File name: Pandora64s1_NewHavenCT_20210510_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T231013.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v3d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210510_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210510 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210510T122633.9Z 7800.518448 201 1 47.75 2 60.03 92.17 55.92 107.89 0.00 1 0.00 1 0 17 2.031e-02 9.361e-03 8.614e-03 2.453e-03 2.923056e-01 1.317960e-03 3.495532e-03 -6.000000e+00 1.241055e-02 230.67 -2.00 3.52 -2.00 317.53 0.00e+00 4.788903e-04 2.013601e-04 1.841423e-04 -6.000000e+00 5.419295e-04 282.84 -2.00 20.00 -2.00 316.81 0.00e+00 1.993 0.000 302.00 328.00 3 5.3112e+00 3.5027e-03 2.5273e-02 -6.0000e+00 3.1039e-02 6.6964e-02 3.9223e-03 1.5276e-02 -6.0000e+00 3.3489e-02 -5.1061e-03 2.3793e-03 7.4609e-03 -6.0000e+00 1.9902e-02 -3.6062e-03 1.1715e-03 2.0863e-03 -6.0000e+00 8.4086e-03 2.3841e-04 -8.4441e-05 7.6820e-05 2.5164e-05 -6.0000e+00 6.0460e-04 -1.0890e-03 1.6012e-05 12 8 8 10 0 0 99.99 21.18 0.10 -0.00109 -0.00172 40 10 1 5 0 1193.490 25.90 20.00 21.18 17.02 31.9 1004.26 -393 -912 -2971 -2616 -12592 -2197 -6867 2343 -256 3124 -8514 -5482 -2055 -495 -41 -999 -1574 -59 793 2774 2020 1989 3603 1667 295 3903 285 -1012 -3222 1269 770 272 2850 878 -3817 -2940 -1614 -1635 -435 -122 -163 -670 -456 -1271 -363 475 -429 -851 -1070 -2035 1570 453 1004 1155 -125 722 1484 116 677 -9 613 1176 1928 2236 1579 -1596 -399 -1588 661 1526 753 482 322 796 -414 -1508 -1388 -3476 -929 -306 -1555 -793 -2017 -2248 -57 -315 378 611 1777 452 334 87 -1600 -580 533 536 -58 1652 874 -171 -617 -1636 -2551 -79 378 -1120 -595 -141 115 933 1147 207 441 -143 -798 -660 158 -426 419 363 85 189 703 -132 1040 266 -1731 798 913 215 377 -615 -754 -303 553 -110 -277 758 499 -227 -224 -991 -36 -89 -296 -251 -1235 -197 -699 243 -28 361 -1039 -708 -294 -80 -7 -198 -325 -13 174 622 458 451 843 420 78 1025 76 -255 -800 310 204 77 857 265 -1142 -918 -528 -628 -196 -59 -84 -358 -250 -701 -199 257 -229 -451 -565 -1118 893 276 642 776 -86 508 1047 82 469 -6 429 883 1539 1857 1270 -1229 -294 -1192 536 1363 683 448 292 721 -348 -1156 -1047 -2655 -719 -264 -1434 -794 -2151 -2426 -65 -379 470 769 2179 529 379 91 -1604 -586 578 611 -73 2136 1161 -220 -783 -1951 -3009 -97 493 -1473 -822 -202 168 1428 1817 327 662 -210 -1095 -876 212 -603 629 542 128 277 1039 -186 1393 358 -2303 1081 1267 319 583 -939 -1187 -498 919 -190 -489 1345 879 -388 -372 -1670 SS 20210510T125949.6Z 7800.541546 225 1 1.21 2 53.81 98.02 50.13 114.84 0.00 1 0.00 1 0 17 1.211e-02 8.445e-03 3.287e-03 1.732e-03 2.457573e-01 9.400540e-04 2.967855e-03 -6.000000e+00 7.398922e-03 230.67 -2.00 3.52 -2.00 315.99 0.00e+00 3.290214e-04 9.842112e-05 5.909087e-05 -6.000000e+00 3.231257e-04 282.85 -2.00 20.00 -2.00 315.33 0.00e+00 1.689 0.000 302.00 328.00 3 1.5657e+00 2.4436e-03 2.1315e-02 -6.0000e+00 1.8505e-02 1.7360e-02 2.7106e-03 1.2772e-02 -6.0000e+00 1.9968e-02 -3.4844e-03 1.5579e-03 6.2189e-03 -6.0000e+00 1.1866e-02 -1.6057e-03 7.0765e-04 1.7240e-03 -6.0000e+00 5.0118e-03 1.5064e-02 -4.1025e-04 5.3189e-05 2.2932e-05 -6.0000e+00 3.6055e-04 -5.2188e-04 -4.4068e-05 12 9 1 12 1 1 96.57 21.17 0.16 -0.00052 -0.00360 12 143 1 5 0 79.410 