File name: Pandora64s1_NewHavenCT_20210315_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T225729.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v2d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210315_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210315 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210315T113240.3Z 7744.481022 56 1 48.56 2 85.26 96.79 99.76 77.55 0.00 1 0.00 1 0 17 8.922e-01 1.112e-01 3.576e-01 4.764e-02 1.216821e+00 2.991680e-02 1.409914e-02 -6.000000e+00 5.410020e-01 226.13 -2.00 3.52 -2.00 321.12 0.00e+00 3.214519e-03 7.324641e-03 3.776234e-03 -6.000000e+00 2.756513e-02 276.80 -2.00 20.00 -2.00 320.45 0.00e+00 10.217 0.020 302.00 328.00 3 -5.1532e-01 8.5840e-02 1.2072e-01 -6.0000e+00 1.3384e+00 3.5519e+00 9.9076e-02 6.2102e-02 -6.0000e+00 1.4533e+00 -2.6238e+00 5.6098e-02 3.0752e-02 -6.0000e+00 8.6165e-01 6.2579e-01 2.9056e-02 9.2330e-03 -6.0000e+00 3.6871e-01 3.9823e-06 2.5851e-03 1.1718e-03 1.5565e-04 -6.0000e+00 2.8369e-02 3.2712e-03 -1.8523e-04 12 8 8 10 0 0 13.86 21.29 0.94 0.00327 0.02270 14 3 1 5 0 3467.890 26.00 20.00 21.29 -1.25 29.4 901.13 72287 275383 62852 900000 -32298 27692 -25990 285417 128664 900000 -25595 900000 -42193 28798 4961 155873 29994 190333 15642 386303 56215 900000 148047 900000 27044 900000 -40053 900000 -8495 -15159 45583 102146 106629 25392 78126 900000 900000 56672 97571 63137 56051 67282 99673 25642 -14386 -54457 195160 -10883 900000 -73465 204770 -29060 102335 -19820 900000 13421 31278 -20664 441249 -21218 79744 24548 123092 -6121 329736 3884 91406 23028 31512 17103 88547 26653 80669 -17234 -30913 -38071 -8361 -11478 -8625 32825 -18838 20825 29441 18779 48442 11851 34831 29506 68805 21169 -26100 49907 -25492 730 156 49182 6078 44276 -3323 8428 -8448 4535 -24455 24444 -15501 -384 -23057 110697 -2708 31239 -9160 10471 -6629 9270 1597 -1919 1313 2509 -14518 3966 -8054 6984 38 13740 962 -4513 -4838 14204 4537 2890 -5462 -3593 -3463 -2087 2729 -2497 4053 -882 6652 -5628 4346 146 10424 12764 8254 900000 -7152 3066 -4685 13229 5964 900000 -4416 900000 -12929 5191 1303 10200 6642 8822 3625 17905 7204 900000 6862 900000 3834 900000 -8664 900000 -1343 -3058 5966 8355 8722 4223 6816 900000 900000 7108 9045 8779 8405 8805 8968 4474 -3569 -19599 9046 -2671 900000 -36321 9491 -11251 11858 -7512 900000 3513 6396 -6367 20452 -5554 8316 4618 10341 -1919 15283 1112 12180 6090 8506 5642 15134 7485 12386 -5686 -9946 -12041 -2156 -3255 -2869 9034 -9399 7779 10515 7680 15057 5332 12346 10619 16743 7157 -13307 12578 -13762 352 91 20651 4557 25351 -3117 6618 -6956 2819 -18736 11796 -11538 -256 -21060 31747 -2665 25552 -11912 12534 -9065 11297 2055 -2564 1758 3427 -22543 5180 -11001 7693 44 13261 1044 -5119 -5870 17001 6799 5120 -11914 -8457 -8919 -5756 7640 -7511 11534 -2630 17573 -15507 10027 332 SS 20210315T114442.5Z 7744.489381 59 1 49.00 2 83.01 98.80 97.58 79.51 0.00 1 0.00 1 0 25 4.185e-01 2.053e-02 2.141e-01 7.220e-03 1.182241e+00 4.443028e-03 1.277274e-02 -6.000000e+00 2.511533e-01 226.13 -2.00 3.52 -2.00 322.40 0.00e+00 1.084246e-02 2.535293e-03 8.151232e-03 -6.000000e+00 1.088617e-02 276.80 -2.00 20.00 -2.00 322.01 0.00e+00 7.547 0.008 302.00 328.00 3 3.1984e-01 1.7022e-02 1.1505e-01 -6.0000e+00 