File name: Pandora85s1_NewOrleansLA-XULA_20240725_L2Fit_fout2c6d20240531p1-8.txt File generation date: 20260326T084638.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v6d20240531.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240725_L1_smca1c6d20240531p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240725 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1050 305.2456 305.3862 305.5268 305.6674 305.8080 305.9486 306.0892 306.2297 306.3703 306.5108 306.6513 306.7918 306.9323 307.0728 307.2133 307.3537 307.4942 307.6346 307.7751 307.9155 308.0559 308.1963 308.3367 308.4770 308.6174 308.7577 308.8981 309.0384 309.1787 309.3190 309.4593 309.5996 309.7398 309.8801 310.0203 310.1606 310.3008 310.4410 310.5812 310.7214 310.8615 311.0017 311.1418 311.2820 311.4221 311.5622 311.7023 311.8424 311.9825 312.1226 312.2626 312.4027 312.5427 312.6827 312.8227 312.9627 313.1027 313.2427 313.3826 313.5226 313.6625 313.8025 313.9424 314.0823 314.2222 314.3621 314.5019 314.6418 314.7816 314.9215 315.0613 315.2011 315.3409 315.4807 315.6205 315.7602 315.9000 316.0397 316.1795 316.3192 316.4589 316.5986 316.7383 316.8779 317.0176 317.1573 317.2969 317.4365 317.5761 317.7157 317.8553 317.9949 318.1345 318.2740 318.4136 318.5531 318.6926 318.8321 318.9716 319.1111 319.2506 319.3900 319.5295 319.6689 319.8084 319.9478 320.0872 320.2266 320.3659 320.5053 320.6447 320.7840 320.9233 321.0627 321.2020 321.3413 321.4806 321.6198 321.7591 321.8983 322.0376 322.1768 322.3160 322.4552 322.5944 322.7336 322.8728 323.0119 323.1511 323.2902 323.4293 323.5684 323.7075 323.8466 323.9857 324.1248 324.2638 324.4028 324.5419 324.6809 324.8199 324.9589 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240725T122322.0Z 8972.516226 228 1 53.90 2 77.02 74.82 50.51 238.25 0.00 1 0.00 1 0 25 1.577e-01 1.231e-02 2.704e-02 1.418e-03 5.049827e-01 7.228121e-04 5.806387e-03 -6.000000e+00 9.042341e-02 229.96 -2.00 3.24 -2.00 319.50 0.00e+00 1.665986e-03 2.111929e-04 2.737819e-03 -6.000000e+00 4.179153e-03 294.38 -2.00 20.00 -2.00 318.59 0.00e+00 4.332 0.001 302.00 328.00 3 2.2425e+00 2.0865e-03 5.0734e-02 -6.0000e+00 2.2488e-01 1.2383e-02 2.4885e-03 2.8864e-02 -6.0000e+00 2.4367e-01 -2.7361e-02 1.9147e-03 1.2752e-02 -6.0000e+00 1.4592e-01 -1.0198e-04 1.0061e-03 3.1536e-03 -6.0000e+00 6.2168e-02 4.4144e-04 4.8396e-04 3.9471e-05 3.9992e-05 -6.0000e+00 4.2839e-03 1.6959e-02 0.0000e+00 12 8 8 10 0 0 99.76 27.06 0.44 0.01696 0.02060 105 12 1 5 0 513.300 34.25 20.00 27.06 33.28 23.5 1019.92 -46265 66481 -45472 -56820 -6141 -58790 -54914 -49271 -73923 -32340 -44823 -35625 -7882 -19995 25652 -8787 -13235 