File name: Pandora64s1_NewHavenCT_20210508_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T231013.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v3d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210508_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210508T114855.7Z 7798.492311 159 1 49.41 2 67.45 86.45 56.30 125.75 0.00 1 0.00 1 0 17 6.871e-02 9.117e-03 2.417e-02 2.326e-03 4.504962e-01 1.257660e-03 5.287790e-03 -6.000000e+00 4.193702e-02 230.50 -2.00 3.52 -2.00 318.97 0.00e+00 4.750942e-04 2.994098e-04 4.525164e-04 -6.000000e+00 1.830969e-03 282.62 -2.00 20.00 -2.00 318.29 0.00e+00 2.586 0.000 302.00 328.00 3 4.6547e+00 3.4724e-03 3.5381e-02 -6.0000e+00 1.0485e-01 1.9188e-02 3.9987e-03 2.3709e-02 -6.0000e+00 1.1316e-01 -7.3665e-03 2.9227e-03 1.1700e-02 -6.0000e+00 6.7248e-02 -3.8608e-03 1.5263e-03 3.3011e-03 -6.0000e+00 2.8405e-02 2.0857e-04 -3.0938e-04 7.1348e-05 3.8485e-05 -6.0000e+00 2.0448e-03 8.2590e-05 -2.8192e-05 11 8 0 10 0 0 90.81 21.18 0.12 0.00008 -0.00224 19 5 1 5 0 2600.090 25.90 19.99 21.18 17.31 31.8 1005.57 -18323 -10712 -13689 -2919 -42451 -14575 -37093 -5971 -16016 3316 -34683 -9594 -3566 -7023 -7407 -2829 -7316 11361 -7441 4384 2050 3355 3600 7050 -1382 3445 -6226 -5320 -5944 -2434 -448 -59 1936 752 -1878 -2348 -1091 -2520 -657 -1363 787 69 1208 -1391 -144 -933 1042 -1005 1371 -3384 2777 -167 2059 421 906 -11 3201 87 1593 303 972 1208 3208 2775 1415 -1931 -179 -828 1036 1420 581 61 170 -331 -143 -1418 -1112 -2157 -1219 46 -1894 -420 -2136 -2222 -410 -529 418 387 1231 691 400 616 -1373 -143 497 686 -323 1279 787 -306 -679 -1840 -2338 378 233 -1514 -335 -60 -302 402 1388 203 -94 454 -414 -338 241 -263 320 527 -111 -32 661 15 1142 678 -1628 592 681 307 495 -745 -642 -460 763 -198 -441 535 577 -338 -22 -872 -499 -293 -397 -70 -1434 -386 -1360 -182 -598 108 -1714 -423 -178 -432 -512 -209 -606 844 -700 385 187 306 350 712 -160 396 -779 -629 -703 -298 -61 -9 316 124 -305 -408 -203 -566 -174 -398 243 23 405 -481 -50 -327 358 -358 487 -1335 1130 -73 936 207 458 -5 1661 46 816 159 513 696 1979 1761 894 -1250 -113 -542 715 1049 460 50 134 -247 -101 -926 -720 -1439 -867 36 -1615 -391 -2069 -2285 -430 -585 477 447 1387 738 413 595 -1348 -140 534 796 -395 1697 1044 -407 -847 -2207 -2736 456 290 -2000 -450 -85 -448 622 2245 323 -149 697 -603 -494 348 -399 497 837 -176 -50 1009 22 1640 939 -2258 856 1042 493 818 -1291 -1124 -826 1438 -379 -860 1047 1112 -646 -40 -1592 SS 20210508T115914.2Z 7798.499469 162 1 48.30 2 65.51 88.11 54.75 128.18 0.00 1 0.00 1 0 17 2.786e-02 7.833e-03 8.354e-03 1.093e-03 4.214656e-01 5.884339e-04 4.978638e-03 -6.000000e+00 1.700367e-02 230.50 -2.00 3.52 -2.00 318.52 0.00e+00 4.621272e-04 1.220733e-04 2.906979e-04 -6.000000e+00 7.424324e-04 282.62 -2.00 20.00 -2.00 317.83 0.00e+00 2.396 0.000 302.00 328.00 3 3.4703e+00 1.5996e-03 3.2916e-02 -6.0000e+00 4.2511e-02 6.9154e-03 1.8184e-03 2.2104e-02 -6.0000e+00 4.5883e-02 -4.8062e-03 1.2478e-03 1.0847e-02 -6.0000e+00 2.7268e-02 -3.3765e-03 6.4969e-04 3.0333e-03 -6.0000e+00 1.1516e-02 8.5541e-04 -4.7662e-04 3.3356e-05 3.4900e-05 -6.0000e+00 8.2918e-04 3.9112e-04 -5.5863e-05 11 8 0 10 0 0 46.16 21.18 0.12 0.00039 -0.00319 75 18 1 5 0 643.870 