File name: Pandora85s1_NewOrleansLA-XULA_20240810_L2Fit_fout2c6d20240531p1-8.txt File generation date: 20260326T085739.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v6d20240531.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240810_L1_smca1c6d20240531p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1050 305.2456 305.3862 305.5268 305.6674 305.8080 305.9486 306.0892 306.2297 306.3703 306.5108 306.6513 306.7918 306.9323 307.0728 307.2133 307.3537 307.4942 307.6346 307.7751 307.9155 308.0559 308.1963 308.3367 308.4770 308.6174 308.7577 308.8981 309.0384 309.1787 309.3190 309.4593 309.5996 309.7398 309.8801 310.0203 310.1606 310.3008 310.4410 310.5812 310.7214 310.8615 311.0017 311.1418 311.2820 311.4221 311.5622 311.7023 311.8424 311.9825 312.1226 312.2626 312.4027 312.5427 312.6827 312.8227 312.9627 313.1027 313.2427 313.3826 313.5226 313.6625 313.8025 313.9424 314.0823 314.2222 314.3621 314.5019 314.6418 314.7816 314.9215 315.0613 315.2011 315.3409 315.4807 315.6205 315.7602 315.9000 316.0397 316.1795 316.3192 316.4589 316.5986 316.7383 316.8779 317.0176 317.1573 317.2969 317.4365 317.5761 317.7157 317.8553 317.9949 318.1345 318.2740 318.4136 318.5531 318.6926 318.8321 318.9716 319.1111 319.2506 319.3900 319.5295 319.6689 319.8084 319.9478 320.0872 320.2266 320.3659 320.5053 320.6447 320.7840 320.9233 321.0627 321.2020 321.3413 321.4806 321.6198 321.7591 321.8983 322.0376 322.1768 322.3160 322.4552 322.5944 322.7336 322.8728 323.0119 323.1511 323.2902 323.4293 323.5684 323.7075 323.8466 323.9857 324.1248 324.2638 324.4028 324.5419 324.6809 324.8199 324.9589 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240810T120913.8Z 8988.506409 51 1 53.91 2 81.69 77.06 147.40 61.32 0.00 1 0.00 1 0 25 6.557e-01 4.416e-02 2.117e-01 6.926e-03 7.448590e-01 3.968358e-03 9.136373e-03 -6.000000e+00 3.908479e-01 229.65 -2.00 3.24 -2.00 321.49 0.00e+00 6.011551e-03 2.198962e-03 1.003253e-02 -6.000000e+00 2.493552e-02 294.59 -2.00 20.00 -2.00 320.83 0.00e+00 6.486 0.003 302.00 328.00 3 2.5493e+00 1.5163e-02 9.0462e-02 -6.0000e+00 9.6654e-01 7.8466e-01 1.9373e-02 7.3208e-02 -6.0000e+00 1.0528e+00 -1.1012e+00 1.5656e-02 2.1069e-02 -6.0000e+00 6.3096e-01 4.5010e-01 7.7158e-03 8.4374e-03 -6.0000e+00 2.7514e-01 2.8787e-05 -7.0138e-04 1.9758e-04 1.3295e-04 -6.0000e+00 1.8833e-02 1.2847e-02 0.0000e+00 12 8 8 10 0 0 -32.58 27.02 1.05 0.01285 0.00758 24 3 1 5 0 2246.010 34.25 20.01 27.02 32.96 21.1 1016.06 900000 900000 900000 -115828 900000 -23898 900000 -132597 -21796 63044 900000 900000 900000 84870 900000 -35 351698 900000 900000 900000 57708 186174 