File name: Pandora64s1_NewHavenCT_20210626_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T232307.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v3d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210626_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210626T143920.3Z 7847.610652 355 1 44.84 2 33.43 111.95 127.29 268.70 0.00 1 0.00 1 0 17 1.094e-02 8.426e-03 5.615e-04 3.758e-04 1.576914e-01 2.068057e-04 1.902367e-03 -6.000000e+00 6.743984e-03 232.94 -2.00 3.52 -2.00 315.04 0.00e+00 2.524108e-04 1.808373e-05 4.663798e-05 -6.000000e+00 2.977766e-04 287.52 -2.00 20.00 -2.00 314.39 0.00e+00 1.198 0.000 302.00 328.00 3 2.7813e+00 5.3541e-04 1.4632e-02 -6.0000e+00 1.6935e-02 2.6253e-02 5.8961e-04 8.2769e-03 -6.0000e+00 1.8224e-02 1.4393e-03 3.3681e-04 3.9893e-03 -6.0000e+00 1.0840e-02 -4.8558e-03 1.4759e-04 1.0884e-03 -6.0000e+00 4.5806e-03 8.5801e-03 1.8741e-04 1.1610e-05 1.5439e-05 -6.0000e+00 3.2599e-04 -1.0910e-03 6.8794e-05 11 8 0 10 0 0 100.00 21.32 0.19 -0.00109 0.00032 883 213 1 5 0 50.650 26.00 20.01 21.32 31.49 33.1 1069.75 1178 -619 631 -3134 -3670 -1075 207 1588 1910 644 -2762 -1284 97 -182 1120 495 -954 592 272 1661 1063 -495 822 760 411 1223 577 -917 -552 406 1785 178 2483 -28 -4319 -2257 -1636 -1025 266 139 -1072 -1173 -385 -1121 -620 -123 -872 -390 -986 -509 1119 973 736 1342 236 801 1079 514 93 359 535 1296 1259 2257 521 -1410 -570 -1763 654 1691 479 538 -100 729 287 -658 -891 -2007 -637 -244 -1120 -576 -2066 -1972 -410 -334 202 291 939 457 352 182 -1090 -215 717 331 4 1323 789 -384 -411 -1549 -1813 203 423 -1244 -222 -699 -203 452 961 493 239 -54 -439 -332 297 -362 543 552 141 -86 647 -118 832 693 -1016 315 782 280 491 -543 -737 -333 592 -13 -345 488 235 -441 0 -874 371 -204 203 -935 -1094 -312 63 529 626 216 -930 -447 37 -76 506 236 -465 294 138 856 551 -258 403 388 217 649 298 -479 -271 196 885 93 1341 -15 -2269 -1214 -900 -652 182 106 -875 -988 -328 -955 -523 -102 -699 -301 -743 -385 877 800 631 1188 213 683 925 438 84 308 478 1227 1256 2286 507 -1273 -518 -1605 594 1680 509 548 -108 746 271 -605 -757 -1671 -561 -221 -1119 -621 -2213 -2230 -493 -399 251 366 1160 568 402 203 -1135 -222 780 368 5 1613 981 -463 -497 -1777 -2065 243 509 -1580 -294 -962 -274 634 1369 688 333 -70 -558 -406 369 -447 714 762 198 -119 866 -150 1067 847 -1212 382 995 351 636 -718 -998 -469 827 -18 -515 738 353 -651 1 -1233 SS 20210626T144407.2Z 7847.613973 358 1 3.28 2 32.60 113.28 128.14 269.45 0.00 1 0.00 1 0 17 1.074e-02 8.565e-03 1.345e-03 1.002e-03 1.555110e-01 5.543377e-04 1.887802e-03 -6.000000e+00 6.619823e-03 232.94 -2.00 3.52 -2.00 314.52 0.00e+00 3.361226e-04 4.363361e-05 2.195795e-05 -6.000000e+00 2.923060e-04 287.52 -2.00 20.00 -2.00 313.91 0.00e+00 1.186 0.000 302.00 328.00 3 2.2720e+00 1.4274e-03 1.4482e-02 -6.0000e+00 1.6623e-02 1.6573e-02 1.5690e-03 8.1859e-03 -6.0000e+00 1.7889e-02 5.4092e-04 8.9908e-04 3.9475e-03 -6.0000e+00 1.0641e-02 -2.9745e-03 3.8685e-04 1.0876e-03 -6.0000e+00 4.4960e-03 1.4548e-02 7.9388e-05 3.0782e-05 1.6020e-05 -6.0000e+00 3.2001e-04 -9.5130e-04 5.1109e-05 12 9 1 12 1 1 99.95 21.32 0.23 -0.00095 -0.00035 35 129 1 5 0 86.370 26.00 20.01 21.32 32.00 33.0 1071.89 1765 -1181 719 -2803 -3561 -1099 -277 1001 1545 294 -2814 -1322 -19 58 884 850 -888 641 419 1323 1223 18 638 1117 478 1433 628 -675 -713 582 1294 156 2389 265 -4378 -1604 -1983 -986 87 235 -1571 -1014 -533 -937 -643 190 -1145 -105 -1003 -623 760 1253 839 1356 40 916 1065 527 75 472 349 1356 1264 1987 439 -1323 -358 -1691 930 1620 418 370 -99 583 562 -683 -658 -1813 -334 -185 -1012 -826 -2081 -2120 -406 -535 26 92 957 213 472 -18 -904 -285 1054 399 67 1286 828 -409 -336 -1556 -1786 98 550 -1218 -169 -584 -336 303 865 398 295 -95 -382 -209 295 -245 525 598 -36 -95 642 167 893 886 -993 617 816 348 573 -408 -801 -314 456 -99 -493 350 87 -371 -51 -771 709 -466 296 -1067 -1244 -374 -100 393 648 118 -1209 -545 -8 29 442 445 -478 351 234 755 698 10 375 635 282 848 362 -388 -386 309 710 89 1421 156 -2531 -943 -1223 -659 64 192 -1304 -862 -460 -807 -550 159 -932 -87 -808 -504 639 1040 727 1214 37 846 989 487 69 438 322 1322 1238 1980 440 -1230 -329 -1556 867 1659 436 396 -104 586 546 -636 -565 -1611 -297 -172 -1041 -876 -2229 -2401 -466 -651 32 113 1152 254 540 -20 -924 -289 1123 444 78 1596 1046 -502 -388 -1789 -2039 117 673 -1510 -218 -752 -451 423 1177 551 385 -120 -464 -256 351 -307 675 807 -48 -128 839 217 1099 1085 -1190 749 996 445 724 -526 -1061 -415 634 -138 -704 506 126 -522 -73 -1081 SS 20210626T144759.2Z 7847.616657 361 1 39.18 2 31.94 114.38 128.82 270.07 0.00 1 0.00 1 0 17 1.086e-02 8.377e-03 3.302e-04 2.219e-04 1.545190e-01 1.221524e-04 1.865912e-03 -6.000000e+00 6.691084e-03 232.94 -2.00 3.52 -2.00 315.02 0.00e+00 3.105596e-04 1.061246e-05 3.409653e-05 -6.000000e+00 2.954399e-04 287.52 -2.00 20.00 -2.00 314.36 0.00e+00 1.178 0.000 302.00 328.00 3 1.5741e+00 3.1617e-04 1.4378e-02 -6.0000e+00 1.6802e-02 1.8141e-02 3.4852e-04 8.1233e-03 -6.0000e+00 1.8081e-02 1.1370e-03 1.9921e-04 3.9142e-03 -6.0000e+00 1.0755e-02 -4.5092e-03 8.6924e-05 1.0732e-03 -6.0000e+00 4.5447e-03 2.9541e-02 1.8700e-04 6.8600e-06 1.5349e-05 -6.0000e+00 3.2342e-04 -1.1202e-03 7.0480e-05 11 8 0 10 0 0 100.00 21.32 0.26 -0.00112 0.00028 2664 641 1 5 0 14.060 26.00 19.96 21.32 32.31 33.0 1074.09 1204 -619 590 -2892 -3638 -1249 87 1448 1889 551 -2839 -1365 270 59 1094 568 -944 717 355 1657 1074 -416 729 799 323 1205 490 -972 -732 380 1651 201 2469 -50 -4331 -2179 -1620 -1042 218 138 -1143 -1166 -464 -1073 -494 -63 -838 -324 -950 -492 1053 959 727 1330 153 801 1038 545 117 329 577 1379 1275 2221 546 -1376 -566 -1757 617 1641 414 507 -64 706 292 -669 -904 -2092 -558 -266 -1078 -617 -2025 -1952 -379 -341 167 257 988 451 378 209 -1105 -256 772 295 23 1302 757 -388 -393 -1575 -1807 212 436 -1258 -217 -730 -247 409 961 448 260 -12 -400 -296 332 -359 536 523 82 -159 676 -99 893 755 -937 378 797 326 523 -536 -758 -342 567 -34 -367 421 195 -411 10 -844 381 -205 190 -941 -1085 -363 27 483 618 185 -955 -474 102 24 492 269 -458 353 179 849 553 -215 386 438 169 635 272 -505 -357 182 812 104 1321 -27 -2252 -1159 -955 -656 159 104 -923 -970 -391 -904 -412 -51 -664 -247 -707 -368 816 778 615 1162 136 722 941 491 105 298 508 1288 1255 2220 524 -1312 -508 -1576 591 1607 434 543 -68 712 272 -607 -757 -1719 -484 -255 -1060 -655 -2278 -2173 -448 -427 204 319 1202 552 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