File name: Pandora64s1_NewHavenCT_20200928_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T222642.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v2d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20200928_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20200928 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200928T135552.3Z 7576.580466 1318 1 18.58 2 57.68 128.34 153.98 340.10 0.00 1 0.00 1 0 25 1.152e-02 8.258e-03 1.072e-03 5.551e-04 2.256267e-01 2.978169e-04 2.737134e-03 -6.000000e+00 6.954291e-03 227.68 -2.00 3.52 -2.00 316.04 0.00e+00 3.032783e-04 3.225903e-05 6.869471e-05 -6.000000e+00 3.112080e-04 285.97 -2.00 20.00 -2.00 315.32 0.00e+00 1.864 0.000 302.00 328.00 3 2.1044e+00 7.6991e-04 2.1935e-02 -6.0000e+00 1.7249e-02 1.0967e-03 8.5673e-04 1.1620e-02 -6.0000e+00 1.8647e-02 4.0256e-03 4.9326e-04 5.6863e-03 -6.0000e+00 1.1130e-02 -4.7571e-03 2.2612e-04 1.5963e-03 -6.0000e+00 4.7406e-03 7.8460e-03 1.6766e-04 1.7170e-05 2.1082e-05 -6.0000e+00 3.4251e-04 5.5560e-03 1.1132e-05 12 9 1 12 1 1 99.92 21.15 0.17 0.00556 0.00682 161 102 1 5 0 113.580 26.00 20.00 21.15 28.31 29.1 1043.91 717 -251 121 -3507 -4481 -1991 -921 1017 1436 -31 -3572 -1426 -127 -28 1235 382 -644 811 499 1510 966 -559 1055 819 787 1270 552 -1263 -873 107 1584 121 2745 -687 -4315 -2293 -1676 -1095 513 115 -840 -1114 -276 -1112 -314 -223 -758 -278 -862 -509 1207 856 944 1247 251 826 1141 606 118 339 522 1305 1394 2410 485 -1365 -664 -1669 842 1582 377 503 -53 654 54 -584 -987 -2067 -531 -327 -1177 -547 -2045 -1811 -394 -377 114 357 980 418 283 97 -1073 -188 681 304 -112 1395 679 -291 -516 -1730 -1925 450 317 -1208 -115 -739 -277 437 985 425 206 -15 -407 -301 336 -293 618 445 -43 -215 775 -33 1099 583 -904 567 902 398 584 -526 -727 -388 563 -175 -377 439 162 -432 -12 -912 149 -55 26 -707 -844 -371 -184 221 336 -7 -884 -373 -37 -9 409 136 -237 307 195 604 389 -212 411 336 334 547 232 -502 -357 44 634 52 1227 -309 -1903 -1047 -855 -608 310 78 -575 -791 -199 -805 -226 -158 -526 -188 -578 -349 866 649 751 976 202 674 936 494 96 278 450 1137 1290 2279 444 -1173 -576 -1467 757 1483 378 514 -53 624 50 -519 -821 -1716 -474 -307 -1167 -588 -2224 -2084 -460 -445 139 442 1188 502 329 104 -1138 -201 741 347 -135 1792 889 -369 -617 -2047 -2262 554 400 -1540 -153 -1029 -389 641 1423 604 289 -20 -537 -385 439 -388 868 627 -62 -301 1088 -45 1459 741 -1131 728 1228 549 835 -743 -1058 -567 865 -269 -595 700 257 -668 -19 -1391 SU 20200928T135754.1Z 7576.581876 1320 1 48.24 2 57.38 128.83 154.10 341.13 0.00 1 0.00 1 0 25 1.153e-02 8.190e-03 5.848e-04 2.948e-04 2.236853e-01 1.581950e-04 2.719382e-03 -6.000000e+00 6.960057e-03 227.68 -2.00 3.52 -2.00 316.09 0.00e+00 2.753602e-04 1.733385e-05 7.048014e-05 -6.000000e+00 3.114999e-04 285.97 -2.00 20.00 -2.00 315.36 0.00e+00 1.849 0.000 302.00 328.00 3 1.8006e+00 4.0930e-04 2.1766e-02 -6.0000e+00 1.7263e-02 8.1157e-04 4.5559e-04 1.1541e-02 -6.0000e+00 1.8663e-02 4.1672e-03 2.6290e-04 5.6483e-03 -6.0000e+00 1.1140e-02 -4.9597e-03 1.2087e-04 1.5856e-03 -6.0000e+00 4.7442e-03 1.0828e-02 1.4503e-04 9.1462e-06 2.1136e-05 -6.0000e+00 3.4281e-04 5.9026e-03 -3.0063e-06 11 8 0 10 0 0 99.73 21.15 0.18 0.00590 0.00699 721 174 1 5 0 66.900 26.00 20.01 21.15 28.31 