File name: Pandora64s1_NewHavenCT_20200819_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T222028.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v2d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20200819_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20200819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200819T124053.5Z 7536.528397 829 1 4.98 2 62.00 98.08 66.76 91.18 0.00 1 0.00 1 0 25 1.643e-02 8.952e-03 1.260e-02 4.273e-03 2.846854e-01 2.311991e-03 3.460658e-03 -6.000000e+00 1.003981e-02 231.45 -2.00 3.52 -2.00 317.11 0.00e+00 3.327832e-04 3.215385e-04 1.205998e-04 -6.000000e+00 4.511975e-04 289.68 -2.00 20.00 -2.00 316.26 0.00e+00 2.119 0.000 302.00 328.00 3 4.1122e+00 6.1090e-03 2.6065e-02 -6.0000e+00 2.5095e-02 4.0317e-03 6.8232e-03 1.5043e-02 -6.0000e+00 2.7054e-02 9.0360e-04 4.0376e-03 7.2897e-03 -6.0000e+00 1.6133e-02 -2.9053e-03 1.9474e-03 1.9913e-03 -6.0000e+00 6.8300e-03 7.3412e-04 -3.0743e-03 1.3274e-04 2.5755e-05 -6.0000e+00 4.8942e-04 1.2611e-02 -2.1840e-04 12 9 1 12 9 1 64.70 21.08 0.04 0.01261 -0.01049 3 10 1 5 0 1203.210 26.00 19.97 21.08 25.94 28.2 1033.77 -2184 434 4679 -6823 2864 -2649 -159 -876 2125 -600 -4911 -1482 5551 -1527 1697 -2406 -185 1382 413 -548 2026 1166 3293 -2100 -1873 1099 3703 -2562 -827 1328 3085 1459 3889 -1917 -3909 -3613 -1870 -2096 226 -296 -1008 -276 -21 -601 -201 -1910 -1837 -821 -661 89 1363 711 531 1752 -144 926 1115 748 -1150 325 530 2057 560 2139 603 -1275 -640 -1143 1160 1388 314 1019 -235 971 266 -390 -1399 -1521 -1091 237 -987 -983 -1629 -1584 -253 -193 -204 593 1651 1011 -433 525 -636 -569 1006 595 -460 1530 361 -749 -568 -1699 -2135 10 156 -1132 -367 -618 -170 391 811 546 734 -105 -189 -880 757 -856 453 215 -66 -460 980 -80 1376 647 -1045 -33 1482 586 356 -480 -414 -593 386 -104 -53 788 -40 -478 111 -982 -262 53 556 -826 292 -290 -18 -114 294 -88 -750 -239 903 -304 371 -562 -44 340 106 -148 536 312 905 -644 -597 349 1118 -771 -236 381 940 482 1359 -666 -1378 -1275 -731 -922 115 -164 -575 -163 -13 -365 -122 -1175 -1105 -483 -386 53 864 463 365 1252 -107 671 817 544 -842 237 406 1677 478 1877 517 -1033 -519 -937 990 1268 297 979 -224 903 237 -329 -1114 -1203 -905 210 -948 -1000 -1756 -1749 -288 -232 -249 727 1978 1187 -491 564 -649 -591 1114 684 -571 1971 480 -970 -711 -2063 -2556 12 202 -1500 -496 -874 -247 582 1216 833 1065 -147 -253 -1186 1026 -1200 653 315 -96 -683 1399 -113 1886 855 -1399 -44 2040 838 534 -722 -641 -941 628 -171 -89 1339 -67 -788 181 -1612 SU 20200819T124300.5Z 7536.529867 831 1 49.01 2 61.61 98.46 66.38 91.53 0.00 1 0.00 1 0 17 1.142e-02 7.791e-03 7.384e-04 2.493e-04 2.808645e-01 1.349129e-04 3.367794e-03 -6.000000e+00 7.002022e-03 231.45 -2.00 3.52 -2.00 317.13 0.00e+00 2.026313e-04 1.903238e-05 1.592235e-04 -6.000000e+00 3.136594e-04 289.68 -2.00 20.00 -2.00 316.30 0.00e+00 2.093 0.000 302.00 328.00 3 1.0345e+00 3.5716e-04 2.5703e-02 -6.0000e+00 1.7504e-02 -6.2236e-03 3.9882e-04 1.4763e-02 -6.0000e+00 1.8850e-02 1.9715e-03 2.3523e-04 7.1388e-03 -6.0000e+00 1.1242e-02 -5.0857e-03 1.1377e-04 1.9481e-03 -6.0000e+00 4.7765e-03 1.6567e-02 1.6826e-05 7.7598e-06 2.3783e-05 -6.0000e+00 3.4012e-04 -2.4059e-03 4.9116e-05 11 8 0 10 0 0 99.98 21.08 0.19 -0.00241 -0.00228 1584 381 1 