File name: Pandora64s1_NewHavenCT_20210130_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T224921.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v2d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210130_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210130T123806.4Z 7700.526463 272 1 48.86 2 85.14 118.46 81.15 281.53 0.00 1 0.00 1 0 33 5.045e-01 5.357e-02 3.043e-01 2.907e-02 1.167532e+00 1.754800e-02 1.307036e-02 -6.000000e+00 3.019489e-01 224.27 -2.00 3.52 -2.00 321.96 0.00e+00 4.370215e-03 6.095235e-03 2.083500e-03 -6.000000e+00 1.307391e-02 274.94 -2.00 20.00 -2.00 321.44 0.00e+00 10.048 0.019 302.00 328.00 3 -5.1120e-01 5.5513e-02 1.1716e-01 -6.0000e+00 7.4705e-01 2.7420e+00 6.4047e-02 5.8687e-02 -6.0000e+00 8.1244e-01 -2.5625e+00 3.9554e-02 2.9926e-02 -6.0000e+00 4.8257e-01 8.2856e-01 2.1758e-02 9.4071e-03 -6.0000e+00 2.0370e-01 7.8543e-06 -1.7931e-03 7.1673e-04 1.5928e-04 -6.0000e+00 1.4988e-02 6.8766e-03 -1.3083e-04 12 8 8 10 0 0 -4.42 20.95 0.62 0.00688 -0.00660 25 6 1 5 0 1953.850 25.79 20.00 20.95 -4.62 28.0 878.92 94781 85513 145705 81347 -55622 -14714 -40982 18006 303120 25207 -42976 7894 -21420 20236 77220 90571 36534 900000 4098 26740 18365 146066 -35479 96148 -1160 74870 4138 29735 -25297 -35106 -22654 78476 8240 148389 -45534 103926 61726 49962 8590 60155 107747 43028 32706 19607 54968 18040 107191 -12309 20731 -54008 143895 11111 17699 2466 80665 -17932 -7451 -19857 3863 -32673 20270 -2139 77838 36535 81535 14616 964 17332 22561 2548 34017 19835 4924 -26974 -23096 -28795 -24895 -12052 -13769 -2647 8650 4685 4358 8802 15960 -5192 26543 -11339 31613 14177 -10934 683 -19447 -8498 -2832 11446 8676 12792 6044 -1893 -12842 -2260 -10744 -131 -8049 -7484 -10077 22652 -5655 3967 4393 1590 2390 5097 -3813 -4945 -364 -900 -7633 5665 -136 6100 -647 11112 4498 -85 -6215 8253 242 -1879 -2418 -1020 -2471 167 798 -176 300 3050 1731 645 -2067 -2558 6163 5846 4859 4069 -8321 -1374 -4646 1081 8592 1303 -4443 579 -2607 1957 4892 5436 3838 900000 553 2630 1715 4140 -4969 3747 -106 3183 304 1633 -2278 -4039 -2795 4171 893 4206 -6985 3682 3499 3540 1035 4689 5344 4040 3303 2119 3992 1854 4557 -1810 2314 -12967 5608 1752 2759 467 7002 -3887 -1478 -4081 568 -6541 2442 -356 6619 5243 7655 2693 215 3500 4836 684 7231 4708 1230 -7645 -5769 -6886 -5821 -2776 -3903 -807 2743 1656 1649 3317 5827 -2389 9545 -5501 10193 5073 -4448 260 -9014 -4066 -1539 6450 5902 9555 5069 -1657 -11391 -1567 -7398 -83 -5784 -5577 -8401 15258 -5921 4186 5265 2104 3229 6670 -5349 -7001 -511 -1317 -12296 7788 -185 7319 -804 12598 5369 -105 -7986 10721 410 -3787 -5563 -2406 -6451 459 2334 -532 908 8977 4967 1724 -5226 -6385 SS 20210130T124955.4Z 7700.534669 275 1 48.72 2 83.21 120.52 83.27 283.31 0.00 1 0.00 1 0 17 4.416e-01 2.216e-02 1.488e-01 6.165e-03 1.049473e+00 3.652713e-03 1.140632e-02 -6.000000e+00 2.629848e-01 224.27 -2.00 3.52 -2.00 322.21 0.00e+00 8.300916e-03 2.013916e-03 3.899810e-03 -6.000000e+00 1.140171e-02 274.94 -2.00 20.00 -2.00 321.81 0.00e+00 7.731 0.008 302.00 328.00 3 1.3564e-01 1.3590e-02 1.0007e-01 -6.0000e+00 6.4962e-01 1.2438e+00 1.7944e-02 7.0518e-02 -6.0000e+00 7.0551e-01 -1.6045e+00 1.6614e-02 3.2323e-02 -6.0000e+00 4.1943e-01 