File name: Pandora64s1_NewHavenCT_20210711_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T232851.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v3d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210711_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210711T161324.4Z 7862.675977 297 1 1.57 2 21.39 151.11 33.15 115.50 0.00 1 0.00 1 0 17 1.143e-02 9.094e-03 4.571e-03 3.526e-03 1.521919e-01 1.954510e-03 1.830827e-03 -6.000000e+00 7.040118e-03 232.95 -2.00 3.52 -2.00 314.32 0.00e+00 2.431254e-04 1.491377e-04 1.761883e-05 -6.000000e+00 3.127854e-04 288.93 -2.00 20.00 -2.00 313.72 0.00e+00 1.074 0.000 302.00 328.00 3 3.7275e+00 5.0265e-03 1.3461e-02 -6.0000e+00 1.7670e-02 2.0492e-02 5.5210e-03 7.9446e-03 -6.0000e+00 1.9015e-02 -4.1629e-03 3.1645e-03 3.8343e-03 -6.0000e+00 1.1320e-02 -1.8390e-03 1.3562e-03 1.0491e-03 -6.0000e+00 4.7863e-03 3.8127e-03 -2.5370e-04 1.0799e-04 1.5672e-05 -6.0000e+00 3.4051e-04 1.6547e-03 -1.1438e-05 12 9 1 12 1 1 999.00 22.90 0.23 0.00165 -0.00025 2 25 1 5 0 460.980 27.15 20.00 22.90 32.21 33.1 1067.90 561 -1152 889 -2921 -2691 -2225 -472 717 2190 403 -2843 -1473 560 121 1529 -52 -1204 693 439 2415 2762 -287 276 999 631 1717 919 -1260 -12 -366 1612 87 3105 -304 -4247 -2238 -883 -1342 55 187 -1037 -1478 114 -1905 212 -422 -630 -678 -1195 -509 1101 1207 1056 938 -63 800 791 412 646 -279 1375 763 1342 2206 529 -1800 -653 -1496 767 1403 32 336 -215 886 258 -446 -621 -1557 -1359 -431 -1121 184 -1882 -2078 -212 -421 -1 260 803 433 -72 -337 -951 120 257 -61 176 1803 1303 135 -647 -1029 -2060 774 237 -1071 -417 -714 -51 415 619 489 371 -411 -327 -402 95 -252 353 629 197 185 435 -185 1411 1051 -607 42 506 341 450 -560 -819 -409 497 -140 -38 327 240 -932 179 -637 238 -510 379 -1154 -1036 -852 -190 293 947 179 -1263 -677 260 62 795 -28 -677 395 255 1417 1610 -171 169 595 387 1058 549 -751 -7 -202 907 52 1883 -185 -2512 -1358 -557 -936 42 152 -898 -1262 98 -1652 188 -370 -532 -554 -998 -426 909 1041 948 835 -57 732 728 377 583 -258 1306 744 1369 2283 525 -1738 -591 -1350 741 1424 34 357 -225 920 248 -405 -546 -1341 -1252 -415 -1136 192 -2084 -2339 -243 -512 -2 320 971 513 -82 -365 -999 124 272 -68 204 2213 1628 164 -775 -1161 -2330 913 289 -1324 -539 -923 -68 557 848 652 483 -515 -392 -484 113 -312 452 813 258 239 566 -238 1707 1262 -712 51 612 430 564 -716 -1075 -538 687 -194 -53 472 345 -1318 245 -886 SS 20210711T161712.6Z 7862.678618 300 1 34.87 2 21.06 153.36 32.53 116.60 0.00 1 0.00 1 0 17 1.141e-02 8.821e-03 1.887e-03 1.290e-03 1.521893e-01 7.109193e-04 1.845210e-03 -6.000000e+00 7.029214e-03 232.95 -2.00 3.52 -2.00 314.95 0.00e+00 2.996013e-04 6.050720e-05 6.189564e-05 -6.000000e+00 3.122509e-04 288.93 -2.00 20.00 -2.00 314.26 0.00e+00 1.071 0.000 302.00 328.00 3 5.0779e+00 1.8398e-03 1.3463e-02 -6.0000e+00 1.7643e-02 2.7741e-02 2.0267e-03 7.9794e-03 -6.0000e+00 1.8983e-02 3.2270e-03 1.1583e-03 3.8558e-03 -6.0000e+00 1.1301e-02 -5.5481e-03 5.0461e-04 1.0537e-03 -6.0000e+00 4.7806e-03 9.8477e-04 1.6672e-04 3.9887e-05 1.5290e-05 -6.0000e+00 3.3987e-04 1.0325e-03 7.4795e-05 12 9 1 12 1 1 100.00 22.91 0.08 0.00103 0.00229 68 23 1 5 0 502.790 27.15 20.00 22.91 32.33 33.1 1068.90 1378 -702 940 -3037 -3598 -1125 