File name: Pandora64s1_NewHavenCT_20210320_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T225828.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v2d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210320_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210320 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210320T113520.2Z 7749.482873 67 1 48.41 2 83.17 95.99 113.03 22.44 0.00 1 0.00 1 0 17 4.168e-01 2.498e-02 2.249e-01 8.466e-03 1.049565e+00 5.138249e-03 1.155715e-02 -6.000000e+00 2.506025e-01 226.50 -2.00 3.52 -2.00 322.23 0.00e+00 7.764023e-03 2.742166e-03 1.530075e-03 -6.000000e+00 1.089775e-02 277.31 -2.00 20.00 -2.00 321.82 0.00e+00 7.693 0.008 302.00 328.00 3 6.1168e-01 1.8953e-02 9.6270e-02 -6.0000e+00 6.2151e-01 1.4313e+00 2.4204e-02 5.9204e-02 -6.0000e+00 6.7333e-01 -1.8054e+00 2.0381e-02 3.1094e-02 -6.0000e+00 4.0027e-01 7.1140e-01 9.8767e-03 1.1449e-02 -6.0000e+00 1.6973e-01 4.0565e-05 -2.7844e-03 2.2462e-04 1.8500e-04 -6.0000e+00 1.2390e-02 3.7750e-03 -1.1866e-04 12 8 8 10 0 0 -6.59 21.47 0.35 0.00378 -0.01715 61 15 1 5 0 793.280 26.11 19.97 21.47 6.23 30.4 942.96 -12226 -58845 -28582 -32178 -98397 -117771 -87847 -122588 -63412 1742 -107356 -41998 -93022 -60851 -41679 54554 -33342 101748 -27061 153501 -15926 900000 -28514 161925 -48573 94413 -76580 -33910 -63169 18818 -23448 105989 10752 35185 -7868 50750 -14432 29243 22501 2611 37370 71539 23837 49455 20668 36945 39865 36492 34632 -18258 38951 41278 41165 34270 56031 25642 7191 28350 53674 24691 36576 15182 44583 31254 56353 15328 31012 25837 26482 17898 35252 17459 22404 4985 11234 -6787 8407 -10496 -469 548 2362 5945 5671 -1885 6671 -2862 4242 -2513 3794 1286 -2806 -5065 -6176 -7592 -1080 -4290 -3854 -597 133 -2211 -3410 -3277 -7971 -3010 -2789 -5194 -2973 693 -2400 141 -1312 -983 -1125 441 -936 -705 -523 1168 652 2649 685 2954 1928 3650 3767 2326 -1610 2153 846 878 156 -166 -1056 595 301 30 -324 817 509 -220 -980 -2694 -248 -1943 -665 -652 -3249 -4330 -2307 -4507 -1285 18 -3464 -851 -4048 -2420 -1657 941 -1476 1344 -1157 1267 -538 900000 -1006 1336 -2041 1013 -3907 -1069 -2749 466 -1003 1575 420 1162 -331 1298 -693 1134 1077 155 1820 2539 1252 2163 1194 1830 1974 1988 2058 -1836 2484 2818 3027 2880 4255 2424 804 2425 3677 2001 3019 1583 3981 3611 5285 2185 4002 3761 4332 3559 6163 3629 4135 987 1846 -1217 1312 -2197 -107 151 748 2087 1982 -749 2579 -1264 1794 -1137 1576 518 -1112 -2024 -2600 -3681 -587 -2883 -3035 -525 123 -2050 -2953 -2502 -5872 -2163 -2124 -4240 -2587 647 -2676 165 -1768 -1414 -1661 635 -1339 -1000 -768 1757 1025 4044 1012 4023 2570 4625 4675 2887 -2116 3112 1470 1757 329 -382 -2647 1578 856 86 -956 2389 1443 -583 -2414 -6281 SS 20210320T114512.4Z 7749.489727 70 1 48.76 2 81.33 97.65 112.30 24.67 0.00 1 0.00 1 0 17 7.668e-01 1.578e-02 1.110e-01 2.956e-03 8.970691e-01 1.723061e-03 1.003360e-02 -6.000000e+00 4.608697e-01 226.50 -2.00 3.52 -2.00 321.74 0.00e+00 8.087025e-03 9.220209e-04 2.279814e-03 -6.000000e+00 1.998898e-02 277.31 -2.00 20.00 -2.00 321.31 0.00e+00 6.264 0.004 302.00 328.00 3 6.7354e-01 6.1912e-03 7.9770e-02 -6.0000e+00 1.1434e+00 3.9929e-01 9.1359e-03 5.1271e-02 -6.0000e+00 1.2389e+00 -5.5044e-01 9.7560e-03 3.0477e-02 -6.0000e+00 7.3634e-01 2.2514e-01 