File name: Pandora85s1_NewOrleansLA-XULA_20240917_L2Fit_fwvt1c6d20240531p1-8.txt File generation date: 20260326T090037.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v6d20240531.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240917_L1_smca1c6d20240531p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240917 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0445 492.1652 492.2859 492.4067 492.5273 492.6480 492.7687 492.8893 493.0100 493.1306 493.2512 493.3717 493.4923 493.6128 493.7334 493.8539 493.9744 494.0949 494.2153 494.3358 494.4562 494.5766 494.6970 494.8174 494.9377 495.0580 495.1784 495.2987 495.4190 495.5392 495.6595 495.7797 495.9000 496.0202 496.1403 496.2605 496.3807 496.5008 496.6209 496.7410 496.8611 496.9812 497.1012 497.2213 497.3413 497.4613 497.5813 497.7012 497.8212 497.9411 498.0610 498.1809 498.3008 498.4207 498.5405 498.6603 498.7802 498.9000 499.0197 499.1395 499.2592 499.3790 499.4987 499.6184 499.7380 499.8577 499.9773 500.0970 500.2166 500.3362 500.4557 500.5753 500.6948 500.8144 500.9339 501.0533 501.1728 501.2923 501.4117 501.5311 501.6505 501.7699 501.8893 502.0086 502.1280 502.2473 502.3666 502.4859 502.6051 502.7244 502.8436 502.9628 503.0820 503.2012 503.3203 503.4395 503.5586 503.6777 503.7968 503.9159 504.0350 504.1540 504.2730 504.3920 504.5110 504.6300 504.7489 504.8679 504.9868 505.1057 505.2246 505.3434 505.4623 505.5811 505.6999 505.8187 505.9375 506.0563 506.1750 506.2938 506.4125 506.5312 506.6499 506.7685 506.8872 507.0058 507.1244 507.2430 507.3616 507.4801 507.5987 507.7172 507.8357 507.9542 508.0726 508.1911 508.3095 508.4279 508.5463 508.6647 508.7831 508.9014 509.0198 509.1381 509.2564 509.3747 509.4929 509.6112 509.7294 509.8476 509.9658 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240917T122638.4Z 9026.518500 237 1 9.82 2 82.13 92.31 107.39 271.44 0.00 1 0.00 1 0 232 3.863e-02 3.806e-02 1.199e-02 1.138e-02 1.653733e+03 7.159240e+02 1.487287e+02 -6.000000e+00 2.232931e+03 293.32 -2.00 20.00 -2.00 504.74 0.00e+00 5.898711e-03 3.145651e-04 4.240274e-04 -6.000000e+00 1.113122e-03 293.32 -2.00 20.00 -2.00 499.06 0.00e+00 -3.567011e+00 2.366223e-01 5.768857e-02 -6.000000e+00 7.646837e-01 228.40 -2.00 3.24 -2.00 500.68 0.00e+00 6.803 0.004 489.00 513.00 1 8.2283e+00 1.8224e-02 1.4286e-02 -6.0000e+00 5.8801e-02 2.9920e-01 4.8481e-03 7.2277e-04 -6.0000e+00 1.5318e-02 2.3706e-04 4.1201e-02 1.1050e-03 1.5595e-04 -6.0000e+00 3.9480e-03 2.6412e-03 2.5974e-04 12 8 8 10 0 0 38.53 26.83 0.91 0.00264 0.28843 523 58 1 4 0 18.760 34.25 20.01 26.83 31.92 39.2 1012.56 304 1463 5674 4840 8084 6419 5150 2660 2168 -845 -3231 -2740 -4256 -2277 -3375 -630 4473 1094 468 956 2072 2151 2705 4582 1919 -1571 -2017 -5325 -5906 -6201 -4517 258 -269 1077 2162 -2330 -133 -1056 -1775 -1051 -330 3677 4289 5297 1573 213 -121 -3503 -5717 -9263 -6840 -4153 -3739 -2906 1940 1997 1555 3499 3243 4714 3639 3998 4374 732 -2103 -2132 -698 -5297 -1543 -5491 -3748 902 -2059 -3541 -4110 -4041 -4354 -5350 -7768 -3924 -3676 -1587 -1292 -1390 -2310 -2201 -3149 -1308 1823 274 2545 2929 423 -194 -261 -3922 -4363 -5009 -7498 -5584 -195 -116 1502 86 -3273 -2073 -2143 -937 -768 1824 4340 6302 8412 9263 8779 9283 3634 5106 1715 1687 1431 4733 7404 4087 1066 4271 1977 1004 638 1509 -1216 -2968 -3585 1176 4634 2829 2819 5838 1721 4115 5756 4349 3425 674 -1135 880 -1820 -8416 -1410 -1866 900000 388 1894 7177 6263 10196 7688 6158 3193 2563 -1007 -3863 -3213 -5041 -2656 -4030 -744 5087 1288 553 1120 2397 2491 3119 5163 2194 -1816 -2263 -5997 -6626 -7030 -5156 289 -307 1209 2371 -2635 -146 -1162 -1977 -1174 -370 4009 4674 5702 1739 235 -131 -3802 -6167 -10165 -7311 -4393 -4049 -3202 2069 2138 1669 3675 3421 4918 3836 4173 4490 767 -2226 -2222 -707 -5537 -1546 -5747 -3886 900 -2113 -3642 -4173 -4035 -4320 -5346 -7978 -3896 -3652 -1552 -1268 -1366 -2284 -2164 -3121 -1277 1742 270 2478 2839 415 -188 -248 -3744 -4070 -4618 -7069 -5233 -177 -108 1385 80 -3086 -1903 -1960 -805 -669 1574 3700 5311 6967 7618 7243 7555 3079 4179 1425 1382 1169 3747 5705 3246 869 3350 1577 801 502 1152 -935 -2287 -2767 873 3370 2117 2123 4273 1311 3053 4194 3203 2523 501 -835 617 -1284 -6320 -996 -1342 900000 SQ 20240917T122648.3Z 9026.518615 237 2 9.82 2 82.09 92.33 107.43 271.46 0.00 1 0.00 1 0 239 3.840e-02 3.795e-02 1.201e-02 1.140e-02 7.829057e+02 6.957479e+02 1.079957e+02 -6.000000e+00 2.219376e+03 293.32 -2.00 20.00 -2.00 504.75 0.00e+00 6.122664e-03 3.154433e-04 4.416265e-04 -6.000000e+00 1.105863e-03 293.32 -2.00 20.00 -2.00 499.08 0.00e+00 -3.047638e+00 2.377288e-01 5.705768e-02 -6.000000e+00 7.586021e-01 228.40 -2.00 3.24 -2.00 500.70 0.00e+00 6.777 0.004 489.00 513.00 1 8.1954e+00 1.8315e-02 1.4499e-02 -6.0000e+00 5.8358e-02 2.8996e-01 4.8894e-03 6.4904e-04 -6.0000e+00 1.5164e-02 2.3666e-04 3.1004e-02 1.0981e-03 1.6479e-04 -6.0000e+00 3.9227e-03 1.8556e-03 4.0719e-04 12 8 8 10 0 0 39.93 26.83 0.91 0.00186 0.21691 523 58 1 4 0 18.760 34.25 20.01 26.83 31.92 39.2 1012.59 -1952 1450 4250 5212 7399 6372 6121 4090 2512 -198 -1199 -2489 -3992 -3099 -666 -1414 2603 505 1339 1778 3281 1081 2356 1487 1847 750 -1325 -5460 -5932 -6208 -4485 -2773 -393 2175 1126 -566 -533 -3496 -440 553 667 1871 4618 4672 1424 2652 432 -2873 -6528 -7524 -8211 -7463 -2931 -2315 -432 384 4170 1441 860 5509 5530 1253 4569 2097 868 -1166 -1570 -4923 -4089 -3669 -2180 -1094 -2860 -1913 -2066 -3933 -5004 -5027 -6459 -5370 -3652 -1417 -2767 -2521 -1176 -3616 -4232 -655 918 -412 2120 1914 5144 2305 1317 -2919 -4882 -7464 -7972 -5253 -3891 -1096 2271 1623 -1651 -1447 -4718 -4358 2131 1382 6053 3113 8060 7667 6289 8054 6444 2414 6611 1100 1219 2947 6496 3383 5038 3918 3383 2462 997 2027 6 1197 -4355 1028 1400 571 242 2666 4992 6001 6405 2579 4103 2589 -410 -624 -3917 -4203 -3094 -2141 900000 -2504 1853 5401 6666 9359 7641 7769 4873 2978 -236 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