File name: Pandora64s1_NewHavenCT_20210804_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20260321T233336.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora64_OF_v3d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20210804_L1_smca1c4d20190911p1-8.txt.bz2 Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20210804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210804T113415.0Z 7886.482118 210 1 48.27 2 72.06 82.70 30.84 113.39 0.00 1 0.00 1 0 17 2.762e-02 7.518e-03 8.361e-03 8.833e-04 4.160230e-01 4.780877e-04 4.891267e-03 -6.000000e+00 1.694886e-02 232.25 -2.00 3.52 -2.00 318.89 0.00e+00 2.122332e-04 1.122648e-04 4.433057e-04 -6.000000e+00 7.585335e-04 289.77 -2.00 20.00 -2.00 318.06 0.00e+00 3.202 0.001 302.00 328.00 3 2.2511e+00 1.3290e-03 3.9044e-02 -6.0000e+00 4.2450e-02 -1.0870e-02 1.5298e-03 2.2209e-02 -6.0000e+00 4.5720e-02 2.2307e-03 1.0663e-03 1.0707e-02 -6.0000e+00 2.7249e-02 -6.5942e-03 5.5443e-04 2.8993e-03 -6.0000e+00 1.1530e-02 1.3941e-03 -2.6138e-04 2.7327e-05 3.3615e-05 -6.0000e+00 8.2265e-04 8.8520e-03 -8.0904e-05 11 8 0 10 0 0 86.71 21.33 0.19 0.00885 0.00689 174 42 1 5 0 277.340 26.00 20.00 21.33 25.68 33.5 1028.04 -8119 -4247 -7853 -10853 -14620 -9822 -7756 -5769 -5813 -3263 -10053 -5929 -3421 -2366 1473 -769 -2485 -290 -1472 497 -1463 -434 728 233 -163 819 -867 -2188 -2079 -1452 1326 -289 2588 -1282 -5374 -4047 -1220 -1589 138 109 -676 -938 -168 -958 -318 -467 -392 -377 -1266 -1121 1279 847 1368 1333 431 981 942 479 340 399 659 1436 1878 2747 765 -979 -370 -1432 978 1701 742 659 -141 539 -295 -950 -1347 -2040 -439 -435 -1177 -528 -1785 -1750 -384 -326 209 480 1125 697 500 287 -754 131 719 165 36 1148 498 -557 -664 -1964 -2047 374 190 -1289 -286 -835 -218 500 798 402 242 -31 -352 -324 338 -155 739 362 -164 -225 762 103 1160 475 -1169 530 861 340 427 -690 -577 -355 513 -245 -290 542 265 -293 144 -890 -236 -128 -250 -327 -435 -320 -250 -206 -230 -132 -452 -293 -196 -159 111 -66 -230 -28 -153 53 -161 -48 86 30 -20 104 -110 -291 -275 -204 187 -46 437 -223 -938 -749 -251 -392 40 33 -224 -328 -60 -348 -116 -172 -144 -140 -483 -452 552 396 633 656 221 516 503 254 179 213 372 880 1165 1788 494 -611 -228 -921 690 1328 581 527 -110 423 -214 -631 -859 -1340 -319 -338 -1032 -479 -1733 -1808 -398 -357 237 549 1258 738 522 281 -719 130 783 191 44 1524 644 -737 -823 -2408 -2464 445 241 -1734 -385 -1192 -318 779 1242 626 381 -46 -518 -466 497 -229 1152 582 -263 -351 1146 155 1675 663 -1632 776 1304 556 705 -1189 -990 -643 938 -466 -563 1058 511 -545 269 -1618 SS 20210804T113954.0Z 7886.486042 213 1 48.38 2 71.01 83.60 29.89 115.01 0.00 1 0.00 1 0 25 2.353e-02 7.608e-03 7.163e-03 8.466e-04 3.954039e-01 4.578516e-04 4.655701e-03 -6.000000e+00 1.443535e-02 232.25 -2.00 3.52 -2.00 318.77 0.00e+00 3.048539e-04 1.032936e-04 3.281537e-04 -6.000000e+00 6.460563e-04 289.77 -2.00 20.00 -2.00 317.93 0.00e+00 3.036 0.000 302.00 328.00 3 2.3202e+00 1.2661e-03 3.7038e-02 -6.0000e+00 3.6155e-02 -1.4128e-02 1.4530e-03 2.1067e-02 -6.0000e+00 3.8940e-02 8.4504e-03 9.9897e-04 1.0187e-02 -6.0000e+00 2.3208e-02 -9.7358e-03 5.1803e-04 2.7764e-03 -6.0000e+00 9.8196e-03 1.5673e-03 -2.7038e-04 2.6312e-05 3.2241e-05 -6.0000e+00 7.0067e-04 9.4102e-03 -6.7733e-05 11 8 0 10 0 0 88.89 21.33 0.16 0.00941 