900000 76875 900000 900000 900000 145152 900000 -50242 900000 74859 12604 -78176 90732 779 -7579 85331 120005 210091 234304 900000 26687 56104 -12809 900000 67445 27446 210609 86866 135322 27857 -13612 103657 74698 15533 24665 42731 19323 28044 93853 5123 -20410 1956 48391 -5649 61551 19330 22411 41523 43763 -16937 16420 -1326 -4998 -14525 3077 -8955 23080 1701 -4864 3450 -13849 5939 15302 -2248 1561 8599 -7083 6454 -4010 -4758 -9927 7052 -14190 1601 -541 -2284 -2091 716 -5719 -3180 1103 -6956 -5133 -459 -353 1072 -1144 -2351 4805 5466 2638 -1584 893 -2959 -3910 -3946 -2098 3217 4398 5118 2898 1872 664 -4969 1539 -1995 1575 283 1169 680 3087 -996 35 -1584 0 1441 670 583 -3069 -916 -436 900000 900000 900000 -6799 900000 -453 900000 -7865 -440 540 900000 900000 900000 1038 900000 -1 2366 900000 900000 900000 1341 1252 900000 1457 900000 900000 900000 1367 900000 -3349 900000 2165 755 -10469 2258 47 -545 2812 3309 2685 2522 900000 2423 3774 -1706 900000 4083 2548 3258 4966 5279 3485 -2774 6972 6934 2654 3849 5375 2924 3810 6881 1013 -5931 505 8040 -1565 8736 4382 5517 9608 10656 -7001 5147 -457 -1600 -4582 778 -2686 5837 637 -2067 1536 -7952 2960 7420 -1376 958 5016 -4786 3627 -2327 -2630 -5694 3648 -10447 1183 -478 -2164 -2125 697 -5520 -2927 896 -6287 -4912 -443 -363 1082 -1318 -3119 6622 7923 3648 -2215 1259 -4217 -5760 -5663 -3137 4695 6728 7453 4176 2631 911 -6986 1989 -2872 2319 480 2165 1356 5905 -2119 80 -3804 0 3237 1608 1327 -6771 -1855 -855 SS 20240810T122321.8Z 8988.516225 56 1 53.88 2 78.69 78.71 144.80 65.07 0.00 1 0.00 1 0 17 2.852e-01 1.468e-02 5.620e-02 1.926e-03 5.737683e-01 1.005571e-03 6.912947e-03 -6.000000e+00 1.639940e-01 229.65 -2.00 3.24 -2.00 320.29 0.00e+00 1.322333e-03 3.818298e-04 4.865923e-03 -6.000000e+00 7.824452e-03 294.59 -2.00 20.00 -2.00 319.45 0.00e+00 4.922 0.001 302.00 328.00 3 2.2083e+00 3.1409e-03 6.0922e-02 -6.0000e+00 4.0701e-01 -2.8750e-02 3.9578e-03 4.2395e-02 -6.0000e+00 4.4105e-01 -6.0307e-02 3.4125e-03 1.5256e-02 -6.0000e+00 2.6400e-01 1.7224e-02 1.7354e-03 4.8394e-03 -6.0000e+00 1.1313e-01 2.5470e-04 3.5690e-04 5.3572e-05 6.0866e-05 -6.0000e+00 7.7649e-03 1.1691e-02 0.0000e+00 12 8 8 10 0 0 25.92 27.09 0.63 0.01169 0.01437 95 11 1 5 0 567.140 34.25 20.00 27.09 33.74 21.2 1016.25 -33274 900000 -64614 -143219 900000 -131786 -65553 -130507 -113701 -84216 5273 -48828 -312 -35671 103430 -30990 3964 -4799 9194 35794 -24035 -12664 13586 -7340 16801 15600 31301 -17926 -1058 -35272 31479 -6687 -11140 -28113 -15180 -10720 -19273 -1317 798 5184 8656 14339 -3082 -168 -4651 10157 4107 -4037 5201 2920 6815 -1203 -2714 