File name: Pandora85s1_NewOrleansLA-XULA_20240804_L2Fit_fout2c6d20240531p1-8.txt File generation date: 20260326T085259.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v6d20240531.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240804_L1_smca1c6d20240531p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1050 305.2456 305.3862 305.5268 305.6674 305.8080 305.9486 306.0892 306.2297 306.3703 306.5108 306.6513 306.7918 306.9323 307.0728 307.2133 307.3537 307.4942 307.6346 307.7751 307.9155 308.0559 308.1963 308.3367 308.4770 308.6174 308.7577 308.8981 309.0384 309.1787 309.3190 309.4593 309.5996 309.7398 309.8801 310.0203 310.1606 310.3008 310.4410 310.5812 310.7214 310.8615 311.0017 311.1418 311.2820 311.4221 311.5622 311.7023 311.8424 311.9825 312.1226 312.2626 312.4027 312.5427 312.6827 312.8227 312.9627 313.1027 313.2427 313.3826 313.5226 313.6625 313.8025 313.9424 314.0823 314.2222 314.3621 314.5019 314.6418 314.7816 314.9215 315.0613 315.2011 315.3409 315.4807 315.6205 315.7602 315.9000 316.0397 316.1795 316.3192 316.4589 316.5986 316.7383 316.8779 317.0176 317.1573 317.2969 317.4365 317.5761 317.7157 317.8553 317.9949 318.1345 318.2740 318.4136 318.5531 318.6926 318.8321 318.9716 319.1111 319.2506 319.3900 319.5295 319.6689 319.8084 319.9478 320.0872 320.2266 320.3659 320.5053 320.6447 320.7840 320.9233 321.0627 321.2020 321.3413 321.4806 321.6198 321.7591 321.8983 322.0376 322.1768 322.3160 322.4552 322.5944 322.7336 322.8728 323.0119 323.1511 323.2902 323.4293 323.5684 323.7075 323.8466 323.9857 324.1248 324.2638 324.4028 324.5419 324.6809 324.8199 324.9589 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240804T120555.6Z 8982.504116 52 1 53.25 2 81.72 75.08 82.17 70.86 0.00 1 0.00 1 0 25 7.005e-01 3.923e-02 2.536e-01 6.657e-03 7.560484e-01 3.824323e-03 7.868160e-03 -6.000000e+00 4.171065e-01 229.77 -2.00 3.24 -2.00 321.54 0.00e+00 -6.593358e-03 2.181575e-03 5.768904e-03 -6.000000e+00 2.660623e-02 294.51 -2.00 20.00 -2.00 320.88 0.00e+00 6.510 0.003 302.00 328.00 3 2.5575e+00 1.4817e-02 8.3358e-02 -6.0000e+00 1.0371e+00 4.8743e-01 2.0475e-02 6.3721e-02 -6.0000e+00 1.1316e+00 -7.8008e-01 1.8374e-02 1.8941e-02 -6.0000e+00 6.8123e-01 3.2178e-01 8.5853e-03 1.2821e-02 -6.0000e+00 2.9533e-01 3.1091e-05 5.2849e-04 1.9090e-04 6.8365e-05 -6.0000e+00 1.9708e-02 1.4174e-02 0.0000e+00 12 9 8 11 32 0 49.71 27.20 0.98 0.01417 0.01815 26 3 1 5 0 2047.770 34.50 20.00 27.20 33.91 23.8 1010.99 900000 900000 -126718 -82309 900000 -68574 87566 -190888 -161028 900000 900000 900000 900000 900000 900000 25316 900000 900000 900000 900000 28775 21482 