1291 -825 460 299 -699 -917 -400 -951 -216 -305 -426 -396 -832 -352 1138 455 296 1490 312 827 1150 342 -232 -64 569 1324 1348 2590 1064 -1320 -1072 -2274 348 2382 1317 884 480 626 0 -828 -1286 -2221 -1291 -198 -1423 -829 -2025 -2147 -635 -606 604 788 1581 733 349 169 -2193 -836 148 718 -276 1816 1090 -690 -276 -2263 -2506 -222 180 -1708 -386 48 34 693 1702 1104 260 -88 -667 -900 242 -472 525 1181 827 415 1035 334 1653 665 -1714 53 1052 432 711 -554 -987 -361 566 -36 -329 605 426 -601 54 -2046 SU 20200529T161249.1Z 7454.675568 5679 1 48.11 2 20.99 155.84 87.32 73.32 0.00 1 0.00 1 0 25 1.421e-02 1.083e-02 3.159e-03 2.146e-03 1.554876e-01 1.177531e-03 1.872445e-03 -6.000000e+00 8.728137e-03 232.00 -2.00 3.52 -2.00 314.97 0.00e+00 6.851616e-04 1.003637e-04 4.201704e-05 -6.000000e+00 3.824801e-04 284.91 -2.00 20.00 -2.00 314.35 0.00e+00 1.071 0.000 302.00 328.00 3 6.3192e+00 3.0417e-03 1.3526e-02 -6.0000e+00 2.1886e-02 6.8344e-02 3.3558e-03 8.1298e-03 -6.0000e+00 2.3579e-02 -5.2521e-03 1.9159e-03 3.9154e-03 -6.0000e+00 1.4014e-02 -2.3933e-03 8.3316e-04 1.1219e-03 -6.0000e+00 5.9187e-03 2.7948e-04 1.9446e-04 6.6175e-05 1.5102e-05 -6.0000e+00 4.2315e-04 -2.1513e-03 6.1703e-05 12 8 8 10 0 0 99.86 21.11 0.45 -0.00215 -0.00069 24 6 1 5 0 2004.220 26.00 20.01 21.11 29.03 26.8 1066.23 1734 -317 2568 -2781 -4876 -3004 -476 451 2773 147 -4581 -1263 -580 -908 2751 997 -1570 1490 -609 1415 1631 548 1758 1686 651 1828 146 -1506 -1426 -775 705 655 2242 -264 -5179 -2317 -2035 -1139 602 505 -1196 -431 -22 -349 -809 -511 -863 -129 -1010 -760 1458 693 453 963 359 541 980 565 -242 -399 821 842 1913 2677 1602 -1724 -1344 -1945 920 1587 999 967 398 823 53 -1266 -1560 -3410 -1474 -1046 -1290 -573 -1651 -2038 -280 -98 422 611 1646 659 536 -75 -2088 -1171 147 512 123 1570 1176 -277 -553 -2239 -2312 95 322 -1247 -65 -45 -245 907 1503 883 358 129 -971 -968 -229 -557 407 874 206 107 715 -92 1221 448 -1915 364 411 278 210 -637 -974 -459 774 359 -152 1104 238 -545 -19 -1139 584 -112 867 -885 -1439 -866 -143 147 946 52 -1644 -459 -231 -399 1277 462 -753 714 -304 711 816 274 894 888 355 1000 78 -758 -720 -386 360 345 1156 -144 -2780 -1260 -1151 -741 425 398 -1007 -350 -18 -287 -703 -436 -711 -102 -779 -589 1163 582 396 821 310 474 859 492 -209 -352 746 815 1929 2745 1568 -1583 -1233 -1772 840 1591 1063 1054 428 844 50 -1161 -1320 -2846 -1291 -1009 -1287 -615 -1770 -2314 -337 -118 528 774 2037 816 610 -83 -2164 -1198 158 564 148 2009 1454 -351 -661 -2553 -2610 112 406 -1572 -85 -61 -347 1261 2121 1221 492 163 -1208 -1159 -278 -710 525 1178 283 145 934 -120 1508 530 -2226 425 505 356 278 -860 -1279 -626 1105 531 -220 1610 347 -819 -28 -1638 SU 20200529T161552.1Z 7454.677686 5682 1 48.14 2 20.76 157.73 86.79 73.80 0.00 1 0.00 1 0 33 1.524e-02 1.205e-02 3.680e-03 2.490e-03 1.589186e-01 1.367191e-03 1.907836e-03 -6.000000e+00 9.358370e-03 232.00 -2.00 3.52 -2.00 314.98 0.00e+00 8.888843e-04 1.161799e-04 6.388774e-05 -6.000000e+00 4.100967e-04 284.91 -2.00 20.00 -2.00 314.36 0.00e+00 1.069 0.000 302.00 328.00 3 6.6036e+00 3.5327e-03 1.3612e-02 -6.0000e+00 2.3466e-02 7.7269e-02 3.8957e-03 8.2896e-03 -6.0000e+00 2.5281e-02 -7.1317e-03 2.2253e-03 3.9774e-03 -6.0000e+00 1.5026e-02 -1.8128e-03 9.7011e-04 1.1597e-03 -6.0000e+00 6.3461e-03 2.0822e-04 1.4452e-04 7.6880e-05 1.5330e-05 -6.0000e+00 4.5371e-04 -2.6544e-03 4.2969e-05 12 8 8 10 0 0 99.30 21.11 0.19 -0.00265 -0.00157 15 4 1 5 0 3208.600 26.00 20.02 21.11 29.16 26.8 1067.12 1271 227 2361 -1822 -5678 -2004 -855 -316 1952 43 -4636 -1890 -960 -1586 778 1566 -2030 1681 498 2587 1171 615 2143 1818 -98 1365 620 -1413 -2272 -538 575 739 2095 -1355 -5294 -1398 -2930 -1345 339 862 -790 271 664 -207 -229 -360 -217 -745 -1285 -608 885 723 798 1150 734 110 1522 5 109 -1103 424 1296 1867 2931 1917 -2337 -2059 -2949 673 2155 1361 1450 403 1079 -353 -1625 -2396 -3787 -2158 -438 -1648 -623 -1491 -1678 -258 -27 606 1014 1486 752 -119 -12 -2499 -1632 -483 496 -248 1660 1406 -529 -490 -2092 -2803 30 208 -1337 -100 615 -132 1111 1642 1330 296 16 -1044 -936 -664 -447 462 1037 587 623 725 39 1080 318 -2221 272 423 192 95 -542 -947 -501 808 187 -95 821 248 -279 -277 -1194 429 75 799 -574 -1689 -572 -256 -103 669 15 -1659 -690 -383 -665 350 732 -993 817 249 1305 597 312 1100 969 -55 759 335 -720 -1100 -255 280 371 1102 -716 -2716 -719 -1702 -847 246 660 -647 226 563 -176 -194 -300 -174 -580 -974 -485 696 595 682 1015 656 100 1377 5 98 -1014 383 1238 1867 2972 1854 -2143 -1869 -2664 640 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