File name: Pandora64s1_NewHavenCT_20201025_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T223033.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v2d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20201025_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20201025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20201025T120722.6Z 7603.505122 217 1 49.12 2 81.68 114.60 156.01 346.26 0.00 1 0.00 1 0 25 2.649e-01 3.367e-02 8.855e-02 9.792e-03 6.929291e-01 5.430255e-03 9.260978e-03 -6.000000e+00 1.582477e-01 224.93 -2.00 3.52 -2.00 321.10 0.00e+00 8.097454e-03 2.095600e-03 7.157310e-03 -6.000000e+00 7.060572e-03 282.68 -2.00 20.00 -2.00 320.50 0.00e+00 6.493 0.005 302.00 328.00 3 2.6541e+00 1.7125e-02 8.0494e-02 -6.0000e+00 3.9045e-01 8.6074e-01 2.0292e-02 5.2297e-02 -6.0000e+00 4.2320e-01 -1.1100e+00 1.3510e-02 2.2433e-02 -6.0000e+00 2.5265e-01 4.6002e-01 6.8264e-03 5.3848e-03 -6.0000e+00 1.0786e-01 2.6300e-05 -2.4424e-03 2.8770e-04 1.6980e-04 -6.0000e+00 7.8718e-03 3.5774e-03 -1.4979e-04 12 8 8 10 0 0 99.40 21.04 -0.06 0.00358 -0.01478 15 4 1 5 0 3273.770 25.90 20.01 21.04 13.28 28.4 964.81 -6558 -29962 -47567 24988 -118347 -41195 -87024 -59010 -55124 -24173 -95101 -14767 -38206 -30870 23607 -6766 -3112 80735 769 40413 37971 58199 16612 46759 -4623 48949 12345 5807 -26801 -24671 48 -2631 40804 4436 8317 32755 7069 2294 21212 16632 52195 20991 43809 23964 39437 66928 54406 5154 23633 19835 50381 12885 26749 22110 32092 8599 17028 4092 28818 8953 8781 8600 19727 13711 29797 7083 9104 16530 15117 6521 8176 4302 578 -513 -5442 -5102 -10601 -9085 -13241 6084 -8167 1182 -2747 -3161 -5317 -3840 444 -1363 -1327 2341 -7543 -45 -7459 -5827 -5059 -612 -3346 -797 -798 -2358 -3149 -2319 -6201 -2388 -3096 -3616 -3208 -2467 -1033 2451 2680 2183 -365 1852 -917 -1657 -809 333 543 2502 2413 3267 2918 3093 4326 1447 -1406 2793 2104 1119 75 -198 -845 -611 480 85 -301 393 586 -1781 -806 -2427 -339 -1907 -3507 865 -12488 -2105 -6554 -3612 -3282 -1045 -7919 -672 -2704 -2325 1286 -524 -244 3228 61 2247 2047 2570 1045 2316 -356 2307 756 359 -2303 -2300 4 -257 2842 436 724 2263 687 267 2359 2038 5012 2683 4822 3012 4496 5826 5408 815 3209 2977 6479 2454 4710 4304 5736 1966 3549 935 4952 1871 1933 2098 4803 3876 7223 2093 2680 4699 4875 2418 3134 1727 230 -201 -2018 -1716 -3689 -3296 -5502 2585 -4342 645 -1666 -2035 -3737 -2790 321 -1011 -969 1561 -5196 -27 -4899 -4076 -4029 -513 -3305 -865 -906 -2643 -3312 -2189 -5775 -2240 -3125 -3839 -3654 -3024 -1392 3400 4053 3429 -584 2799 -1366 -2446 -1223 521 893 4092 3850 4972 4341 4413 6224 2086 -2076 4135 3559 2121 149 -418 -1903 -1396 1157 211 -762 998 1453 -4267 -1889 -5482 SU 20201025T120917.8Z 7603.506456 219 1 39.56 2 81.36 114.94 156.09 347.32 0.00 1 0.00 1 0 25 4.368e-01 2.979e-02 1.859e-01 9.215e-03 6.983111e-01 5.149279e-03 8.948814e-03 -6.000000e+00 2.610547e-01 224.93 -2.00 3.52 -2.00 321.24 0.00e+00 1.291270e-02 2.348446e-03 5.337816e-03 -6.000000e+00 1.164197e-02 282.68 -2.00 20.00 -2.00 320.69 0.00e+00 6.277 0.005 302.00 328.00 3 2.6131e+00 1.7164e-02 7.4792e-02 -6.0000e+00 6.4412e-01 5.9926e-01 2.1112e-02 4.1451e-02 -6.0000e+00 6.9805e-01 -7.6791e-01 1.6501e-02 2.3429e-02 -6.0000e+00 4.1674e-01 3.2322e-01 8.0682e-03 