File name: Pandora64s1_NewHavenCT_20210531_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T231534.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v3d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210531_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210531T172502.8Z 7821.725726 464 1 47.72 2 20.69 203.98 119.93 269.42 0.00 1 0.00 1 0 17 1.126e-02 8.755e-03 1.584e-03 1.070e-03 1.825347e-01 5.898472e-04 2.214162e-03 -6.000000e+00 6.919215e-03 232.07 -2.00 3.52 -2.00 314.99 0.00e+00 3.192899e-04 5.029354e-05 4.140384e-05 -6.000000e+00 3.032456e-04 285.01 -2.00 20.00 -2.00 314.37 0.00e+00 1.069 0.000 302.00 328.00 3 5.1541e+00 1.5231e-03 1.4484e-02 -6.0000e+00 1.7352e-02 3.1657e-02 1.6791e-03 9.5169e-03 -6.0000e+00 1.8692e-02 -1.5646e-03 9.5930e-04 4.6263e-03 -6.0000e+00 1.1110e-02 -2.4726e-03 4.1903e-04 1.2750e-03 -6.0000e+00 4.6929e-03 8.5285e-04 -2.6782e-05 3.2952e-05 1.8316e-05 -6.0000e+00 3.3531e-04 -3.3368e-03 6.1367e-05 11 8 0 10 0 0 99.88 21.32 0.10 -0.00334 -0.00354 28 7 1 5 0 1703.770 26.00 20.01 21.32 21.92 32.6 1027.73 1299 -748 435 -2632 -4009 -1367 -228 576 2039 770 -3703 -1672 -33 -163 710 463 -408 992 408 1684 1222 -72 769 935 355 1383 618 -1238 -702 252 1292 334 2075 202 -4567 -1871 -1893 -1200 561 303 -959 -839 -298 -1097 -541 84 -445 -156 -890 -858 1218 872 531 1302 102 790 1246 434 391 357 235 1340 1037 2325 800 -1545 -610 -1635 386 1671 572 452 -51 844 150 -872 -985 -2236 -869 -72 -1100 -580 -1838 -1965 -467 -435 109 162 927 576 228 157 -1348 -444 760 147 -40 1427 1061 -206 -398 -1589 -1904 127 184 -1107 -248 -507 -178 580 1097 583 339 -84 -418 -554 177 -518 530 552 70 -26 842 48 1123 902 -1136 336 954 430 553 -596 -855 -309 499 -70 -410 411 228 -505 -80 -867 407 -247 141 -838 -1178 -391 -69 191 675 263 -1285 -599 -13 -71 318 219 -197 490 207 871 635 -37 390 493 194 761 332 -660 -352 125 663 180 1108 107 -2511 -989 -1116 -777 400 232 -783 -675 -244 -899 -439 70 -359 -122 -681 -664 975 735 448 1134 91 712 1127 391 348 322 212 1280 1008 2297 793 -1431 -556 -1488 361 1640 601 467 -54 851 146 -804 -878 -1959 -771 -67 -1094 -623 -2013 -2189 -553 -524 136 206 1155 679 257 168 -1409 -459 829 169 -49 1776 1347 -254 -480 -1817 -2236 151 226 -1424 -321 -682 -242 818 1527 824 453 -108 -514 -681 221 -656 690 754 96 -35 1107 62 1378 1096 -1352 405 1210 553 736 -784 -1153 -418 710 -100 -603 611 337 -731 -117 -1234 SS 20210531T172937.4Z 7821.728906 467 1 29.88 2 21.06 206.77 120.75 270.16 0.00 1 0.00 1 0 17 1.210e-02 9.403e-03 2.554e-03 1.706e-03 1.833461e-01 9.377415e-04 2.224145e-03 -6.000000e+00 7.432864e-03 232.07 -2.00 3.52 -2.00 315.05 0.00e+00 3.274163e-04 8.105267e-05 5.480310e-05 -6.000000e+00 3.257563e-04 285.01 -2.00 20.00 -2.00 314.43 0.00e+00 1.071 0.000 302.00 328.00 3 5.4955e+00 2.4238e-03 1.4533e-02 -6.0000e+00 1.8640e-02 3.5639e-02 2.6747e-03 9.5592e-03 -6.0000e+00 2.0080e-02 -3.5268e-03 1.5265e-03 4.6494e-03 -6.0000e+00 1.1935e-02 -1.4710e-03 6.6774e-04 1.2799e-03 -6.0000e+00 5.0413e-03 6.0305e-04 -3.4668e-05 5.2368e-05 1.8364e-05 -6.0000e+00 3.6021e-04 -3.4414e-03 5.8483e-05 12 9 9 12 1 1 99.87 21.32 0.18 -0.00344 -0.00370 11 5 1 5 0 2474.900 26.00 20.01 21.32 22.29 32.6 1029.76 -182 -74 1 -2175 -4241 -1199 -1585 1378 2291 3 -4540 -890 -827 -396 599 735 -768 1723 137 2209 1277 252 260 1879 334 1458 559 -594 -637 477 1014 841 2364 57 -4137 -2114 -2589 -1425 110 124 -835 -940 -163 -1112 -197 370 -353 -344 -941 -1335 1187 461 1000 1213 175 755 1257 299 560 149 626 1145 1354 2117 883 -1445 -372 -1883 510 2014 775 674 125 550 239 -1102 -1447 -2414 -813 -187 -1468 -911 -2080 -2245 -175 -296 343 305 1050 506 111 224 -1473 -879 647 355 25 1359 866 -299 -564 -1454 -2081 278 445 -1335 -368 -321 -304 673 1161 533 460 0 -584 -678 153 -439 634 820 10 93 737 264 1131 865 -1198 603 749 417 609 -354 -923 -322 727 -77 -368 345 285 -657 -151 -1055 -58 -24 0 -647 -1246 -341 -484 424 754 1 -1583 -315 -324 -162 267 346 -372 842 66 1072 625 123 132 976 182 797 298 -297 -317 234 519 448 1252 30 -2134 -1114 -1529 -919 78 94 -677 -753 -133 -906 -159 305 -282 -268 -717 -1032 945 388 834 1052 155 676 1129 268 494 134 584 1089 1303 2082 870 -1329 -336 -1707 473 2039 806 719 131 552 231 -1012 -1287 -2104 -716 -174 -1516 -976 -2268 -2586 -205 -354 425 384 1297 614 129 247 -1530 -906 702 404 30 1680 1093 -367 -677 -1712 -2430 327 559 -1707 -473 -428 -410 940 1655 748 631 0 -742 -829 189 -551 847 1106 14 125 962 339 1428 1043 -1469 720 944 531 803 -477 -1236 -448 1025 -114 -536 509 418 -976 -217 -1492 SS 20210531T174709.2Z 7821.741079 473 1 5.46 2 22.79 216.63 123.87 273.05 0.00 1 0.00 1 0 17 1.083e-02 8.491e-03 7.900e-04 5.715e-04 1.730975e-01 3.158184e-04 2.108377e-03 -6.000000e+00 6.650408e-03 232.07 -2.00 3.52 -2.00 314.68 0.00e+00 3.072885e-04 2.530472e-05 1.978386e-05 -6.000000e+00 2.914786e-04 285.01 -2.00 20.00 -2.00 314.08 0.00e+00 1.084 0.000 302.00 328.00 3 1.7917e+00 8.1368e-04 1.4264e-02 -6.0000e+00 1.6678e-02 9.4081e-03 8.9605e-04 9.0501e-03 -6.0000e+00 1.7966e-02 2.7170e-03 5.1223e-04 4.3971e-03 -6.0000e+00 1.0679e-02 -3.7116e-03 2.2118e-04 1.2166e-03 -6.0000e+00 4.5103e-03 2.4935e-02 -3.6631e-05 1.7547e-05 1.7509e-05 -6.0000e+00 3.2233e-04 -3.3441e-03 3.6895e-05 12 9 1 12 1 1 98.97 21.35 0.22 -0.00334 -0.00362 83 182 1 5 0 62.870 26.00 20.00 21.35 23.40 32.2 1033.85 1345 -832 493 -2896 -3601 -1448 136 825 1763 362 -2969 -1527 208 -146 1256 573 -785 801 519 1719 1121 -270 610 968 754 1464 660 -717 -809 705 1553 202 2452 239 -4388 -2052 -1734 -957 103 52 -1224 -1185 -557 -1042 -648 79 -677 -159 -929 -299 1017 967 726 1347 101 744 1050 518 39 430 465 1291 1168 2283 606 -1386 -501 -1655 620 1602 334 385 -49 676 348 -516 -692 -1887 -398 -221 -882 -641 -2067 -2067 -459 -548 21 27 856 438 441 276 -786 -124 888 381 24 1242 796 -396 -349 -1489 -1693 210 581 -1294 -197 -853 -335 256 828 402 156 110 -325 -211 427 -340 478 584 -19 -125 715 80 944 969 -809 565 834 431 652 -469 -714 -374 485 -74 -395 335 140 -521 -140 -832 482 -314 182 -1069 -1219 -479 47 293 668 141 -1165 -621 92 -67 625 283 -398 414 275 927 609 -147 341 562 451 833 389 -396 -423 385 825 113 1425 138 -2491 -1188 -1050 -632 75 40 -1014 -1012 -460 -902 -556 66 -553 -125 -756 -244 822 820 613 1175 91 672 953 467 35 389 440 1235 1130 2246 601 -1278 -456 -1507 576 1633 349 412 -51 679 337 -476 -619 -1658 -352 -217 -909 -684 -2244 -2369 -536 -651 26 34 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