File name: Pandora64s1_NewHavenCT_20210225_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T225440.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v2d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210225_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210225T121154.1Z 7726.508265 256 1 48.14 2 83.53 107.87 102.64 311.76 0.00 1 0.00 1 0 33 4.816e-01 3.821e-02 3.155e-01 2.111e-02 8.761111e-01 1.247651e-02 9.869820e-03 -6.000000e+00 2.881368e-01 225.32 -2.00 3.52 -2.00 321.86 0.00e+00 1.045603e-02 5.378296e-03 1.919815e-03 -6.000000e+00 1.251095e-02 275.63 -2.00 20.00 -2.00 321.37 0.00e+00 8.046 0.010 302.00 328.00 3 1.7486e+00 4.1610e-02 9.3994e-02 -6.0000e+00 7.1304e-01 1.4525e+00 4.9159e-02 5.2782e-02 -6.0000e+00 7.7347e-01 -1.6635e+00 3.5665e-02 2.3559e-02 -6.0000e+00 4.5975e-01 6.2787e-01 1.8282e-02 1.0273e-02 -6.0000e+00 1.9517e-01 1.0810e-05 -3.6587e-03 6.0980e-04 1.4249e-04 -6.0000e+00 1.4318e-02 2.1079e-03 -3.0988e-04 12 8 8 10 0 0 99.73 21.39 0.18 0.00211 -0.02538 20 5 1 5 0 2406.280 26.11 20.02 21.39 10.54 30.5 960.72 13488 -600 242870 54796 -51192 -47173 -91799 -33663 36069 82344 -14460 -80830 8682 -43767 105408 25888 89944 15130 -19508 47123 165213 900000 900000 30291 44004 84056 -60384 -28837 -29172 -37104 2516 11078 57749 16305 15176 -27534 22606 4825 70247 34790 29286 183201 213177 25471 -12848 51633 89454 19405 102961 -39575 57083 -399 41130 1699 79310 6623 2562 17137 15751 9020 24385 50476 59465 30085 63475 5639 9396 72000 15304 29248 21347 12591 26522 1859 -15367 -12666 -12894 1637 -10107 3933 -12506 4726 6 -7012 -5079 -8573 3327 2203 4440 3755 -196 -2074 -11205 -12045 -10451 6864 -4737 -358 142 -1286 -1156 -2671 -3498 -1060 -1010 -4029 -3055 10282 -2460 1005 4189 -1183 -1691 2560 -345 -3465 1244 502 -3645 -300 -177 1743 3389 5220 4836 840 -3485 4950 746 -188 -1349 -1985 -992 160 906 1077 943 896 2517 -737 -2170 -3511 632 -33 4998 1459 -3102 -2481 -7137 -1508 786 1695 -508 -6099 357 -3553 2576 1473 2831 1044 -1762 2225 3400 900000 900000 1357 1651 2162 -5523 -1920 -1978 -3099 171 778 2796 1165 992 -2733 1450 415 3795 2780 2588 3770 4387 2374 -1645 3688 4717 2020 5165 -7873 5045 -64 4879 297 6817 1113 439 2552 2250 1354 3277 5805 7055 5022 8222 1212 2009 9152 3622 6688 5516 3541 6095 497 -4340 -3157 -3199 380 -3120 1259 -5175 1869 3 -3524 -2657 -4838 1719 1155 2232 1798 -91 -957 -5753 -6901 -6905 4498 -4053 -318 133 -1188 -1041 -2178 -2679 -817 -829 -3566 -2899 9377 -2752 1241 5595 -1758 -2553 3630 -489 -5003 1773 754 -5978 -478 -270 2493 4634 6768 6150 1092 -4758 6953 1272 -366 -2816 -4487 -2379 407 2440 2989 2646 2536 6835 -1939 -5412 -8343 SS 20210225T122132.3Z 7726.514957 259 1 16.56 2 81.82 109.53 103.93 313.54 0.00 1 0.00 1 0 25 4.601e-01 2.900e-02 2.977e-01 1.471e-02 7.447429e-01 8.315724e-03 1.004316e-02 -6.000000e+00 2.754770e-01 225.32 -2.00 3.52 -2.00 321.41 0.00e+00 1.544791e-02 3.754480e-03 7.457026e-03 -6.000000e+00 1.191326e-02 275.63 -2.00 20.00 -2.00 320.95 0.00e+00 6.590 0.005 302.00 328.00 3 2.2107e+00 2.7158e-02 8.0545e-02 -6.0000e+00 6.8198e-01 6.9331e-01 3.3929e-02 4.7041e-02 -6.0000e+00 7.3963e-01 -8.4265e-01 2.9838e-02 3.0795e-02 -6.0000e+00 4.3954e-01 3.3901e-01 1.4644e-02 1.5098e-02 -6.0000e+00 1.8651e-01 3.5378e-05 -1.6594e-03 4.2428e-04 3.2050e-04 -6.0000e+00 1.3671e-02 -2.7467e-03 -9.0081e-05 12 9 9 12 1 1 76.04 21.39 -0.12 -0.00275 -0.01522 6 5 1 5 0 2339.930 26.11 20.01 21.39 10.66 30.3 961.37 -83030 -60038 -106136 -69248 -154830 -111676 -133236 -27546 168226 99323 -143340 -133198 -75989 -108040 17156 25098 5694 193225 42119 -34773 -38686 11671 136259 94628 -14614 -2860 21913 -36078 -46139 -49424 -12618 -5550 45154 -21717 28353 -40818 73350 5814 49572 4647 44801 29036 33760 26673 39339 16759 40883 1027 12850 -12667 55774 12065 49419 17400 30569 12964 22162 6096 11993 -10573 13047 12843 8594 15941 29365 12475 16992 23785 13377 6993 13933 9052 2573 2373 -8811 63 119 -320 -12846 9064 -8253 3746 40 -4105 -5557 -1360 276 712 906 1209 -8827 -4253 -8318 -5912 -5229 1513 -4949 1360 -581 -248 -2623 -1392 -4675 274 -991 -3276 -2236 2017 -1374 497 2253 428 -999 1284 223 -1479 689 435 -715 1412 818 1565 3231 2966 4136 -1725 -1677 343 3312 49 448 -570 -802 -1057 1906 -1188 -8 165 1273 -997 -315 -2014 -2102 -1399 -3761 -1614 -6662 -3109 -4497 -395 2413 1425 -5684 -5519 -2500 -6027 385 608 173 2772 1057 -1690 -1880 366 1954 1454 -543 -94 589 -1613 -2414 -2954 -681 -305 1791 -1592 1244 -3448 2433 385 2593 404 2785 2221 2583 2232 2978 1643 3258 122 1505 -1960 5111 1767 5631 2745 4292 2192 3396 1063 1919 -2147 2236 2482 1966 3767 6207 3070 4105 5620 3742 2332 4566 3142 908 776 -2907 18 34 -94 -5049 3400 -4244 1932 22 -2470 -3625 -893 185 481 602 761 -5752 -2545 -5187 -3925 -3993 1263 -4859 1422 -651 -269 -2714 -1341 -4381 254 -993 -3351 -2442 2298 -1815 694 3395 682 -1609 1959 330 -2197 1035 686 -1199 2342 1324 2411 4762 4213 5911 -2440 -2477 525 5626 93 920 -1206 -1805 -2542 4743 -3023 -21 423 3160 -2485 -735 -4528 SS 20210225T124724.4Z 7726.532921 273 1 48.78 2 77.30 114.13 107.22 318.50 0.00 1 0.00 1 0 25 1.643e-01 7.509e-03 1.436e-02 6.014e-04 5.596154e-01 3.246657e-04 6.488380e-03 -6.000000e+00 9.836776e-02 225.32 -2.00 3.52 -2.00 320.06 0.00e+00 1.121488e-03 1.086127e-04 5.437383e-04 -6.000000e+00 4.254063e-03 275.63 -2.00 20.00 -2.00 319.55 0.00e+00 4.427 0.002 302.00 328.00 3 1.1838e-01 9.4166e-04 5.2784e-02 -6.0000e+00 2.4352e-01 1.4366e-02 1.1476e-03 2.9363e-02 -6.0000e+00 2.6411e-01 -5.6534e-03 1.0551e-03 1.5151e-02 -6.0000e+00 1.5695e-01 -6.1478e-03 5.4240e-04 4.7810e-03 -6.0000e+00 6.6596e-02 3.1319e-03 -6.1359e-04 1.8179e-05 5.9210e-05 -6.0000e+00 4.8817e-03 -1.6486e-03 -4.6038e-05 11 8 0 10 0 0 -11.80 21.41 0.18 -0.00165 -0.00626 744 179 1 5 0 64.760 26.11 20.02 21.41 11.74 30.3 966.76 -63897 -52959 -52900 -60403 -69655 -57824 -61745 -45216 -46705 -39671 -46431 -32667 -25615 -19623 -15737 -6504 -11922 -4839 -7766 -5135 -7351 -6463 -7662 -3790 -5936 -1936 -5106 -4507 -7601 -3276 -2137 -56 924 -398 -7098 -3382 -3124 -556 624 1585 317 163 1208 453 420 1110 218 820 -390 -698 1784 1105 1206 1541 617 959 1318 516 39 -34 527 1474 2125 2855 1337 -1237 -81 -1551 590 1740 752 807 218 307 -377 -1562 -1473 -2501 -757 -360 -1143 -330 -1766 -1865 -350 -377 429 718 1349 802 401 244 -927 -303 505 142 -124 1258 803 -238 -444 -1795 -2186 246 413 -1368 -423 -725 -148 432 954 428 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