29.2 1044.24 567 -803 39 -3648 -4312 -1800 -374 1066 1526 -114 -3532 -1587 25 25 1159 538 -750 891 244 1806 861 -285 837 899 502 1388 458 -942 -879 488 1686 275 2701 -506 -4528 -2355 -1744 -1019 345 126 -1035 -1058 -310 -1001 -350 -41 -784 -270 -1001 -419 1111 841 867 1301 196 836 1119 482 44 321 619 1353 1428 2348 397 -1375 -572 -1772 902 1583 429 508 -126 664 162 -727 -940 -2071 -362 -295 -1017 -586 -2053 -1836 -394 -387 202 231 934 385 413 191 -1059 -80 835 217 -12 1367 612 -434 -528 -1716 -1831 422 368 -1239 -236 -824 -198 430 915 406 253 -37 -378 -265 305 -306 629 467 -54 -137 667 -41 1085 707 -956 555 901 446 582 -515 -722 -306 549 -152 -369 429 120 -438 27 -882 114 -169 8 -705 -776 -321 -71 222 342 -26 -836 -398 7 8 367 182 -264 322 91 687 330 -111 335 378 219 569 197 -383 -342 190 690 120 1147 -232 -2046 -1022 -846 -537 211 81 -715 -757 -225 -730 -254 -29 -548 -184 -676 -289 803 642 653 1020 158 683 920 394 36 264 534 1176 1318 2216 363 -1178 -495 -1558 807 1474 427 516 -126 628 149 -646 -781 -1717 -322 -276 -999 -624 -2209 -2091 -455 -471 243 282 1169 456 473 201 -1114 -85 896 257 -15 1727 788 -541 -650 -2001 -2120 513 457 -1623 -309 -1129 -284 619 1347 588 363 -49 -491 -333 391 -414 868 672 -78 -195 919 -56 1416 924 -1231 701 1205 602 816 -743 -1027 -456 860 -237 -590 693 193 -686 41 -1369 SU 20200928T135939.4Z 7576.583095 1322 1 48.85 2 57.13 129.25 154.19 342.03 0.00 1 0.00 1 0 17 1.154e-02 8.223e-03 5.938e-04 3.165e-04 2.223982e-01 1.698880e-04 2.705042e-03 -6.000000e+00 6.967386e-03 227.68 -2.00 3.52 -2.00 315.95 0.00e+00 3.271381e-04 1.802932e-05 6.086771e-05 -6.000000e+00 3.118259e-04 285.97 -2.00 20.00 -2.00 315.23 0.00e+00 1.836 0.000 302.00 328.00 3 1.9981e+00 4.3862e-04 2.1622e-02 -6.0000e+00 1.7281e-02 8.1607e-04 4.8801e-04 1.1474e-02 -6.0000e+00 1.8683e-02 3.7455e-03 2.8091e-04 5.6192e-03 -6.0000e+00 1.1152e-02 -4.5972e-03 1.2809e-04 1.5812e-03 -6.0000e+00 4.7492e-03 9.0157e-03 1.2113e-04 9.7756e-06 2.1018e-05 -6.0000e+00 3.4317e-04 5.8877e-03 -2.0058e-06 11 8 0 10 0 0 99.43 21.15 0.19 0.00589 0.00680 457 110 1 5 0 105.710 26.00 20.01 21.15 28.32 29.2 1044.46 677 -1028 156 -4009 -4319 -1959 -355 750 1463 -45 -3407 -1596 179 5 1208 655 -752 845 371 1967 833 -238 864 870 479 1455 468 -1060 -770 398 1506 466 2588 -403 -4468 -2160 -1840 -864 427 214 -1106 -1005 -343 -1009 -341 45 -719 -206 -974 -384 1143 911 717 1279 123 864 1052 498 12 275 491 1389 1397 2362 403 -1316 -636 -1753 881 1570 412 446 -127 642 145 -637 -961 -2049 -354 -361 -1003 -669 -2056 -1910 -403 -376 204 285 959 391 388 223 -954 -146 829 258 23 1333 634 -418 -490 -1728 -1809 391 356 -1273 -207 -830 -211 418 885 367 260 -33 -379 -230 385 -277 664 460 -12 -137 676 15 1111 727 -942 586 935 500 576 -497 -720 -289 533 -134 -409 414 96 -398 -2 -923 148 -237 35 -848 -847 -380 -73 170 356 -11 -875 -434 54 1 415 240 -286 331 139 753 322 -93 348 368 211 646 203 -434 -324 168 621 204 1190 -186 -2027 -1012 -901 -492 265 140 -778 -731 -254 -748 -251 33 -511 -143 -668 -268 838 706 551 1021 101 718 880 414 10 230 409 1233 1317 2162 376 -1150 -560 -1485 804 1495 419 441 -130 622 137 -545 -812 -1727 -320 -344 -1007 -694 -2267 -2129 -477 -450 253 357 1178 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