File name: Pandora236s1_NewLondonCT_20230728_L2Fit_fout2c4d20220606p1-8.txt File generation date: 20230731T044815.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Brooke S.Stutzman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 236 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora236_OF_v3d20220107.txt Instrument calibration file used: Pandora236s1_CF_v4d20220606.txt Level 1 file used: Pandora236s1_NewLondonCT_20230728_L1_smca1c4d20220606p1-8.txt Full location name: United States Coast Guard Academy Short location name: NewLondonCT Country of location: United States Location latitude [deg]: 41.3758 Location longitude [deg]: -72.1004 Location altitude [m]: 30 Local noon date: 20230728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3 "1.8 field calibration all gases" change in SO2 First and last pixel inside fitting window: 197 338 Nominal wavelengths inside fitting window [nm]: 305.1267 305.2679 305.4091 305.5502 305.6914 305.8325 305.9737 306.1148 306.2559 306.3970 306.5381 306.6792 306.8203 306.9613 307.1024 307.2434 307.3845 307.5255 307.6665 307.8075 307.9485 308.0894 308.2304 308.3714 308.5123 308.6532 308.7942 308.9351 309.0760 309.2169 309.3577 309.4986 309.6395 309.7803 309.9211 310.0620 310.2028 310.3436 310.4844 310.6251 310.7659 310.9067 311.0474 311.1881 311.3289 311.4696 311.6103 311.7510 311.8916 312.0323 312.1730 312.3136 312.4543 312.5949 312.7355 312.8761 313.0167 313.1573 313.2978 313.4384 313.5790 313.7195 313.8600 314.0005 314.1410 314.2815 314.4220 314.5625 314.7029 314.8434 314.9838 315.1243 315.2647 315.4051 315.5455 315.6859 315.8262 315.9666 316.1070 316.2473 316.3876 316.5279 316.6682 316.8085 316.9488 317.0891 317.2294 317.3696 317.5099 317.6501 317.7903 317.9305 318.0707 318.2109 318.3511 318.4912 318.6314 318.7715 318.9117 319.0518 319.1919 319.3320 319.4721 319.6121 319.7522 319.8923 320.0323 320.1723 320.3124 320.4524 320.5924 320.7323 320.8723 321.0123 321.1522 321.2922 321.4321 321.5720 321.7119 321.8518 321.9917 322.1316 322.2715 322.4113 322.5512 322.6910 322.8308 322.9706 323.1104 323.2502 323.3900 323.5297 323.6695 323.8092 323.9490 324.0887 324.2284 324.3681 324.5078 324.6474 324.7871 324.9268 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230728T102356.9Z 8609.433297 62 1 51.71 2 83.15 70.68 147.86 291.16 0.00 1 0.00 1 0 30 6.636e-01 3.161e-02 4.543e-01 2.399e-02 8.847790e-01 1.412040e-02 9.801427e-03 -6.000000e+00 3.888794e-01 232.49 -2.00 3.52 -2.00 322.25 0.00e+00 -2.921354e-03 7.733768e-03 1.092475e-03 -6.000000e+00 1.781288e-02 289.44 -2.00 20.00 -2.00 321.72 0.00e+00 7.653 0.008 302.00 328.00 3 1.2207e+00 5.7197e-02 9.0497e-02 -6.0000e+00 9.7571e-01 1.1497e+00 7.5784e-02 4.9141e-02 -6.0000e+00 1.0568e+00 -1.5193e+00 5.5402e-02 2.4933e-02 -6.0000e+00 6.2418e-01 6.0827e-01 2.5737e-02 7.3268e-03 -6.0000e+00 2.6671e-01 3.0164e-05 -1.6922e-03 6.6363e-04 9.1321e-05 -6.0000e+00 1.7964e-02 1.0947e-03 0.0000e+00 12 8 8 10 0 0 31.45 24.50 0.62 0.00109 -0.01162 31 5 1 5 0 1667.750 26.62 20.00 24.50 31.97 11.2 1066.58 181299 -56404 -79455 900000 71367 900000 900000 -135282 221988 221318 -115925 -116062 22616 30814 900000 12168 -25758 