6.3728e-01 7.9035e-03 1.2400e-02 -6.0000e+00 1.7793e-01 6.8277e-05 -2.2908e-03 1.6358e-04 1.7702e-04 -6.0000e+00 1.3117e-02 6.6593e-03 -1.4278e-04 12 9 8 11 8 0 59.92 20.96 0.26 0.00666 -0.01055 101 24 1 5 0 477.540 25.79 20.00 20.96 -3.97 28.0 882.18 -74664 -82494 -103606 -130579 -149856 -136699 -148082 -162076 -74947 -133650 -135271 -130688 -76328 -91013 -13795 -54415 31884 -14901 -34131 -38780 5997 -42866 14086 -25540 10001 -38005 36012 -80749 -13719 -44344 16711 -741 26937 34457 1090 -25389 28652 10394 35613 47194 57036 26253 24203 45438 21692 19784 70587 32162 26192 -4263 43483 31364 35317 39810 42253 32878 16239 31060 15007 19212 28685 16272 29700 35475 28535 25110 20199 23704 21777 18358 17322 17337 8212 8216 201 -1016 -7379 1648 -2976 6261 -58 7139 4001 1448 -563 1477 3032 2529 3299 2223 -3369 -920 -7664 -4113 -2355 -1598 -3804 -906 200 -2892 -2724 -3744 -5087 -1768 -1493 -3409 -2899 -1909 -2442 -902 -189 -1836 -230 -542 -661 -1810 566 -760 1648 1284 2268 1635 3575 2784 3191 613 -938 447 1723 645 1024 -79 -521 -202 603 187 -355 460 907 -267 -734 -2830 -1306 -1623 -2435 -3425 -4095 -3063 -3642 -4606 -991 -2922 -3179 -3642 -1789 -2885 -274 -1695 498 -394 -1087 -1259 115 -1263 237 -645 174 -1051 455 -3155 -289 -1519 392 -24 745 870 35 -1084 775 387 1199 1589 1851 1199 1149 1721 1043 987 2206 1585 1480 -328 2588 2319 2718 3135 3327 2623 1509 2595 1263 1675 2397 1583 2922 3742 3368 3115 2804 3420 3642 3541 3531 3515 1701 1535 36 -169 -1339 306 -704 1639 -19 2505 1435 563 -237 632 1314 1101 1393 897 -1362 -359 -3355 -1986 -1340 -1081 -3100 -825 176 -2556 -2395 -2933 -3733 -1293 -1155 -2818 -2602 -1894 -2611 -1107 -261 -2752 -347 -813 -972 -2682 850 -1206 2647 2042 3382 2315 4819 3658 4103 797 -1269 685 3094 1252 2225 -188 -1351 -525 1655 528 -1015 1305 2470 -680 -1862 -6830 SS 20210130T125940.2Z 7700.541437 278 1 48.35 2 81.65 122.26 85.01 284.78 0.00 1 0.00 1 0 17 7.738e-01 1.825e-02 1.035e-01 2.638e-03 9.317574e-01 1.527643e-03 1.036091e-02 -6.000000e+00 4.608394e-01 224.27 -2.00 3.52 -2.00 321.82 0.00e+00 8.693520e-03 8.126994e-04 2.146480e-03 -6.000000e+00 1.997659e-02 274.94 -2.00 20.00 -2.00 321.41 0.00e+00 6.474 0.005 302.00 328.00 3 2.3840e-01 5.4481e-03 8.2118e-02 -6.0000e+00 1.1384e+00 4.7895e-01 8.0716e-03 5.2864e-02 -6.0000e+00 1.2363e+00 -6.6221e-01 8.7213e-03 3.1009e-02 -6.0000e+00 7.3496e-01 2.7303e-01 4.0161e-03 1.4049e-02 -6.0000e+00 3.1183e-01 2.5662e-04 -1.4222e-03 7.1163e-05 2.1579e-04 -6.0000e+00 2.2982e-02 6.0447e-03 -1.2989e-04 12 8 8 10 0 0 13.14 20.97 0.18 0.00604 -0.00464 214 52 1 5 0 225.860 25.79 20.00 20.97 -3.62 27.9 883.93 -256914 -219171 -263888 -208585 -302626 -200849 -282266 -191311 -263002 -160432 -242547 -176975 -193679 -115739 -140119 -63026 -107559 -34687 -113409 -28970 -78102 18792 -81513 -37676 -61696 -46039 -67180 -38324 -76680 -36078 -43996 7990 -13471 7511 -23672 -2804 -3555 495 13836 13018 29686 7944 25729 20322 26501 11358 19195 11961 22569 7449 29574 15728 27585 17680 26392 9582 15633 9605 17846 6504 16555 8583 20257 15937 20549 8407 14953 7625 13308 10078 9719 7154 7495 3953 3199 968 253 -2344 918 54 -121 320 -865 -1744 -936 -135 752 511 1055 837 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