File name: Pandora64s1_NewHavenCT_20210719_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T233033.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v3d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210719_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210719 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210719T104319.8Z 7870.446756 88 1 7.50 2 79.11 71.86 147.59 308.77 0.00 1 0.00 1 0 25 4.090e-01 1.996e-02 2.121e-01 9.716e-03 6.603648e-01 5.514730e-03 7.864299e-03 -6.000000e+00 2.519359e-01 232.83 -2.00 3.52 -2.00 320.84 0.00e+00 5.685678e-04 2.397024e-03 3.665632e-03 -6.000000e+00 1.144393e-02 289.41 -2.00 20.00 -2.00 320.17 0.00e+00 5.094 0.002 302.00 328.00 3 2.5203e+00 1.8064e-02 6.4757e-02 -6.0000e+00 6.3350e-01 2.1627e-01 2.3046e-02 4.2927e-02 -6.0000e+00 6.8263e-01 -3.4847e-01 1.9301e-02 1.8677e-02 -6.0000e+00 4.0505e-01 1.5390e-01 9.3656e-03 5.0522e-03 -6.0000e+00 1.7092e-01 1.2940e-04 -5.7784e-04 2.8907e-04 7.6042e-05 -6.0000e+00 1.2196e-02 1.0298e-02 -2.8783e-05 12 9 9 12 1 1 83.64 21.20 0.23 0.01030 0.00596 5 10 1 5 0 1219.340 25.90 20.01 21.20 28.48 33.2 1046.06 -37492 -163634 -55824 -174370 -139523 -200109 110910 -143532 900000 -182915 -66524 -76290 -54428 -82981 -15011 -23679 -9904 -40935 -17315 -46420 37321 -7372 16839 -5996 -4322 -15940 9201 -49524 -25040 19699 21247 28914 17222 7254 -8680 11597 3588 5837 12289 13380 15944 10383 26604 21561 4515 12640 6214 9017 8214 2784 13153 10621 10640 12109 11103 12563 3917 10748 9800 3618 1589 9305 5416 14883 213 3982 489 2687 -1219 3032 2977 3069 -3417 2999 -5124 2426 -4462 -5977 -2220 -2200 -2900 -158 -1548 -2095 -1066 -1260 -183 1700 1388 1182 -2845 -690 -4428 -1034 -2758 -990 -661 -465 579 -613 142 -3462 -2669 -1660 1170 -1576 -597 -643 386 -44 711 -677 1354 -516 3 -302 278 388 1599 77 392 598 1805 13 1976 1507 -605 1856 1037 -234 929 -1523 -602 -329 1145 -208 -128 728 43 -783 -128 -1668 -355 -4753 -604 -5285 -3021 -7708 1051 -3897 900000 -8663 -1125 -1703 -1215 -2830 -335 -657 -261 -1499 -562 -1964 732 -229 444 -215 -161 -690 305 -2658 -1152 653 819 1174 886 385 -521 651 233 446 1063 1318 1661 1206 2722 2328 587 1540 824 1213 1172 429 2048 1861 2028 2452 2366 2744 946 2380 2141 848 404 2440 1651 4502 75 1320 173 982 -496 1326 1382 1445 -1651 1270 -2135 916 -1778 -2418 -1005 -1163 -1770 -100 -1060 -1538 -832 -1038 -155 1426 1149 926 -2181 -496 -3299 -808 -2504 -961 -728 -543 690 -714 161 -3700 -2731 -1781 1300 -1884 -721 -839 527 -66 1156 -1090 2205 -821 5 -452 427 624 2676 126 655 960 2787 20 2832 2208 -862 2832 1712 -431 1749 -3093 -1282 -712 2605 -473 -297 1682 97 -1767 -272 -3593 SS 20210719T104912.8Z 7870.450843 91 1 48.83 2 78.05 72.77 148.41 310.75 0.00 1 0.00 1 0 17 4.139e-01 1.685e-02 2.767e-01 7.260e-03 6.111832e-01 4.151843e-03 7.236799e-03 -6.000000e+00 2.566790e-01 232.83 -2.00 3.52 -2.00 320.84 0.00e+00 5.071412e-03 1.828688e-03 2.511130e-03 -6.000000e+00 1.222372e-02 289.41 -2.00 20.00 -2.00 320.16 0.00e+00 4.680 0.002 302.00 328.00 3 4.0439e+00 1.3648e-02 5.8073e-02 -6.0000e+00 6.4725e-01 1.2806e-01 1.7702e-02 3.5076e-02 -6.0000e+00 6.9866e-01 -1.0282e-01 1.5952e-02 1.8771e-02 -6.0000e+00 4.1166e-01 3.1736e-02 7.7815e-03 6.2154e-03 -6.0000e+00 1.7330e-01 4.2241e-05 -1.2134e-03 2.2386e-04 9.8861e-05 -6.0000e+00 1.2592e-02 1.1925e-02 -1.6730e-04 12 8 8 10 0 0 99.89 21.20 0.21 0.01193 0.00281 20 5 1 5 0 2440.980 25.90 19.97 21.20 28.62 33.3 1046.84 -71377 84004 66016 -74354 -193705 -98033 900000 -99618 900000 900000 -138083 90141 -83909 -83455 -45748 34592 -6849 117465 -59975 63091 48040 113405 62820 221534 -24226 26433 -44870 -13226 -58002 28850 -20359 13337 32160 25343 -15509 4936 803 1545 2064 2699 23496 14526 9275 9973 -6734 578 9135 6774 -10773 -22690 11719 4006 5110 -567 8274 1511 2835 -522 15703 -598 6945 -1892 6102 6179 9805 2017 1696 3167 3257 -622 5384 718 -1149 -804 -43 -4908 2398 -5913 -858 -2343 -3788 -794 -2411 -4110 -850 -3769 1249 -52 2872 2632 -78 1438 -1560 -1178 -271 2173 -1063 1646 1620 -693 -996 -3613 -3370 -380 291 -1882 -1514 2856 -719 1770 873 274 -96 1217 -709 -1298 479 -178 243 872 -436 439 1490 -981 752 -85 -2393 2015 1095 535 -700 -1187 -797 62 649 -204 -587 764 1152 -164 22 -1233 -537 594 467 -625 -4837 -1040 900000 -1321 900000 900000 -3419 638 -1892 -2362 -1092 428 -142 831 -2346 863 722 963 948 1567 -921 631 -2054 -462 -3114 791 -1025 584 1322 1121 -942 263 51 117 187 264 2151 1462 1032 1121 -921 75 1124 892 -1778 -4593 1884 762 1044 -132 1824 369 693 -130 3283 -150 1736 -547 1820 2004 3063 665 573 1111 1298 -288 2488 353 -554 -362 -17 -1926 859 -2437 -389 -1257 -2353 -509 -1675 -3092 -665 -3196 1047 -45 2351 2039 -58 1006 -1113 -902 -233 2091 -1142 1916 1941 -818 -1096 -3722 -3513 -407 314 -2167 -1862 3610 -992 2622 1400 449 -154 1843 -1043 -1891 708 -277 397 1434 -710 684 2233 -1439 1102 -121 -3483 3067 1793 965 -1318 -2355 -1660 136 1444 -470 -1384 1797 2640 -361 48 -2618 SS 20210719T124827.9Z 7870.533656 160 1 3.36 2 55.99 91.39 156.62 8.89 0.00 1 0.00 1 0 25 1.461e-02 8.967e-03 8.556e-03 3.802e-03 2.572482e-01 2.076071e-03 3.148088e-03 -6.000000e+00 8.927663e-03 232.82 -2.00 3.52 -2.00 316.52 0.00e+00 2.466650e-04 2.459460e-04 1.333168e-04 -6.000000e+00 4.010715e-04 289.42 -2.00 20.00 -2.00 315.70 0.00e+00 1.782 0.000 302.00 328.00 3 3.8699e+00 5.4508e-03 2.2548e-02 -6.0000e+00 2.2390e-02 7.9692e-03 6.0544e-03 1.3607e-02 -6.0000e+00 2.4151e-02 3.8156e-03 3.5040e-03 6.5799e-03 -6.0000e+00 1.4386e-02 -5.9049e-03 1.6275e-03 1.8250e-03 -6.0000e+00 6.0432e-03 1.3485e-03 -6.4573e-03 1.1772e-04 2.4543e-05 -6.0000e+00 4.3486e-04 2.3946e-02 -1.0949e-03 12 9 1 12 9 1 80.10 21.17 0.13 0.02395 -0.02458 3 15 1 5 0 794.750 25.90 20.01 21.17 30.09 33.2 1054.78 -5391 -1473 -3429 -1844 -5917 886 -2083 3230 -1761 548 -3371 1275 -233 1356 517 1859 -935 2676 708 2830 -186 165 -525 1309 -1150 2402 -2038 -1830 -1147 2193 1324 415 2443 -1066 -3818 -3796 -56 -500 242 -34 805 -1476 364 -1398 378 -73 -732 -101 -1667 -766 2630 552 1421 1396 -75 66 1048 -120 464 -134 1951 1213 1674 1769 107 -2783 -290 -1978 1353 1127 872 320 151 34 219 -1055 -819 -1682 -435 -775 -527 -961 -2043 -2099 -456 -790 655 112 412 407 1067 222 -929 -31 629 677 346 1636 605 -108 -856 -1688 -1952 436 40 -1185 -513 -367 -141 603 699 587 296 660 -193 -81 114 -407 414 345 -102 79 538 22 979 860 -1214 1114 83 633 384 -1105 -675 -551 8 33 -136 638 115 -213 220 -896 -951 -260 -608 -289 -907 130 -345 564 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