9.6200e-03 -6.0000e+00 1.7798e-01 3.3999e-05 -2.4943e-03 2.6941e-04 2.2056e-04 -6.0000e+00 1.2979e-02 2.9436e-03 -6.0893e-05 12 9 9 12 1 1 98.01 21.05 -0.40 0.00294 -0.01580 13 4 1 5 0 2812.920 25.90 20.02 21.05 13.30 28.4 965.20 -44743 -26500 -150604 85425 -175976 -77081 -82032 -85670 -90673 35561 -160408 29521 -40704 -8758 10133 70249 -31043 147295 -26211 96966 -2426 110569 -14974 213305 19713 68781 -25598 22601 -46968 5686 -14737 7483 39056 39452 16533 63580 61865 8267 26112 32084 47654 36999 33327 18057 29478 6916 58402 11685 31864 12908 39957 13004 30208 17053 25491 3939 30086 4269 20827 11940 7785 2586 24250 8849 27557 3434 16794 8062 7318 3355 15147 1685 4369 -2315 -1160 -6208 1 -7534 -3266 -1311 -2424 -2380 -712 -5457 -2627 -7075 1363 -2130 -262 2283 -6062 1439 -8637 -5083 -1983 -279 -2734 899 -959 564 -689 -2424 -6721 -1344 -3019 -1665 -3481 2160 -2273 1342 1576 1014 -669 1926 -923 -914 -601 191 -1 1363 349 2376 2173 3750 2040 2972 -2309 3187 1023 1814 266 -872 -1132 -39 576 261 -574 238 714 -699 -1175 -2000 -1498 -801 -9259 844 -11069 -3255 -2778 -2859 -3042 511 -9369 557 -1341 -287 338 2083 -1624 2382 -1374 2701 -104 2484 -696 1917 732 2348 -1299 785 -2837 262 -897 443 1899 1918 944 2464 2675 623 1916 2498 3402 3084 3011 1827 2869 821 4490 1420 3315 1746 4573 2122 4443 3040 4255 786 4852 823 3487 2208 1518 595 5066 2385 6277 974 4255 2325 2384 1274 5396 662 1678 -883 -396 -2033 0 -2616 -1268 -562 -1208 -1339 -423 -3591 -1799 -5080 980 -1604 -191 1543 -4171 881 -5813 -3573 -1554 -239 -2756 988 -1079 637 -732 -2368 -6478 -1280 -3123 -1777 -4075 2592 -3041 1940 2382 1594 -1064 3004 -1420 -1381 -935 295 -2 2227 561 3752 3345 5459 2934 4125 -3359 4813 1718 3361 523 -1841 -2536 -89 1382 648 -1456 605 1767 -1660 -2755 -4485 SU 20201025T121117.2Z 7603.507838 221 1 48.44 2 81.02 115.30 156.16 348.43 0.00 1 0.00 1 0 33 4.397e-01 2.105e-02 1.800e-01 6.797e-03 6.900683e-01 3.817507e-03 8.703384e-03 -6.000000e+00 2.626896e-01 224.93 -2.00 3.52 -2.00 321.20 0.00e+00 7.844830e-03 1.814181e-03 5.511434e-03 -6.000000e+00 1.171876e-02 282.68 -2.00 20.00 -2.00 320.65 0.00e+00 6.067 0.004 302.00 328.00 3 2.6361e+00 1.2867e-02 7.4206e-02 -6.0000e+00 6.4815e-01 3.8617e-01 1.6727e-02 4.6549e-02 -6.0000e+00 7.0249e-01 -4.5564e-01 1.5141e-02 2.4641e-02 -6.0000e+00 4.1939e-01 1.7994e-01 7.2734e-03 7.7273e-03 -6.0000e+00 1.7906e-01 4.2870e-05 -1.8179e-03 2.0106e-04 1.7220e-04 -6.0000e+00 1.3065e-02 3.5704e-03 -1.1937e-04 12 8 8 10 0 0 99.58 21.05 0.09 0.00357 -0.01009 19 5 1 5 0 2548.890 25.90 19.98 21.05 13.37 28.4 965.66 -136820 -71236 -148982 -101649 -208950 -157616 -159357 -56798 -121201 -45157 -183768 -88583 -41903 -112737 36885 -48992 108 7500 100007 17365 8850 41298 45628 9537 -5776 46032 32637 -25690 2843 -45699 -25636 -36883 7746 8761 13443 17219 27019 12733 21899 16686 36503 9294 28781 12633 19905 -8757 31211 4844 7392 16975 18125 4587 13634 2137 7977 710 13276 3576 15134 3766 2695 4198 10654 12198 16693 6140 5202 6538 2173 5892 5168 6687 390 70 -1620 -2586 -6650 -4462 -7332 3194 -3459 1573 -3812 -2563 -1083 -2014 327 -1247 998 2597 -4169 785 -6576 -2959 -1484 1148 -1827 1179 -446 -770 -1719 -2231 -4151 -604 -1917 -2460 -2382 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