4.4822e-03 1.3573e-02 -6.0000e+00 3.1187e-01 2.0750e-04 -1.2855e-03 8.1243e-05 2.0266e-04 -6.0000e+00 2.2788e-02 2.4330e-03 -7.9298e-05 12 8 8 10 0 0 -26.71 21.46 0.18 0.00243 -0.00723 160 39 1 5 0 302.810 26.11 20.01 21.46 6.82 30.4 946.06 -261100 -233276 -203419 -242649 -258138 -273919 -210117 -237827 -196097 -228276 -221770 -209159 -150229 -173109 -116212 -107918 -68423 -61186 -44463 -73859 -56491 -56731 10983 -92878 -2138 -85458 -28297 -83264 -36005 -85806 -8980 -27583 17716 -34213 4970 -29341 14042 -22868 31470 -6180 22005 6957 16923 2875 32381 11415 30248 19541 16560 4137 23527 18229 23580 19031 17009 16249 12862 13255 14120 12339 9827 9975 11298 13462 8686 8856 5546 8324 4092 7754 6221 7133 2056 3465 -1871 56 -3250 -698 -2791 2266 -2285 2234 -2962 -1351 -975 -52 697 1700 961 1700 -1393 -509 -3612 -1611 -1286 -1091 -1150 467 -221 -261 -1456 -2798 -3613 -512 -894 -2474 -1324 -1037 -1018 140 752 -191 -40 -34 -504 -1080 581 -50 1162 881 801 369 1768 914 2158 565 -1178 289 1392 390 548 -470 -530 -419 519 -51 -256 359 630 -440 -112 -1631 -3283 -2506 -1876 -2797 -3246 -4090 -1938 -2866 -1865 -3223 -3259 -3178 -1905 -3356 -1808 -1866 -907 -846 -551 -1277 -814 -817 85 -2168 -21 -1995 -375 -1920 -560 -2428 -166 -731 347 -1049 109 -955 336 -857 907 -274 807 317 736 147 1272 577 1339 1044 993 314 1689 1542 2082 1915 1823 1818 1503 1504 1543 1384 1213 1401 1660 2195 1548 1593 1092 1715 1007 2074 1791 2057 593 908 -466 13 -766 -177 -868 806 -996 984 -1485 -708 -544 -30 415 1009 565 942 -752 -266 -2002 -980 -918 -919 -1048 477 -239 -275 -1432 -2487 -3265 -466 -806 -2370 -1359 -1168 -1306 190 1126 -303 -63 -53 -765 -1633 893 -80 1932 1462 1273 560 2567 1288 2935 765 -1640 447 2473 743 1154 -1074 -1221 -1035 1352 -136 -659 922 1660 -1095 -259 -3618 SS 20210320T120819.4Z 7749.505780 84 1 48.82 2 77.05 101.60 110.36 29.74 0.00 1 0.00 1 0 17 3.164e-01 7.867e-03 2.646e-02 7.664e-04 6.694845e-01 4.216968e-04 7.622476e-03 -6.000000e+00 1.902146e-01 226.50 -2.00 3.52 -2.00 320.51 0.00e+00 1.684158e-03 1.644794e-04 9.807538e-04 -6.000000e+00 8.247540e-03 277.32 -2.00 20.00 -2.00 320.00 0.00e+00 4.345 0.001 302.00 328.00 3 4.8000e-01 1.2768e-03 5.5945e-02 -6.0000e+00 4.7191e-01 3.9713e-02 1.6510e-03 3.5624e-02 -6.0000e+00 5.1129e-01 -3.7604e-02 1.6448e-03 1.9084e-02 -6.0000e+00 3.0387e-01 5.9991e-03 8.1924e-04 6.4469e-03 -6.0000e+00 1.2875e-01 2.0183e-03 -4.9694e-04 2.2154e-05 7.8531e-05 -6.0000e+00 9.4037e-03 1.0048e-03 -4.2797e-05 11 8 0 10 0 0 3.37 21.47 0.21 0.00100 -0.00273 553 133 1 5 0 87.310 26.11 19.97 21.47 8.85 30.4 956.44 -107869 -115211 -105009 -119532 -115746 -123581 -104259 -101699 -84761 -82279 -79395 -63262 -56342 -45547 -34530 -22744 -22632 -17040 -20071 -12748 -22085 -15481 -17533 -11886 -15107 -6782 -14204 -11985 -16635 -8288 -4808 -927 -2061 -1882 -7941 -5997 -5865 -1330 993 2204 602 1382 1321 1866 317 1723 1527 1673 76 899 3094 2693 1781 2780 873 1414 691 448 225 104 904 1663 2136 3165 1637 -895 458 -1218 1265 1610 736 605 -48 76 -297 -1623 -988 -2308 -849 -595 -1065 -535 -1599 -1914 -333 -243 544 611 1502 666 360 31 -829 -298 473 137 -270 1174 741 -329 -531 -2006 -2112 205 546 -1361 -378 -806 -250 490 986 279 130 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