6.2265e-01 1.5464e+00 2.2846e-02 1.0366e-01 -6.0000e+00 6.7495e-01 -1.9595e+00 2.1175e-02 4.0942e-02 -6.0000e+00 4.0113e-01 7.6939e-01 1.0004e-02 1.5653e-02 -6.0000e+00 1.6996e-01 5.3186e-05 -2.6498e-03 1.8179e-04 1.9096e-04 -6.0000e+00 1.2434e-02 1.0016e-03 -1.3716e-04 12 8 8 10 0 0 5.50 21.28 0.29 0.00100 -0.01891 85 20 1 5 0 569.730 26.00 20.00 21.28 -1.00 29.1 902.23 4765 -99329 -21222 -120978 -120191 -126950 -116028 -159440 -86610 -127415 -148630 -123611 -56123 -79658 -55380 -19298 -17089 3393 -39914 -12074 -18397 143428 12445 2752 -23108 4423 -67692 4928 -76809 -6433 -22601 63014 -16701 4231 -3062 -1824 -1919 19816 8126 26983 7629 53444 13536 43789 12970 -1736 11497 43340 10049 -8792 39835 25798 44867 47001 43562 30317 7960 24845 30162 21961 15728 15303 25175 47299 38437 20762 29230 24786 19657 19787 20165 16183 11092 12690 4427 -5121 4676 -5600 2499 6251 3559 5417 2556 949 5072 691 6393 -391 5571 493 275 -6285 -2531 -5163 -878 -2362 -627 -1948 971 -2057 -2010 -5388 -6368 -1654 -2753 -2908 -2023 -1898 -1813 -761 -915 -2016 -1097 -561 -1311 -1651 703 -31 1215 1671 1515 1809 2479 4039 3907 2057 -2186 862 698 709 131 -189 -645 -175 890 476 -535 1011 912 -442 -1052 -2616 43 -2606 -244 -3174 -2615 -2681 -2079 -4286 -1219 -2446 -3710 -3006 -1027 -2192 -1489 -462 -433 74 -1201 -289 -427 1010 193 46 -488 69 -2049 69 -2596 -131 -700 976 -647 131 -93 -54 -61 572 303 931 338 1543 591 1387 557 -88 534 1587 559 -656 2075 1707 2653 2912 2852 2284 667 1819 1954 1500 1196 1325 2304 3996 3761 2259 3143 3014 2856 3204 3394 2807 1874 1884 626 -728 619 -932 472 1396 968 1675 883 351 1899 256 2504 -150 2139 188 100 -2421 -995 -2208 -437 -1450 -450 -1646 852 -1821 -1635 -3957 -4289 -1079 -1921 -2125 -1604 -1688 -1892 -858 -1189 -2870 -1604 -817 -1894 -2387 1030 -48 1906 2557 2179 2424 3187 4950 4712 2501 -2844 1260 1232 1463 286 -456 -1703 -497 2489 1370 -1559 2890 2692 -1215 -2664 -6207 SS 20210315T115432.5Z 7744.496209 62 1 48.91 2 81.19 100.47 95.79 81.09 0.00 1 0.00 1 0 17 8.761e-01 1.741e-02 9.813e-02 2.623e-03 9.990278e-01 1.533243e-03 1.093677e-02 -6.000000e+00 5.259230e-01 226.13 -2.00 3.52 -2.00 321.93 0.00e+00 9.539939e-03 8.549714e-04 1.543169e-03 -6.000000e+00 2.279013e-02 276.80 -2.00 20.00 -2.00 321.51 0.00e+00 6.177 0.004 302.00 328.00 3 4.0360e-01 5.6441e-03 8.3233e-02 -6.0000e+00 1.3039e+00 5.3386e-01 8.5726e-03 5.9315e-02 -6.0000e+00 1.4133e+00 -7.1759e-01 9.2811e-03 3.2847e-02 -6.0000e+00 8.3992e-01 2.9035e-01 4.2099e-03 1.5326e-02 -6.0000e+00 3.5595e-01 2.5640e-04 -1.5109e-03 6.8464e-05 2.2146e-04 -6.0000e+00 2.6036e-02 5.5663e-04 -9.2673e-05 12 8 8 10 0 0 -2.25 21.28 0.18 0.00056 -0.01080 205 49 1 5 0 236.230 26.00 20.00 21.28 -0.76 29.0 903.74 -276297 -270138 -272779 -282431 -288325 -291704 -269552 -258006 -254660 -253471 -222266 -237934 -194345 -177894 -134607 -123100 -95370 -90854 -85429 -96919 -62509 -69951 -46623 -79344 -45155 -68054 -58290 -82700 -51850 -74353 -17239 -14587 -12947 -19399 -22698 -32452 -7309 -2499 10188 6771 4082 15580 18753 14747 4678 11624 22226 9268 20872 5720 21202 20634 21780 18850 21498 23479 11541 15516 13744 13782 9543 17162 17879 22541 18286 13013 13155 11263 10661 12001 10166 11409 5998 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