0.00738 227 55 1 5 0 213.070 26.00 20.01 21.33 25.94 33.4 1029.34 -583 -6327 -1438 -12673 -11320 -10585 -1032 -6193 370 -5400 -3934 -5451 2132 -2517 4097 -1426 304 -331 1133 309 975 -1903 3214 -74 1496 -164 -141 -2827 -997 -491 1413 25 2524 -1440 -5231 -3068 -1987 -1229 -273 -169 -1219 -574 -531 -1035 -679 -167 -1197 -114 -1587 -534 992 1121 532 1293 69 942 1061 441 89 592 351 1693 1467 2914 380 -826 -547 -1398 913 1830 491 877 -60 677 11 -636 -1109 -2084 -637 -413 -1208 -510 -1990 -1827 -433 -138 420 417 1202 678 520 224 -767 77 754 204 -33 1246 500 -498 -572 -2011 -1937 315 288 -1381 -321 -812 -157 436 1039 268 202 -91 -494 -291 312 -282 733 326 -123 -237 785 -171 1104 355 -1139 531 867 403 487 -537 -708 -273 611 -253 -327 545 300 -336 98 -797 -19 -230 -51 -458 -383 -370 -36 -260 16 -260 -192 -308 132 -192 341 -138 31 -33 117 34 107 -219 376 -10 201 -23 -20 -383 -131 -69 216 4 461 -270 -982 -604 -442 -324 -79 -55 -434 -213 -203 -400 -265 -65 -468 -45 -638 -224 449 505 258 660 37 513 585 242 49 326 205 1068 941 1944 252 -526 -344 -912 653 1445 390 707 -47 538 8 -426 -713 -1379 -466 -342 -1059 -490 -1930 -1883 -474 -150 473 475 1339 757 540 218 -725 76 808 231 -42 1619 668 -644 -731 -2418 -2287 389 359 -1825 -445 -1135 -235 663 1644 424 309 -136 -703 -404 444 -423 1159 506 -191 -376 1201 -251 1545 505 -1616 749 1325 630 804 -924 -1213 -492 1110 -479 -631 1058 575 -624 183 -1450 SS 20210804T115854.8Z 7886.499245 222 1 48.35 2 67.45 86.62 26.79 121.07 0.00 1 0.00 1 0 17 1.485e-02 7.788e-03 3.006e-03 6.589e-04 3.401184e-01 3.555750e-04 4.033038e-03 -6.000000e+00 9.112555e-03 232.25 -2.00 3.52 -2.00 317.88 0.00e+00 2.139356e-04 6.126914e-05 2.371566e-04 -6.000000e+00 4.077242e-04 289.77 -2.00 20.00 -2.00 317.03 0.00e+00 2.586 0.000 302.00 328.00 3 2.4250e+00 9.5566e-04 3.1613e-02 -6.0000e+00 2.2824e-02 -5.2235e-03 1.0763e-03 1.7992e-02 -6.0000e+00 2.4579e-02 -6.2314e-04 6.7071e-04 8.6756e-03 -6.0000e+00 1.4649e-02 -4.2485e-03 3.3759e-04 2.3544e-03 -6.0000e+00 6.2003e-03 2.3397e-03 -1.0812e-04 2.0454e-05 2.8206e-05 -6.0000e+00 4.4220e-04 8.2491e-03 -4.3812e-05 11 8 0 10 0 0 99.24 21.33 0.18 0.00825 0.00744 206 50 1 5 0 234.530 26.00 19.98 21.33 27.12 33.2 1036.10 -936 -1551 -2165 -6658 -6196 -4240 -2037 -2228 943 -1322 -5029 -3117 -1396 -1387 1167 -29 -953 417 549 930 626 -581 1928 834 926 975 312 -1955 -1495 -247 1298 69 2479 -1263 -4951 -3120 -1796 -1002 629 38 -808 -757 -130 -654 -315 32 -722 -308 -1073 -445 1198 791 880 1525 82 939 981 453 -117 207 555 1576 1566 2641 485 -1168 -525 -1294 1083 1749 537 613 -178 617 -76 -893 -1099 -1859 -494 -460 -1313 -500 -2114 -1757 -348 -309 311 440 1008 494 447 217 -979 -128 724 223 -55 1296 551 -440 -673 -1829 -1912 426 322 -1292 -263 -754 -232 544 877 296 278 -8 -363 -297 354 -287 694 427 -112 -178 786 -25 1192 477 -1071 473 937 383 461 -590 -730 -306 554 -180 -323 468 189 -356 127 -892 -63 -111 -157 -461 -401 -278 -143 -177 79 -118 -473 -322 -165 -174 163 -4 -156 72 98 172 117 -111 382 178 206 224 70 -425 -316 -54 308 18 685 -356 -1385 -844 -545 -358 245 17 -385 -377 -66 -335 -162 16 -367 -156 -550 -237 634 449 530 964 54 630 624 305 -79 141 372 1136 1216 2002 384 -883 -387 -981 843 1502 467 543 -155 536 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