File name: Pandora64s1_NewHavenCT_20210417_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T230628.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v3d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210417_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210417 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210417T111748.3Z 7777.470698 71 1 16.68 2 78.02 86.28 106.61 34.47 0.00 1 0.00 1 0 25 6.630e-01 1.502e-02 2.443e-01 3.760e-03 8.640992e-01 2.159694e-03 9.703217e-03 -6.000000e+00 4.020880e-01 228.71 -2.00 3.52 -2.00 321.31 0.00e+00 3.449321e-03 1.078943e-03 8.385933e-04 -6.000000e+00 1.789342e-02 280.31 -2.00 20.00 -2.00 320.83 0.00e+00 4.672 0.002 302.00 328.00 3 1.7955e+00 7.3459e-03 6.6565e-02 -6.0000e+00 1.0039e+00 1.9262e-01 1.0546e-02 4.8147e-02 -6.0000e+00 1.0867e+00 -2.7520e-01 1.1152e-02 2.5444e-02 -6.0000e+00 6.4366e-01 1.1347e-01 5.2080e-03 8.6230e-03 -6.0000e+00 2.7161e-01 3.0635e-04 -2.5346e-03 1.0069e-04 1.1162e-04 -6.0000e+00 1.9736e-02 2.1486e-03 -3.4598e-04 12 9 9 12 1 1 99.95 21.39 0.12 0.00215 -0.01690 40 30 1 5 0 392.780 26.00 19.98 21.39 10.65 30.9 970.66 19315 -220272 -122282 -303618 -184929 -254828 -180444 -282622 900000 -263862 21934 -209688 -24606 -187324 -20996 -106344 51663 -108080 19754 -84556 -40366 -81258 88736 -67826 3446 -59154 -16717 -65609 40324 -52640 27065 -13012 11597 -8461 6527 -15830 11694 -344 5498 9623 16128 17305 13242 15608 2302 15958 14461 19995 3006 7951 3313 15933 7427 13044 2701 9868 3544 10380 3575 6570 4437 9105 5316 10239 5067 2747 2357 4351 536 5657 2363 4674 -553 2788 -1874 270 -3609 -2035 -2988 701 -2135 705 -1367 -1578 -391 -944 -29 736 1665 841 -312 -433 -1537 -1808 -386 -715 -691 653 946 -1085 -891 -3012 -2829 -835 159 -2013 -474 -1332 -437 -11 1047 236 51 280 -84 -1108 567 -204 1046 603 168 -54 1671 892 2084 482 -1512 555 939 190 636 -354 -557 -563 517 -304 -286 637 729 -548 55 -1359 71 -1835 -448 -5380 -1048 -3057 -1143 -5180 900000 -5452 80 -3634 -99 -4235 -126 -1807 227 -2413 132 -1691 -525 -1625 390 -1424 38 -1281 -240 -1531 384 -1386 406 -347 282 -259 167 -543 351 -13 239 470 818 930 781 915 159 999 967 1368 265 748 375 1786 926 1685 407 1450 565 1513 542 973 717 1592 1111 2298 1243 695 632 1229 167 1897 871 1708 -203 917 -582 82 -1138 -640 -1128 305 -1115 382 -816 -1004 -263 -669 -21 534 1176 567 -200 -271 -993 -1298 -319 -651 -728 725 1096 -1245 -1002 -3090 -2715 -815 164 -2203 -551 -1607 -591 -16 1652 392 85 455 -131 -1729 896 -337 1781 1028 276 -84 2486 1283 3053 699 -2247 850 1566 359 1254 -754 -1206 -1305 1204 -734 -696 1543 1716 -1281 120 -2963 SS 20210417T112330.9Z 7777.474663 74 1 47.74 2 76.95 87.20 106.01 35.61 0.00 1 0.00 1 0 25 5.925e-01 1.603e-02 2.327e-01 4.575e-03 8.053298e-01 2.626636e-03 9.080300e-03 -6.000000e+00 3.590883e-01 228.71 -2.00 3.52 -2.00 321.21 0.00e+00 5.752934e-03 1.271946e-03 1.375366e-03 -6.000000e+00 1.585310e-02 280.31 -2.00 20.00 -2.00 320.71 0.00e+00 4.315 0.001 302.00 328.00 3 3.5342e+00 8.7978e-03 6.1581e-02 -6.0000e+00 8.9449e-01 1.8629e-01 1.2346e-02 4.4305e-02 -6.0000e+00 9.6732e-01 -2.1933e-01 1.2963e-02 2.5182e-02 -6.0000e+00 5.7509e-01 8.2635e-02 6.1242e-03 1.0468e-02 -6.0000e+00 2.4434e-01 7.8134e-05 -1.6356e-03 1.2698e-04 1.3248e-04 -6.0000e+00 1.7630e-02 4.8474e-04 -1.7246e-04 12 8 8 10 0 0 99.94 21.39 0.28 0.00048 -0.01181 27 6 1 5 0 1767.610 26.00 20.02 21.39 10.87 31.0 971.97 -271389 900000 -237463 -171668 -287432 -117367 -253411 -45655 -161534 14728 -188749 -118059 -154564 -99015 -50305 -53446 -10174 11183 -44499 8748 31423 29495 900000 41749 24493 -24808 -29371 -34808 22978 -43375 37731 -1761 44103 -26810 42572 -35105 29988 -28707 43489 -8068 51059 -2816 30719 193 19209 7989 27857 -1565 16068 -18664 27194 -2828 16885 649 15608 969 9684 2762 9628 -1584 3267 5722 7866 6479 9779 -1486 1663 4622 2129 3341 4787 3288 -2054 2075 -2694 -2482 -2325 -3831 -4893 -198 -3042 3304 -3108 -1882 -1500 -523 -187 1173 637 522 -2403 771 -4719 -1174 -1513 1769 -1360 1438 1329 172 -1228 -1095 -4166 1508 -257 -1395 -1608 1350 -884 1206 1311 669 -29 -380 -350 -961 107 -419 167 590 56 118 1193 1191 1735 290 -1763 397 896 -248 744 -1159 -402 -932 855 58 52 317 1337 -736 152 -1412 -4343 900000 -3301 -1244 -5957 -523 -4254 -204 -1441 66 -2525 -1053 -2514 -1297 -519 -685 -96 97 -719 88 254 247 900000 361 266 -463 -581 -728 288 -1183 610 -47 922 -1104 902 -1621 878 -1709 1529 -554 2143 -205 1789 15 1325 606 1922 -147 1365 -2492 2621 -411 2213 109 2363 167 1644 493 1565 -291 611 1119 1722 1613 2431 -413 468 1347 725 1269 1808 1279 -806 763 -939 -793 -740 -1339 -2041 -89 -1633 1893 -1947 -1235 -1049 -380 -140 874 469 364 -1623 512 -3182 -839 -1258 1584 -1447 1609 1557 197 -1382 -1102 -4065 1445 -266 -1523 -1894 1606 -1207 1742 2077 1064 -46 -615 -542 -1473 167 -684 271 956 92 184 1780 1776 2499 412 -2559 598 1539 -463 1448 -2447 -864 -2145 1985 139 127 772 3139 -1719 331 -3057 SS 20210417T112910.2Z 7777.478590 77 1 48.41 2 75.89 88.13 105.40 36.73 0.00 1 0.00 1 0 25 5.275e-01 1.189e-02 9.272e-02 2.837e-03 7.456443e-01 1.603772e-03 8.638259e-03 -6.000000e+00 3.198170e-01 228.71 -2.00 3.52 -2.00 320.92 0.00e+00 3.412838e-03 7.066313e-04 2.704060e-03 -6.000000e+00 1.392184e-02 280.31 -2.00 20.00 -2.00 320.40 0.00e+00 4.011 0.001 302.00 328.00 3 3.0085e+00 5.0984e-03 5.7669e-02 -6.0000e+00 7.9676e-01 1.1204e-01 6.8738e-03 4.2181e-02 -6.0000e+00 8.6138e-01 -1.3272e-01 6.9428e-03 2.3015e-02 -6.0000e+00 5.1195e-01 4.9395e-02 3.3523e-03 7.5472e-03 -6.0000e+00 2.1658e-01 1.9182e-04 -1.0049e-03 7.9606e-05 1.1337e-04 -6.0000e+00 1.5689e-02 -8.4116e-04 -5.5900e-05 12 8 8 10 0 0 99.91 21.39 0.12 -0.00084 -0.00839 77 19 1 5 0 628.470 26.11 20.00 21.39 11.07 31.0 973.41 -179672 -201588 -191945 -167885 -217583 -143523 -186417 -125554 -113654 -142444 -164179 -123890 -124460 -86159 -65373 -64286 -46488 -33659 -46657 -27599 -18045 -23982 -8881 -28258 -9659 -17479 -21530 -21659 -8805 -28839 -10440 -7800 -454 -9769 6717 -24950 6038 -2351 8229 -84 11681 3923 14940 4198 9560 2328 6201 1371 4056 -4025 9152 2702 7642 5812 7208 635 2962 1799 2959 3121 2221 3101 5612 5722 4705 588 2110 626 1893 2587 583 1992 740 306 -1739 -3023 -3876 -2763 -2285 -66 -1336 -69 -1464 -2440 -717 -652 233 975 1235 157 -1303 -827 -2981 -1182 -247 238 -744 1369 796 -227 -969 -2100 -2938 -75 164 -1319 -531 31 -338 814 1404 825 566 280 -412 -795 95 -371 523 425 -89 -232 1284 887 1031 141 -1544 57 1037 133 424 -863 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