900000 900000 900000 900000 -10853 302247 900000 -80698 900000 229302 -31455 -72993 -5743 -1698 -10852 138697 99744 134973 245011 278052 -8472 13609 108554 900000 72769 9562 255925 31065 127874 20543 -13709 72192 44188 9582 35058 50444 34045 28471 56653 35187 -25316 31637 41322 -25769 25747 19046 21049 29093 24126 -12728 9382 303 -6060 -16824 7418 -7598 30562 -1837 313 337 -11262 8080 13936 -2728 -905 7659 -6067 7211 -6691 3747 -5467 -1657 -11855 1987 937 -1076 -3315 -988 -3688 67 -1248 -4226 -3892 1658 -901 -149 3045 -4310 4758 4338 2258 -1392 120 -4045 -2733 -1855 -2882 1815 2692 5168 2475 1769 -169 -3325 1193 -2534 646 1542 -135 106 2793 -1141 327 -722 -901 1752 1878 1205 -3312 -1516 -213 900000 900000 -2755 -1016 900000 -685 566 -8301 -5773 900000 900000 900000 900000 900000 900000 342 900000 900000 900000 900000 440 353 900000 900000 900000 900000 -319 1954 900000 -4648 900000 1482 -1850 -6512 -245 -71 -568 1972 2579 2879 1901 1797 -876 1108 3368 900000 3246 828 1985 2490 4381 2284 -2348 5693 4885 1567 4533 5446 4115 3534 5493 4686 -7021 5501 6651 -7929 4810 4051 4994 7297 6878 -4877 3063 100 -1916 -5329 1774 -2230 7112 -705 125 154 -6274 3951 6904 -1695 -576 4550 -4083 4034 -4011 1927 -3065 -964 -8799 1502 833 -1023 -3440 -982 -3494 60 -1053 -3807 -3771 1603 -874 -156 3446 -5972 6705 5984 3192 -1979 160 -5490 -3751 -2661 -4424 2725 3911 7612 3629 2524 -238 -4674 1580 -3773 989 2648 -241 202 5510 -2508 711 -1657 -2110 4052 4280 2618 -7537 -3186 -432 SS 20240804T122019.3Z 8982.514113 57 1 53.84 2 78.70 76.75 79.32 72.47 0.00 1 0.00 1 0 25 2.915e-01 1.394e-02 9.114e-02 1.929e-03 5.828148e-01 1.005344e-03 6.881617e-03 -6.000000e+00 1.673196e-01 229.77 -2.00 3.24 -2.00 320.31 0.00e+00 9.067828e-04 3.875781e-04 4.622948e-03 -6.000000e+00 7.825071e-03 294.51 -2.00 20.00 -2.00 319.48 0.00e+00 4.924 0.001 302.00 328.00 3 2.1971e+00 3.1491e-03 6.0729e-02 -6.0000e+00 4.1597e-01 -3.3859e-02 3.9953e-03 4.1569e-02 -6.0000e+00 4.5086e-01 -4.9627e-02 3.4933e-03 1.5279e-02 -6.0000e+00 2.7037e-01 1.2204e-02 1.7702e-03 4.7911e-03 -6.0000e+00 1.1573e-01 2.5412e-04 5.1546e-04 5.3246e-05 5.8452e-05 -6.0000e+00 7.9283e-03 1.3616e-02 0.0000e+00 12 8 8 10 0 0 28.36 27.27 0.57 0.01362 0.01749 94 10 1 5 0 572.650 34.50 20.01 27.27 34.73 23.8 1011.03 -54927 900000 -111161 -70783 65817 -105960 -76593 -149836 -125635 -93742 -5144 -70638 47491 -28384 900000 -32370 -10014 18415 12923 68733 -37637 -7890 24897 6624 -2917 23048 59527 -2708 -3762 -30485 26569 -6101 -10330 -24427 -20346 -9808 -22449 -62 1591 5976 9485 10313 -3687 -486 -9577 15259 2541 -1004 2680 1273 7165 