File name: Pandora64s1_NewHavenCT_20201126_L2Fit_fwvt1c4d20190911p1-8.txt File generation date: 20260321T223653.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v2d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20201126_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20201126 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 1670 1819 Nominal wavelengths inside fitting window [nm]: 492.0778 492.1987 492.3196 492.4405 492.5613 492.6822 492.8030 492.9238 493.0446 493.1654 493.2861 493.4069 493.5276 493.6483 493.7690 493.8897 494.0104 494.1310 494.2516 494.3722 494.4928 494.6134 494.7340 494.8545 494.9751 495.0956 495.2161 495.3365 495.4570 495.5774 495.6979 495.8183 495.9387 496.0591 496.1794 496.2998 496.4201 496.5404 496.6607 496.7810 496.9012 497.0215 497.1417 497.2619 497.3821 497.5023 497.6225 497.7426 497.8627 497.9829 498.1029 498.2230 498.3431 498.4631 498.5832 498.7032 498.8232 498.9431 499.0631 499.1830 499.3030 499.4229 499.5428 499.6627 499.7825 499.9024 500.0222 500.1420 500.2618 500.3816 500.5013 500.6211 500.7408 500.8605 500.9802 501.0999 501.2195 501.3392 501.4588 501.5784 501.6980 501.8176 501.9371 502.0567 502.1762 502.2957 502.4152 502.5347 502.6541 502.7736 502.8930 503.0124 503.1318 503.2512 503.3705 503.4899 503.6092 503.7285 503.8478 503.9670 504.0863 504.2055 504.3247 504.4439 504.5631 504.6823 504.8015 504.9206 505.0397 505.1588 505.2779 505.3970 505.5160 505.6350 505.7541 505.8731 505.9920 506.1110 506.2299 506.3489 506.4678 506.5867 506.7056 506.8244 506.9433 507.0621 507.1809 507.2997 507.4185 507.5372 507.6560 507.7747 507.8934 508.0121 508.1308 508.2494 508.3681 508.4867 508.6053 508.7239 508.8425 508.9610 509.0796 509.1981 509.3166 509.4351 509.5535 509.6720 509.7904 509.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20201126T171856.6Z 7635.721489 472 1 47.29 2 63.10 190.41 116.46 55.51 0.00 1 0.00 1 0 15 3.286e-03 3.263e-03 9.588e-04 9.571e-04 3.857925e+03 5.990386e+01 2.739381e+02 -6.000000e+00 1.840049e+02 278.87 -2.00 20.00 -2.00 505.25 0.00e+00 4.911321e-04 2.643013e-05 3.339056e-05 -6.000000e+00 9.231310e-05 278.87 -2.00 20.00 -2.00 500.41 0.00e+00 1.074522e-01 1.913180e-02 2.896300e-02 -6.000000e+00 6.575293e-02 222.98 -2.00 3.52 -2.00 502.01 0.00e+00 2.198 0.000 489.00 513.00 1 7.7896e+00 1.4665e-03 4.0657e-03 -6.0000e+00 5.0405e-03 7.9734e-03 3.7619e-04 7.0791e-04 -6.0000e+00 1.3032e-03 5.8108e-04 2.1667e-04 9.5851e-05 3.1920e-05 -6.0000e+00 3.4292e-04 -6.8321e-04 -6.4901e-07 10 0 0 10 0 0 98.55 21.16 1.16 -0.00068 0.00082 12 3 1 4 0 3940.200 25.90 20.00 21.16 20.92 29.5 1007.78 -375 -387 -239 185 95 -129 300 335 246 79 -26 98 -58 -209 157 -41 -298 206 551 289 61 69 72 143 274 119 146 576 39 -1121 -398 -161 -357 68 676 69 -320 7 148 -273 160 277 134 126 394 -85 91 -82 238 150 -429 -663 -624 -874 42 477 355 4 -296 -108 -97 332 222 260 219 -117 -62 33 149 -49 -76 -373 -277 17 -99 244 -199 -367 -285 -268 -476 172 -131 -643 -181 4 -290 -150 -211 137 -113 -303 736 479 -49 -44 38 82 81 -629 -491 -881 -657 82 358 80 -74 -422 -504 -295 220 120 278 153 217 338 759 654 478 156 389 -108 -286 275 411 72 280 168 -220 641 395 80 193 -34 -316 -193 261 204 -61 79 -97 -140 123 -41 76 27 -64 -510 -369 -379 -368 -385 -238 190 99 -134 316 355 261 82 -27 100 -60 -214 159 -42 -301 212 579 307 64 72 74 149 286 124 151 605 40 -1130 -407 -161 -362 71 700 72 -332 8 154 -284 166 289 137 130 409 -89 94 -84 246 152 -421 -660 -615 -870 42 480 365 4 -300 -110 -98 336 226 