5 0 30.230 26.00 19.98 21.08 25.93 28.2 1034.16 1162 -458 240 -2943 -4684 -1824 -394 1168 1304 208 -3419 -1246 250 43 929 595 -1063 631 -118 1473 610 -744 569 1004 367 1258 421 -1247 -1167 133 1620 71 2354 -248 -4663 -2513 -1973 -1144 103 183 -1010 -1003 -314 -954 -456 -125 -848 -389 -983 -611 979 865 738 1342 221 769 1079 459 55 304 543 1283 1403 2452 779 -1266 -326 -1533 754 1795 525 623 -39 638 219 -762 -855 -2069 -534 -327 -1103 -615 -1918 -1961 -412 -340 233 270 1036 515 361 361 -880 -127 826 291 -50 1171 675 -498 -518 -1683 -1946 127 441 -1298 -257 -836 -279 415 891 476 235 46 -350 -290 382 -289 566 458 -77 -259 645 1 924 797 -1057 404 889 397 565 -440 -715 -342 547 -77 -435 383 215 -421 17 -736 138 -53 30 -351 -526 -202 -47 152 170 28 -482 -187 42 8 201 140 -263 162 -32 403 170 -194 154 285 109 382 126 -355 -346 40 477 23 795 -85 -1577 -876 -769 -483 51 96 -571 -589 -188 -576 -275 -75 -500 -225 -569 -363 614 577 488 928 158 560 792 336 40 223 417 1056 1163 2101 653 -1005 -264 -1262 631 1655 491 596 -37 604 191 -646 -679 -1646 -457 -295 -1051 -639 -2015 -2181 -463 -403 287 338 1269 599 409 377 -924 -134 890 330 -62 1507 891 -640 -658 -2014 -2292 156 552 -1719 -356 -1162 -409 613 1358 720 340 64 -483 -387 519 -395 821 694 -112 -388 933 2 1272 1051 -1375 540 1268 574 854 -658 -1105 -553 891 -131 -726 646 361 -716 28 -1183 SU 20200819T124445.5Z 7536.531082 833 1 49.05 2 61.28 98.78 66.06 91.81 0.00 1 0.00 1 0 25 1.173e-02 7.848e-03 5.678e-04 2.086e-04 2.778586e-01 1.129900e-04 3.337931e-03 -6.000000e+00 7.190769e-03 231.45 -2.00 3.52 -2.00 316.95 0.00e+00 2.867312e-04 1.515291e-05 1.253662e-04 -6.000000e+00 3.221234e-04 289.68 -2.00 20.00 -2.00 316.12 0.00e+00 2.071 0.000 302.00 328.00 3 7.6200e-01 2.9806e-04 2.5433e-02 -6.0000e+00 1.7976e-02 -9.4033e-03 3.3245e-04 1.4600e-02 -6.0000e+00 1.9358e-02 6.7772e-04 1.9510e-04 7.0653e-03 -6.0000e+00 1.1545e-02 -3.6977e-03 9.3229e-05 1.9323e-03 -6.0000e+00 4.9050e-03 2.2351e-02 -1.0285e-04 6.4789e-06 2.4268e-05 -6.0000e+00 3.4932e-04 -2.3525e-03 3.6620e-05 11 8 0 10 0 0 99.95 21.08 0.22 -0.00235 -0.00313 1611 388 1 5 0 29.720 26.00 20.01 21.08 26.00 28.2 1035.07 916 -1001 264 -3671 -4874 -2658 -1100 406 1066 -316 -3428 -1910 108 -186 986 411 -898 656 226 1565 1024 -556 796 960 623 1263 571 -1084 -1082 70 1646 98 2413 -44 -4482 -2495 -1893 -1117 118 190 -965 -1000 -249 -859 -460 -4 -751 -271 -949 -495 1036 921 675 1381 204 783 1078 522 -14 259 453 1345 1366 2440 750 -1218 -410 -1616 714 1696 501 565 -93 642 205 -715 -828 -2025 -545 -293 -1154 -603 -1941 -1998 -468 -395 165 261 1013 503 379 344 -837 -109 835 301 -50 1209 694 -462 -449 -1628 -1894 164 433 -1321 -258 -813 -300 354 875 398 247 64 -326 -270 390 -309 555 442 -71 -251 685 37 961 844 -963 448 959 425 606 -422 -671 -334 537 -72 -453 385 188 -479 -17 -781 120 -129 37 -488 -606 -328 -145 59 154 -48 -532 -317 20 -40 234 106 -243 170 61 433 287 -158 234 298 202 418 186 -336 -322 21 528 34 886 -16 -1645 -944 -744 -512 59 108 -591 -598 -152 -527 -282 -2 -450 -170 -595 -298 659 623 483 971 148 579 805 388 -10 194 354 1125 1155 2133 642 -985 -337 -1352 609 1594 478 553 -89 587 183 -616 -667 -1634 -473 -269 -1121 -607 -2085 -2166 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