9578 5806 944 1808 1909 66 573 5925 -897 -99 1964 4717 -2288 3006 15 2768 4560 3518 -1122 1309 -212 -1980 -3863 -4309 -5360 -1736 -2107 -2371 -1561 -3616 -626 1577 715 1576 1903 1514 1479 217 -1562 -2585 -1719 -2566 -966 412 473 282 -486 -2148 -2178 -2431 -1210 -1551 -906 -51 363 1221 1665 2421 2524 1372 -85 -297 -777 -661 -424 -123 931 899 1342 1162 578 -157 -2077 -1154 -531 -157 -262 -539 -683 -579 -573 -158 -234 559 957 610 173 -279 -434 -180 -219 900000 -679 -3093 900000 -2475 -714 -3137 -2605 -1534 42 -779 -4 -790 699 -931 93 -135 242 760 -943 -452 403 -295 571 565 970 -872 -43 -2278 1235 -448 -887 -2713 -1229 -864 -1940 -134 98 719 1281 2135 -519 -28 -824 1745 694 -764 937 581 1460 -310 -774 2618 1736 309 601 628 22 187 1936 -350 -40 851 2014 -1009 1251 7 1359 2524 1974 -680 759 -118 -1101 -1977 -2103 -2728 -970 -1287 -1680 -1151 -2939 -524 1393 634 1453 1792 1423 1325 196 -1347 -2178 -1502 -2377 -1015 460 563 357 -606 -2535 -2476 -2603 -1333 -1854 -1067 -63 480 1658 2503 3731 4027 2183 -131 -432 -1157 -1003 -640 -198 1537 1470 2116 1783 858 -238 -3093 -1659 -803 -252 -444 -947 -1269 -1125 -1128 -318 -494 1198 2082 1326 362 -581 -861 -351 SS 20240810T122919.1Z 8988.520360 59 1 54.08 2 77.43 79.41 143.69 66.52 0.00 1 0.00 1 0 17 2.173e-01 1.302e-02 4.947e-02 1.321e-03 5.277181e-01 6.765146e-04 6.270968e-03 -6.000000e+00 1.245708e-01 229.65 -2.00 3.24 -2.00 319.77 0.00e+00 2.021253e-03 2.169920e-04 3.580766e-03 -6.000000e+00 5.765888e-03 294.59 -2.00 20.00 -2.00 318.89 0.00e+00 4.464 0.001 302.00 328.00 3 1.9907e+00 1.9998e-03 5.3467e-02 -6.0000e+00 3.0955e-01 -3.7311e-02 2.4236e-03 3.3220e-02 -6.0000e+00 3.3539e-01 -3.4203e-02 1.9471e-03 1.3679e-02 -6.0000e+00 2.0093e-01 5.9512e-03 1.0164e-03 3.4552e-03 -6.0000e+00 8.5752e-02 5.0764e-04 2.4106e-04 3.6490e-05 4.8914e-05 -6.0000e+00 5.9023e-03 1.1573e-02 0.0000e+00 12 8 8 10 0 0 25.31 27.14 0.49 0.01157 0.01338 147 16 1 5 0 367.850 34.50 20.00 27.14 34.04 21.1 1016.33 -69207 129490 -37533 -91415 -1862 -81820 -50733 -81824 -83666 -60869 -26937 -45930 -5009 -17829 2675 -27332 -6037 1068 -38 6425 -15794 -4413 -1758 -7538 -3156 8627 13612 -9641 -5273 -17369 6332 -3195 -5264 -16684 -14925 -9496 -12413 -2147 798 3363 3128 6802 -536 1470 -1036 6559 748 235 1781 1281 3681 481 67 3997 3207 1034 1727 504 647 491 3226 1241 2088 3460 2862 -497 138 -619 1147 2802 2578 353 1561 -465 -1365 -3133 -3537 -4975 -2638 -2673 -2184 -1642 -2714 -907 397 673 1400 2037 1647 1419 198 -1142 -2170 -1938 -2318 -863 351 558 162 -362 -1817 -2544 -2186 -1324 -1539 -542 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