338 923 1177 732 -2836 -1860 162 -812 768 853 -994 1107 302 2219 813 -315 1081 1363 107 1793 562 -979 -818 180 1439 261 2352 -131 -4608 -2466 -1729 -1042 143 -10 -890 -948 -538 -631 -645 161 -915 -107 -1302 -1102 1076 868 640 1274 101 734 630 514 103 186 712 1245 1419 2401 698 -1483 -541 -1604 613 1685 478 594 209 601 282 -1017 -1070 -2727 -840 -526 -969 -632 -1944 -1772 -68 -181 345 388 988 523 278 90 -1499 -384 516 361 -53 1331 928 -488 -585 -1944 -1938 131 354 -1205 -143 -402 -200 470 1199 671 323 143 -513 -613 195 -387 510 641 198 -1 440 -87 833 587 -992 291 691 201 459 -588 -880 -202 698 -8 -380 611 196 -446 -10 -893 471 -251 326 -979 -1063 -324 102 306 419 264 -1028 -700 66 -341 348 403 -483 543 152 1130 419 -163 569 742 61 1014 310 -506 -397 86 705 133 1249 -69 -2379 -1304 -1011 -660 105 -7 -729 -800 -461 -537 -547 133 -735 -82 -984 -838 843 712 547 1124 91 668 578 466 93 170 639 1186 1419 2434 679 -1339 -485 -1439 556 1671 507 610 223 613 265 -923 -895 -2249 -729 -503 -960 -676 -2084 -2003 -81 -218 431 493 1231 617 317 100 -1547 -391 555 399 -64 1628 1154 -590 -703 -2223 -2197 156 428 -1535 -190 -552 -272 664 1716 940 448 183 -642 -741 239 -476 669 881 277 -2 586 -110 1052 707 -1165 347 865 263 589 -769 -1182 -281 972 -11 -565 919 294 -656 -15 -1255 SS 20210711T162510.5Z 7862.684150 306 1 48.25 2 20.44 158.28 31.24 118.99 0.00 1 0.00 1 0 17 1.076e-02 8.339e-03 1.534e-03 9.363e-04 1.505645e-01 5.099970e-04 1.815345e-03 -6.000000e+00 6.632623e-03 232.95 -2.00 3.52 -2.00 315.51 0.00e+00 1.702546e-04 4.899074e-05 6.664894e-05 -6.000000e+00 2.946253e-04 288.93 -2.00 20.00 -2.00 314.78 0.00e+00 1.067 0.000 302.00 328.00 3 4.4195e+00 1.3267e-03 1.3375e-02 -6.0000e+00 1.6647e-02 1.3264e-02 1.4654e-03 7.8983e-03 -6.0000e+00 1.7911e-02 8.0730e-03 8.3683e-04 3.8133e-03 -6.0000e+00 1.0664e-02 -7.2439e-03 3.7035e-04 1.0375e-03 -6.0000e+00 4.5111e-03 1.9242e-03 2.2921e-04 2.9151e-05 1.4522e-05 -6.0000e+00 3.2067e-04 7.3734e-04 8.2088e-05 11 8 0 10 0 0 100.00 22.93 0.04 0.00074 0.00246 576 139 1 5 0 83.750 27.15 20.00 22.93 32.43 33.1 1069.09 1301 -734 611 -3104 -3208 -315 732 1695 2253 1195 -2145 -820 29 -353 957 450 -1057 798 -83 1571 741 -312 739 722 -71 1445 481 -472 -668 1037 1376 608 2390 312 -4169 -1990 -1815 -955 50 -1 -1235 -1451 -635 -1215 -954 -93 -1050 -489 -1264 -577 1105 620 648 1301 242 812 1026 472 137 324 469 1304 1221 2340 490 -1439 -482 -1496 794 1733 550 516 104 748 278 -567 -816 -2144 -387 -259 -967 -558 -1831 -1760 -153 -304 280 241 1110 421 412 147 -1093 -304 800 325 142 1287 867 -363 -424 -1717 -2071 189 291 -1363 -210 -702 -290 525 1055 532 220 -140 -651 -511 217 -404 453 518 -31 23 620 -112 900 726 -1081 413 707 316 348 -574 -795 -331 686 39 -311 632 251 -405 -75 -747 374 -221 179 -842 -794 -76 186 471 670 363 -653 -258 10 -133 391 193 -465 355 -36 683 346 -146 332 337 -34 698 226 -220 -294 446 612 281 1152 149 -1947 -952 -966 -550 33 -1 -925 -1121 -497 -947 -739 -74 -818 -366 -924 -423 838 494 537 1047 199 674 856 391 113 270 409 1201 1185 2298 462 -1257 -420 -1303 696 1664 564 543 108 739 253 -499 -663 -1711 -325 -241 -930 -578 -2008 -2039 -178 -374 358 312 1408 506 483 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