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3025 4385 3290 -2259 -739 2710 1909 1278 4760 1118 5371 3127 5367 3060 1849 2087 -1163 2055 2832 2417 -2367 356 -1375 2449 -136 3779 2416 4688 3094 1247 344 324 871 -3043 1437 -4189 1057 -805 5103 -3384 -2403 -629 -1783 -7207 -1440 -874 -3841 1339 -3485 -836 -2905 -3139 2149 -3115 -3546 386 -1413 809 -1245 -2935 -489 2157 941 -4309 4364 4150 4159 2382 2445 1676 5106 960 2706 1121 -27 -2426 785 -1631 -3239 2864 983 5420 1451 2544 -3334 -3562 -6320 SS 20230728T103413.1Z 8609.440429 65 1 50.92 2 81.33 72.30 149.57 293.90 0.00 1 0.00 1 0 17 4.862e-01 1.507e-02 2.370e-01 6.701e-03 7.553318e-01 3.773762e-03 8.732672e-03 -6.000000e+00 2.794950e-01 232.49 -2.00 3.52 -2.00 321.94 0.00e+00 3.756739e-03 2.199548e-03 5.053088e-03 -6.000000e+00 1.245074e-02 289.44 -2.00 20.00 -2.00 321.39 0.00e+00 6.250 0.004 302.00 328.00 3 1.1490e+00 1.5192e-02 7.8817e-02 -6.0000e+00 7.0121e-01 4.0807e-01 2.0938e-02 5.1982e-02 -6.0000e+00 7.5777e-01 -6.1330e-01 1.8930e-02 2.4890e-02 -6.0000e+00 4.5119e-01 2.5705e-01 8.7211e-03 6.5463e-03 -6.0000e+00 1.9297e-01 1.5670e-04 -7.1409e-04 1.8771e-04 1.2382e-04 -6.0000e+00 1.2636e-02 6.1664e-04 0.0000e+00 12 8 8 10 0 0 21.74 24.50 0.33 0.00062 -0.00475 81 14 1 5 0 628.590 26.73 20.00 24.50 33.03 11.1 1071.09 -216008 -40316 -174575 -136874 -211678 -47107 -115272 -64533 -175625 -122509 -155333 -117220 -116573 -78350 8814 -91347 -90258 -38032 -33290 -84526 -56158 4628 -36985 -13997 -36461 16452 18237 -27599 -74985 -33896 27254 -7944 -5513 19481 -14134 -15746 22299 6267 38343 24138 9784 29291 21521 11943 35327 2614 9102 21894 24782 9188 21031 14649 33943 24728 13026 6540 17208 12248 4351 14806 10592 15890 19788 10343 12704 7237 10521 5946 6286 7897 6388 -730 4397 530 4883 1354 2343 -2386 2640 -2682 1692 584 -2248 -222 -382 -114 -1252 159 1397 -703 -1675 -2829 -3282 -3219 -2882 -1237 -200 -569 -773 240 -3351 -2365 -1185 -1483 -2172 -2498 -1263 -767 130 -24 -971 698 398 -520 -233 633 -199 320 150 770 1339 1811 983 1187 1109 -26 1591 235 -34 414 -2 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6.802035e-04 2.645777e-03 -6.000000e+00 9.951707e-03 289.44 -2.00 20.00 -2.00 320.66 0.00e+00 5.024 0.002 302.00 328.00 3 1.0929e+00 4.8083e-03 6.2070e-02 -6.0000e+00 5.6047e-01 6.2504e-02 6.7269e-03 3.8627e-02 -6.0000e+00 6.0568e-01 -8.5367e-02 6.5915e-03 1.9199e-02 -6.0000e+00 3.6064e-01 2.5446e-02 3.1103e-03 5.2565e-03 -6.0000e+00 1.5425e-01 6.1223e-04 -3.3480e-04 7.0550e-05 6.4134e-05 -6.0000e+00 1.0100e-02 5.0033e-04 0.0000e+00 11 8 0 10 0 0 37.23 24.50 0.30 0.00050 -0.00202 169 29 1 5 0 302.930 26.62 20.00 24.50 33.53 11.3 1074.40 138916 -131886 -23522 -146520 -136155 -102019 -129542 -119820 -117265 -117889 -142169 -80747 -109678 -28432 -80871 3523 -54910 -33083 -24506 -8904 -26224 -41795 1979 -28468 -30530 -18687 -9281 -15821 -23247 -11635 -8949 5148 11603 -6415 -14892 -6835 -70 -9973 751 6140 3646 -2074 1446 4186 -73 1310 -1665 2401 -1625 4100 163 3308 4778 2797 3425 3387 3761 787 629 2149 1407 2554 3725 4243 696 2137 1154 2022 2024 2651 1468 534 1292 728 -1240 -1789 -2483 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