264 220 -119 -62 33 146 -47 -74 -363 -271 17 -98 241 -193 -352 -280 -262 -454 164 -126 -628 -179 4 -289 -149 -211 136 -114 -300 731 476 -48 -44 37 78 77 -596 -465 -826 -632 80 353 79 -73 -412 -488 -287 216 120 279 155 221 335 755 653 473 157 385 -106 -279 269 402 70 274 164 -215 621 381 76 186 -33 -303 -182 250 199 -61 77 -96 -138 122 -41 75 27 -62 -499 -355 -363 SQ 20201126T175832.9Z 7635.748992 513 1 27.77 2 65.08 200.44 110.17 63.31 0.00 1 0.00 1 0 22 2.800e-03 2.788e-03 6.186e-04 6.175e-04 3.588781e+03 3.856702e+01 2.631000e+02 -6.000000e+00 1.567631e+02 278.87 -2.00 20.00 -2.00 505.25 0.00e+00 4.938884e-04 1.699439e-05 3.275475e-05 -6.000000e+00 7.867215e-05 278.87 -2.00 20.00 -2.00 500.41 0.00e+00 1.336930e-01 1.233976e-02 2.556834e-02 -6.000000e+00 5.606343e-02 222.98 -2.00 3.52 -2.00 502.01 0.00e+00 2.358 0.000 489.00 513.00 1 6.3683e+00 9.4519e-04 4.0950e-03 -6.0000e+00 4.2972e-03 7.7195e-03 2.4301e-04 6.4962e-04 -6.0000e+00 1.1119e-03 2.3494e-03 9.1121e-04 6.2097e-05 3.1914e-05 -6.0000e+00 2.9319e-04 2.3338e-03 -6.2865e-05 12 1 1 12 1 1 99.98 21.19 1.29 0.00233 0.00865 38 16 1 4 0 707.330 25.90 20.00 21.19 21.19 29.5 1009.68 -390 -260 47 420 59 -63 376 314 288 5 -154 247 -108 -182 -42 -114 -236 -7 541 286 25 129 35 141 470 123 41 450 163 -871 -285 -188 -607 56 665 190 -231 -127 30 -247 3 36 111 88 349 215 37 -49 173 -32 -405 -374 -449 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-63 -69 -25 87 31 -337 -437 -358 SQ 20201126T175921.5Z 7635.749554 514 1 0.97 2 65.14 200.64 110.03 63.46 0.00 1 0.00 1 0 15 3.010e-03 2.996e-03 7.315e-04 7.305e-04 3.327751e+03 4.497200e+01 2.437405e+02 -6.000000e+00 1.685587e+02 278.87 -2.00 20.00 -2.00 505.26 0.00e+00 5.315306e-04 2.011089e-05 3.434893e-05 -6.000000e+00 8.456639e-05 278.87 -2.00 20.00 -2.00 500.46 0.00e+00 8.564118e-02 1.455423e-02 2.428587e-02 -6.000000e+00 6.023908e-02 222.98 -2.00 3.52 -2.00 502.05 0.00e+00 2.363 0.000 489.00 513.00 1 3.1518e+00 1.1152e-03 4.0480e-03 -6.0000e+00 4.6177e-03 4.3215e-03 2.8660e-04 6.1516e-04 -6.0000e+00 1.1940e-03 5.8766e-02 3.5940e-04 7.3633e-05 3.0602e-05 -6.0000e+00 3.1427e-04 9.7786e-04 -1.5256e-05 12 1 1 12 1 1 -42.35 21.20 1.33 0.00098 0.00347 14 122 1 4 0 52.830 25.90 20.00 21.20 21.28 29.6 1010.39 -386 -353 -17 471 82 -47 326 416 486 -67 -78 220 17 -195 -128 -32 -222 -13 602 308 -27 124 20 115 302 96 -70 438 235 -789 -318 -203 -582 76 711 59 -257 -66 41 -193 -38 31 174 109 236 432 54 16 80 -43 -585 -437 -720 -853 -192 82 243 65 47 -154 -237 217 221 298 207 213 -106 55 246 -263 -428 -102 -227 -104 260 53 -294 -301 -124 -392 -413 27 -68 -514 -151 -12 -228 -231 33 117 -114 -29 484 598 -75 45 161 -110 -211 -422 -471 -505 -670 63 393 -158 -162 -340 -613 -198 212 87 281 222 281 19 350 683 345 97 317 104 -190 440 309 64 215 144 -179 348 465 -144 -103 216 -307 -15 307 297 -73 211 80 -55 131 8 -86 108 99 -360 -534 -305 -376 -349 -17 474 84 -48 342 431 502 -70 -81 223 18 -197 -128 -32 -224 -14 620 321 -28 131 21 120 318 102 -74 452 241 -792 -321 -206 -589 77 742 62 -265 -69 42 -197 -38 32 180 112 244 445 55 17 82 -43 -576 -429 -703 -841 -190 83 246 67 48 -158 -244 223 224 300 211 214 -106 55 242 -257 -415 -100 -223 -103 259 52 -287 -290 -120 -380 -403 26 -66 -504 -149 -11 -224 -227 32 115 -113 -29 482 594 -74 45 159 -105 -202 -399 -446 -485 -652 62 388 -157 -159 -337 -605 -196 209 87 283 221 282 19 354 690 347 96 315 102 -185 430 304 63 211 141 -175 339 450 -140 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