1270 -1322 6405 3861 1614 3510 1472 1690 1951 3126 103 157 2370 4096 -4406 511 1974 2044 3755 3406 -519 1498 -316 -2321 -4505 -4071 -3515 -999 -1827 -1471 -1403 -3330 -552 1014 138 1824 2215 1308 1606 -381 -998 -2608 -1978 -2939 -263 400 -32 136 -328 -1895 -1887 -2013 -1422 -1614 -160 -357 440 1286 1295 2521 2333 1389 77 -988 -1131 -610 118 269 917 657 1056 1036 127 42 -1561 -799 -394 -426 -310 -780 -720 -489 -568 35 -139 301 1093 840 204 -452 -498 -201 -403 900000 -1672 -665 148 -1395 -850 -4000 -2976 -1727 -42 -1302 339 -544 900000 -919 -252 384 306 982 -1585 -252 623 219 -115 737 1321 -107 -151 -1794 1049 -390 -783 -2177 -1664 -754 -2254 -6 189 799 1352 1553 -607 -79 -1730 2418 424 -179 483 252 1499 313 -365 1776 1158 516 1130 479 535 617 1035 39 62 1009 1735 -1960 216 861 1006 2085 1903 -311 860 -173 -1282 -2298 -1968 -1749 -554 -1112 -1033 -1032 -2697 -462 900 123 1676 2075 1227 1431 -345 -853 -2197 -1737 -2746 -276 450 -38 173 -410 -2232 -2139 -2150 -1575 -1935 -188 -445 584 1753 1861 3902 3747 2219 120 -1453 -1700 -931 179 433 1521 1081 1675 1595 190 63 -2319 -1150 -600 -692 -531 -1385 -1350 -915 -1130 71 -295 652 2295 1834 428 -907 -995 -395 SS 20240804T122618.4Z 8982.518268 60 1 54.12 2 77.44 77.43 78.12 73.13 0.00 1 0.00 1 0 33 1.978e-01 1.232e-02 2.692e-02 1.254e-03 5.342672e-01 6.429575e-04 6.206239e-03 -6.000000e+00 1.133912e-01 229.77 -2.00 3.24 -2.00 319.78 0.00e+00 1.030819e-03 2.061000e-04 3.333530e-03 -6.000000e+00 5.245186e-03 294.51 -2.00 20.00 -2.00 318.90 0.00e+00 4.466 0.001 302.00 328.00 3 1.8891e+00 1.9009e-03 5.3443e-02 -6.0000e+00 2.8186e-01 -4.8635e-02 2.3057e-03 3.2980e-02 -6.0000e+00 3.0538e-01 -2.4746e-02 1.8642e-03 1.3462e-02 -6.0000e+00 1.8293e-01 2.5770e-03 9.7252e-04 3.7270e-03 -6.0000e+00 7.8025e-02 5.5905e-04 4.7883e-04 3.4635e-05 4.3108e-05 -6.0000e+00 5.3718e-03 1.2932e-02 0.0000e+00 12 8 8 10 0 0 23.17 27.32 0.49 0.01293 0.01653 159 18 1 5 0 340.320 34.50 20.01 27.32 35.02 23.8 1011.03 -71064 28158 -70733 -73580 -51391 -72604 -60081 -93386 -67516 -60807 -46346 -44712 -16450 -30014 23713 -18261 -6254 -2646 -2538 8739 -24199 -11111 -206 -2410 4634 -2012 5951 -10219 -7920 -15153 3196 -4110 -4779 -12489 -13824 -8660 -10889 -4442 141 2773 3603 4070 -762 1734 -1632 5786 2597 -36 1664 1295 2944 1295 693 3387 2926 1040 1969 289 115 1419 2593 1327 2803 3000 2397 -1220 -678 -433 1799 2705 1946 784 1464 31 -1119 -2810 -3662 -4191 -2146 -2147 -1869 -1636 -2823 -1054 247 335 1528 2036 1540 1390 -156 -900 -2241 -1498 -2285 -686 338 517 -16 -529 -1680 -2515 -1964 -1117 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