25.90 20.00 21.18 17.58 31.8 1007.26 -1263 -8378 -2645 -14306 -13062 -10468 -5875 -6316 -2001 -7666 -10977 -8124 -1902 -2627 -934 -14 -1046 -842 -347 1012 -1104 122 541 1066 -302 955 -437 -2565 -2298 -1350 1254 564 1926 -723 -4845 -3491 -2727 -1449 -208 941 -609 -664 -226 -562 -156 170 -354 228 -1057 -852 1309 1293 668 1517 213 765 1519 387 77 454 502 1271 1476 2737 1030 -1180 -351 -1295 904 1526 580 485 -106 482 -74 -1082 -863 -1981 -557 -373 -1180 -644 -1988 -2016 -542 -481 451 543 1098 448 231 403 -908 -343 844 199 -205 1219 800 -308 -526 -1895 -2082 336 480 -1341 -286 -601 -267 431 1001 448 184 130 -458 -392 274 -401 682 537 -169 -158 684 -16 1137 641 -1294 345 876 265 475 -574 -591 -419 617 -150 -395 573 304 -387 87 -814 -46 -328 -100 -562 -516 -417 -246 -277 -93 -397 -606 -495 -130 -214 -87 -1 -116 -100 -40 121 -136 15 71 149 -45 146 -67 -380 -335 -208 211 105 392 -151 -1007 -760 -669 -389 -66 339 -225 -258 -90 -226 -63 69 -144 93 -444 -377 620 659 345 826 121 446 892 227 45 265 309 801 1011 1967 737 -817 -238 -911 658 1233 477 407 -92 392 -55 -785 -594 -1399 -433 -313 -1062 -608 -2012 -2164 -588 -551 510 620 1285 498 250 407 -890 -348 932 236 -260 1607 1086 -407 -680 -2286 -2446 408 623 -1765 -395 -845 -387 667 1563 703 289 193 -666 -554 394 -585 1044 846 -265 -242 1010 -23 1591 901 -1811 484 1331 419 762 -963 -993 -741 1108 -280 -727 1060 556 -706 152 -1434 SS 20210508T123745.6Z 7798.526222 227 1 29.16 2 58.28 94.56 49.45 138.12 0.00 1 0.00 1 0 17 2.135e-02 8.821e-03 9.782e-03 2.404e-03 3.341101e-01 1.292864e-03 3.986695e-03 -6.000000e+00 1.303357e-02 230.50 -2.00 3.52 -2.00 317.65 0.00e+00 1.426665e-04 2.064604e-04 1.965077e-04 -6.000000e+00 5.690452e-04 282.62 -2.00 20.00 -2.00 316.93 0.00e+00 1.895 0.000 302.00 328.00 3 5.0141e+00 3.4414e-03 2.6032e-02 -6.0000e+00 3.2585e-02 1.4255e-02 3.8603e-03 1.7446e-02 -6.0000e+00 3.5168e-02 3.8262e-03 2.3926e-03 8.5269e-03 -6.0000e+00 2.0900e-02 -6.9900e-03 1.1956e-03 2.3562e-03 -6.0000e+00 8.8280e-03 3.3490e-04 -2.4161e-04 7.4471e-05 2.8111e-05 -6.0000e+00 6.3550e-04 -2.6233e-04 -4.0578e-05 12 9 1 12 1 1 97.84 21.18 0.01 -0.00026 -0.00208 11 5 1 5 0 2414.790 25.90 19.99 21.18 18.12 32.0 1010.14 117 -7057 4390 -5021 -11902 -3439 -4492 -5705 -575 -2210 -8615 -7976 -1708 -2397 -35 -1072 225 1681 1343 -69 3789 318 2308 1391 1713 1127 1184 437 458 -596 2533 -503 2865 142 -2961 -2224 -2430 -1290 539 -283 329 -1313 -85 -1115 -668 373 -278 -1020 -746 -2141 1310 372 142 1006 249 792 1162 302 158 858 35 1315 1659 2614 1380 -1126 -653 -1379 584 2000 797 618 -232 882 -352 -1123 -1410 -2421 -1103 334 -1715 -514 -2311 -1831 -297 -246 220 260 1494 723 106 520 -1045 -433 832 274 269 1044 1087 -185 -600 -1996 -1990 335 367 -1581 -366 -262 -216 566 938 324 67 -173 -517 -579 477 -148 482 697 43 -120 665 -297 1277 576 -1507 846 688 485 354 -522 -503 -648 672 -142 -572 671 504 -361 -53 -919 9 -582 345 -396 -938 -255 -367 -530 -56 -214 -899 -915 -213 -348 -6 -192 42 309 257 -14 743 65 488 315 405 276 284 99 101 -138 622 -137 825 41 -849 -669 -788 -488 228 -137 162 -684 -45 -597 -358 197 -145 -536 -391 -1183 755 221 90 665 169 552 816 212 109 596 25 993 1293 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