25.90 19.99 21.17 17.65 31.8 1007.83 -241 -703 -631 -3686 -5193 -2413 -195 556 2402 -355 -2661 -1787 -234 -28 2371 783 -514 377 502 1578 1568 -414 1207 397 944 1004 1119 -1700 -730 -282 1728 -280 2792 -120 -4554 -2347 -1381 -1460 314 300 -933 -1507 -557 -873 -178 -112 -407 -294 -674 -336 1321 1215 927 1331 359 802 1002 400 310 386 646 1302 1206 2410 531 -1436 -878 -1504 502 1600 286 555 -4 754 77 -755 -798 -1625 -561 16 -1424 -799 -1879 -2147 -492 -161 49 331 810 323 483 400 -954 -388 741 491 -209 1154 605 -338 -360 -1713 -2010 187 697 -1044 -173 -1160 -315 397 855 440 180 -91 -243 -204 487 -234 803 486 80 -235 875 -107 816 794 -880 468 989 441 733 -443 -910 -519 736 -133 -340 278 314 -378 -158 -1001 -52 -158 -142 -772 -1017 -464 -40 125 574 -89 -678 -449 -65 -9 758 272 -186 142 193 624 622 -167 500 163 399 434 469 -732 -298 -116 747 -122 1266 -55 -2054 -1088 -711 -827 195 197 -660 -1053 -396 -619 -126 -82 -293 -208 -471 -240 937 911 732 1042 289 656 826 328 251 316 555 1137 1123 2198 494 -1257 -772 -1333 458 1528 293 555 -4 735 73 -682 -671 -1357 -503 15 -1446 -842 -2015 -2441 -570 -196 59 408 983 386 554 441 -996 -407 829 579 -251 1489 769 -433 -434 -2029 -2351 228 872 -1330 -230 -1568 -446 568 1257 638 257 -126 -313 -263 637 -311 1093 693 115 -332 1190 -145 1087 1009 -1098 599 1294 611 1018 -633 -1298 -773 1110 -209 -530 439 490 -594 -242 -1496 SS 20210510T131750.0Z 7800.554051 241 1 2.05 2 50.48 101.43 47.13 119.02 0.00 1 0.00 1 0 17 1.148e-02 8.374e-03 4.642e-03 2.602e-03 2.261142e-01 1.413910e-03 2.737771e-03 -6.000000e+00 7.008898e-03 230.67 -2.00 3.52 -2.00 315.77 0.00e+00 3.740891e-04 1.408806e-04 4.842617e-05 -6.000000e+00 3.061001e-04 282.85 -2.00 20.00 -2.00 315.11 0.00e+00 1.568 0.000 302.00 328.00 3 2.3530e+00 3.6672e-03 1.9721e-02 -6.0000e+00 1.7529e-02 1.4332e-02 4.0622e-03 1.1760e-02 -6.0000e+00 1.8916e-02 1.3519e-03 2.3300e-03 5.7290e-03 -6.0000e+00 1.1241e-02 -3.6666e-03 1.0488e-03 1.5936e-03 -6.0000e+00 4.7474e-03 7.9953e-03 -3.0530e-04 8.0273e-05 2.1513e-05 -6.0000e+00 3.4156e-04 -8.8990e-04 -7.5728e-05 12 9 1 12 9 1 95.82 21.15 0.09 -0.00089 -0.00318 5 37 2 5 0 312.240 25.90 20.00 21.15 18.23 32.1 1011.14 702 786 -1731 -1807 -4326 -2393 -1904 1168 1342 900 -4269 -441 -869 -763 1523 174 -227 51 526 1392 892 55 687 484 440 892 452 -216 -98 -869 2336 224 2897 -49 -4485 -2594 -725 -902 1153 5 -530 -1031 -139 -1162 -203 17 -195 -367 -774 -620 550 875 1161 1173 32 210 580 310 87 199 610 984 1096 1626 1125 -1220 -553 -1629 736 2085 226 579 -34 948 -189 -753 -1061 -1541 -648 41 -1485 -338 -2216 -1797 -739 -338 -111 795 829 206 63 603 -760 70 767 664 -375 1587 635 -583 -498 -1626 -1804 515 145 -1297 -212 -571 -446 489 667 366 316 23 -483 -28 415 -298 326 565 -66 -284 994 2 1071 978 -785 524 813 296 612 -551 -653 -494 639 -390 -170 490 221 -411 186 -1269 165 192 -432 -406 -918 -503 -429 283 352 242 -1190 -121 -269 -253 551 65 -87 20 215 584 376 23 302 214 201 415 205 -95 -41 -374 1034 102 1379 -23 -2115 -1262 -372 -522 744 3 -385 -754 -103 -867 -150 13 -143 -264 -550 -450 406 678 909 961 27 174 484 265 74 171 529 885 1015 1551 1059 -1080 -482 -1433 675 2030 230 585 -35 945 -181 -672 -912 -1308 -572 39 -1485 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