9140 3072 12029 -12739 -2983 3870 -123 1454 -1263 11121 -16569 -2376 -14066 6394 -115 -6436 -13451 -8548 -7628 -12091 -2430 3028 3486 1070 3209 3047 -242 -2485 4594 2180 -844 464 -255 3647 1385 -170 4143 3009 1865 2217 671 -663 1106 1417 1709 2016 3452 1671 -1943 -163 -139 1240 2475 1622 1208 671 391 -2083 -2559 -3729 -4442 -1651 -2585 -1567 -1418 -2348 -962 -107 4 1337 1636 904 1473 46 -956 -2193 -1307 -1986 -276 405 676 131 -335 -1550 -2101 -1874 -1166 -1112 -246 -189 97 1191 1659 2483 1766 1131 47 -789 -822 -132 171 532 468 736 1282 871 430 13 -1420 -1056 -453 -514 -213 -617 -896 -903 -579 24 25 741 928 595 343 -339 -551 -319 -870 450 -968 -1257 -76 -1284 -1291 -1253 -2688 -818 -1345 -1133 -235 -832 816 -449 -774 465 177 665 -914 -197 256 -9 115 -107 827 -1551 -192 -1404 605 -13 -891 -2018 -1160 -1069 -1845 -406 586 784 270 838 830 -69 -736 1289 633 -258 144 -78 1194 509 -69 1724 1324 794 960 292 -285 509 635 848 1118 1904 937 -1076 -94 -83 761 1714 1144 880 481 265 -1410 -1569 -2184 -2679 -1093 -1885 -1296 -1230 -2204 -888 -105 4 1370 1710 944 1538 45 -882 -2088 -1204 -2056 -304 478 849 174 -434 -1892 -2466 -2195 -1346 -1386 -303 -247 135 1693 2467 3777 2774 1746 72 -1149 -1211 -197 256 846 742 1155 2030 1345 640 20 -2073 -1493 -671 -809 -351 -1053 -1606 -1618 -1094 47 48 1465 1868 1195 688 -651 -1054 -601 SS 20240725T123813.0Z 8972.526539 234 1 51.20 2 73.90 76.47 53.18 241.37 0.00 1 0.00 1 0 25 5.794e-02 1.162e-02 5.519e-03 7.969e-04 4.200417e-01 4.035591e-04 4.721109e-03 -6.000000e+00 3.322518e-02 229.96 -2.00 3.24 -2.00 318.51 0.00e+00 1.482164e-03 8.546960e-05 1.473084e-03 -6.000000e+00 1.535522e-03 294.38 -2.00 20.00 -2.00 317.56 0.00e+00 3.544 0.000 302.00 328.00 3 1.9605e+00 1.1067e-03 4.0916e-02 -6.0000e+00 8.2630e-02 -7.5453e-03 1.2734e-03 2.1263e-02 -6.0000e+00 8.9532e-02 -5.1086e-03 8.4793e-04 1.0033e-02 -6.0000e+00 5.3617e-02 -7.2331e-03 4.4366e-04 2.6256e-03 -6.0000e+00 2.2844e-02 1.3689e-03 4.4808e-04 2.2398e-05 2.7596e-05 -6.0000e+00 1.5740e-03 1.6489e-02 0.0000e+00 12 9 9 12 1 1 99.94 27.10 0.43 0.01649 0.01986 192 23 1 5 0 265.240 34.25 20.00 27.10 33.68 23.5 1020.03 -14513 297 -14575 -23433 -16304 -25229 -20297 -17955 -24811 -15655 -18827 -13828 -8046 -6012 3617 -2313 -2397 1955 1437 3610 -2431 6 1561 269 303 -364 422 -5278 -4014 -4794 10 -45 -1145 -5295 -6124 -6117 -6058 -1605 1016 1466 809 1603 1664 1168 275 2223 1135 197 -601 349 1743 1002 1215 2089 1529 2047 940 420 -57 672 1903 2472 3032 2883 926 -737 -1414 -964 897 1457 1338 1176 858 359 -1033 -2116 -3511 -3850 -2551 -2416 -1729 -1805 -2492 -1370 -387 210 1038 1548 1283 929 195 -998 -2078 -1585 -1632 -513 450 672 225 -429 -1357 -2220 -1793 -815 -1225 -620 -337 88 1236 1718 2116 1841 1283 101 -488 -453 -44 375 663 657 683 967 750 261 167 -990 -839 -331 -298 -325 -609 -869 -810 -467 -97 -39 671 823 411 306 -201 -681 -458 -589 11 -659 -1065 -639 -1110 -943 -928 -1523 -915 -1166 -922 -611 -540 349 -241 -269 225 176 452 -327 1 217 41 49 -61 70 -871 -640 -827 2 -10 -247 -1193 -1434 -1361 -1535 -466 322 536 324 622 669 477 114 916 472 83 -260 158 851 500 651 1182 847 1163 550 244 -33 384 1134 1613 2053 2098 679 -517 -968 -672 645 1124 1118 1012 727 290 -814 -1517 -2523 -2793 -1919 -1989 -1527 -1689 -2507 -1376 -414 228 1171 1780 1468 1013 207 -1038 -2069 -1604 -1740 -585 552 881 299 -556 -1716 -2695 -2065 -977 -1533 -810 -446 122 1767 2565 3244 2875 1953 151 -709 -631 -62 536 1012 1014 1054 1452 1136 380 241 -1384 -1177 -463 -442 -508 -982 -1461 -1361 -799 -172 -73 1259 1527 764 565 -356 -1201 -793 SS 20240725T124844.1Z 8972.533844 237 1 54.03 2 71.68 77.62 55.13 243.45 0.00 1 0.00 1 0 25 3.484e-02 1.136e-02 1.887e-03 4.461e-04 3.752393e-01 2.259051e-04 4.160903e-03 -6.000000e+00 1.998089e-02 229.96 -2.00 3.24 -2.00 317.85 0.00e+00 1.415089e-03 3.921507e-05 9.245312e-04 -6.000000e+00 9.234291e-04 294.38 -2.00 20.00 -2.00 316.88 0.00e+00 3.140 0.000 302.00 328.00 3 1.3439e+00 6.0744e-04 3.6111e-02 -6.0000e+00 4.9692e-02 -1.0700e-02 6.9031e-04 1.8178e-02 -6.0000e+00 5.3843e-02 -5.6030e-03 4.2542e-04 8.7171e-03 -6.0000e+00 3.2244e-02 -5.5760e-03 2.1566e-04 2.3564e-03 -6.0000e+00 1.3738e-02 3.9530e-03 4.1068e-04 1.2595e-05 2.4593e-05 -6.0000e+00 9.4654e-04 1.6482e-02 0.0000e+00 12 8 8 10 0 0 10.37 27.13 0.39 0.01648 0.01957 439 49 1 5 0 123.070 34.50 20.00 27.13 34.05 23.5 1020.14 -8473 -2455 -8387 -13736 -11565 -14589 -12713 -9544 -9722 -9609 -11762 -7988 -5313 -2317 1225 192 385 1275 2274 2660 248 919 1308 922 961 40 -568 -3355 -2815 -2193 -104 640 -24 -3720 -5576 -4999 -3697 -861 761 754 912 1159 1111 1110 1259 1455 726 95 -359 461 1552 1178 1682 1637 1313 1438 791 393 32 767 1600 2280 3310 2571 663 -335 -1462 -1045 519 925 1184 1017 757 311 -745 -1920 -3331 -3585 -2600 -2407 -1793 -1920 -2491 -1516 -611 152 833 1370 1268 931 403 -991 -1777 -1494 -1372 -691 397 735 176 -435 -1377 -2205 -1752 -754 -1116 -617 -185 36 1065 1748 2057 1821 1220 236 -460 -200 114 373 713 694 598 880 637 295 244 -876 -731 -114 -250 -247 -606 -816 -892 -351 -47 14 661 742 429 159 -250 -725 -594 -616 -183 -669 -1057 -801 -1063 -1004 -827 -932 -953 -1211 -803 -619 -312 186 33 69 223 414 503 48 179 269 203 224 10 -137 -784 -635 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