File name: Pandora85s1_NewOrleansLA-XULA_20260114_L2Fit_fout2c6d20250326p1-8.txt File generation date: 20260115T061342.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v6d20250326.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20260114_L1_smca1c6d20250326p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20260114 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 3 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0210 305.1616 305.3022 305.4428 305.5834 305.7240 305.8645 306.0051 306.1456 306.2862 306.4267 306.5672 306.7077 306.8481 306.9886 307.1291 307.2695 307.4099 307.5504 307.6908 307.8312 307.9716 308.1119 308.2523 308.3927 308.5330 308.6733 308.8136 308.9540 309.0943 309.2345 309.3748 309.5151 309.6553 309.7956 309.9358 310.0760 310.2162 310.3564 310.4966 310.6368 310.7769 310.9171 311.0572 311.1973 311.3375 311.4776 311.6176 311.7577 311.8978 312.0379 312.1779 312.3179 312.4580 312.5980 312.7380 312.8780 313.0179 313.1579 313.2978 313.4378 313.5777 313.7176 313.8576 313.9974 314.1373 314.2772 314.4171 314.5569 314.6968 314.8366 314.9764 315.1162 315.2560 315.3958 315.5356 315.6753 315.8151 315.9548 316.0945 316.2342 316.3739 316.5136 316.6533 316.7930 316.9326 317.0723 317.2119 317.3515 317.4911 317.6307 317.7703 317.9099 318.0494 318.1890 318.3285 318.4681 318.6076 318.7471 318.8866 319.0261 319.1655 319.3050 319.4444 319.5839 319.7233 319.8627 320.0021 320.1415 320.2809 320.4202 320.5596 320.6989 320.8383 320.9776 321.1169 321.2562 321.3955 321.5347 321.6740 321.8133 321.9525 322.0917 322.2309 322.3701 322.5093 322.6485 322.7877 322.9268 323.0660 323.2051 323.3442 323.4834 323.6225 323.7615 323.9006 324.0397 324.1787 324.3178 324.4568 324.5958 324.7348 324.8738 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260114T143535.7Z 9510.608052 181 1 0.78 2 72.57 128.25 57.33 178.05 0.00 1 0.00 1 0 17 5.559e-02 1.325e-02 4.058e-02 6.635e-03 4.273558e-01 3.367788e-03 4.938970e-03 -6.000000e+00 3.196482e-02 224.35 -2.00 3.24 -2.00 318.25 0.00e+00 2.336590e-03 6.478683e-04 1.436575e-03 -6.000000e+00 1.433654e-03 284.90 -2.00 20.00 -2.00 317.50 0.00e+00 3.290 0.000 302.00 328.00 3 1.4422e+00 9.0024e-03 3.8573e-02 -6.0000e+00 7.8740e-02 9.4179e-03 1.0241e-02 2.0670e-02 -6.0000e+00 8.5298e-02 -3.9571e-02 6.8307e-03 1.0404e-02 -6.0000e+00 5.1025e-02 1.3226e-02 3.6114e-03 3.0961e-03 -6.0000e+00 2.2136e-02 2.8346e-03 -6.0033e-04 1.8644e-04 3.3535e-05 -6.0000e+00 1.5465e-03 -1.2060e-02 0.0000e+00 12 9 9 12 1 1 999.00 23.92 0.32 -0.01206 -0.01657 2 23 1 5 0 257.280 32.25 20.01 23.92 16.47 4.3 965.61 -29945 -11623 -2354 -2682 -11707 -12898 -22531 -14010 -7102 -30120 -3620 -5718 -18928 -9719 -9458 -5996 4105 2836 1326 -3932 8974 -3897 3445 143 1368 2213 -4959 466 -3491 -7050 3587 2396 -4059 985 -1709 -4129 -5318 -4717 3062 -688 -278 1079 1893 1642 2667 1446 1434 -467 150 2626 -504 1156 -270 1619 693 764 2807 284 -133 -223 924 572 2490 4467 2731 -882 129 -476 476 743 1805 1818 -56 1683 -459 -777 -2637 -2813 -2126 -1648 -3581 -1658 -1637 -3010 -1438 -328 321 1313 1320 977 853 307 -1917 -2050 -1622 -1990 -815 523 692 -26 57 -1659 -2264 -1686 -378 -1515 -1241 -426 1019 1184 1791 2537 1967 600 107 -1453 311 711 981 1157 564 1165 1427 351 555 59 -1437 -472 413 -1456 -1109 -1027 -944 -812 -94 -183 547 148 780 881 -165 -587 -539 -1550 -587 -117 -134 -583 -609 -1210 -761 -404 -2358 -225 -377 -1641 -931 -990 -712 490 369 187 -615 1277 -633 527 24 241 407 -1012 88 -653 -1360 677 475 -965 243 -428 -1013 -1388 -1396 925 -241 -111 458 837 702 1140 633 632 -210 68 1178 -248 572 -147 926 400 455 1682 177 -82 -135 558 368 1639 3189 1997 -655 90 -344 333 580 1493 1535 -49 1415 -389 -600 -1976 -2103 -1530 -1325 -3062 -1506 -1572 -3116 -1489 -361 357 1511 1549 1135 936 326 -2016 -2066 -1684 -2203 -932 643 908 -34 75 -2139 -2789 -1987 -465 -1949 -1612 -580 1405 1699 2689 3889 3062 913 159 -2109 443 997 1447 1759 866 1826 2175 525 817 84 -2044 -649 594 -2190 -1746 -1668 -1591 -1374 -161 -326 1006 272 1452 1621 -303 -1063 -936 SS 20260114T152129.5Z 9510.639925 212 1 10.39 2 65.22 136.59 58.07 189.85 0.00 1 0.00 1 0 17 2.081e-02 1.087e-02 5.609e-03 1.597e-03 3.202711e-01 8.104560e-04 3.632430e-03 -6.000000e+00 1.196171e-02 224.35 -2.00 3.24 -2.00 317.37 0.00e+00 1.362466e-03 1.220634e-04 6.002512e-04 -6.000000e+00 5.365627e-04 284.90 -2.00 20.00 -2.00 316.63 0.00e+00 2.370 0.000 302.00 328.00 3 2.4822e+00 2.1231e-03 2.7956e-02 -6.0000e+00 2.9465e-02 1.4353e-02 2.3911e-03 1.4982e-02 -6.0000e+00 3.1921e-02 -4.6954e-03 1.4647e-03 7.4710e-03 -6.0000e+00 1.9095e-02 -6.4677e-03 7.4209e-04 2.2019e-03 -6.0000e+00 8.2827e-03 2.7740e-03 -8.4925e-05 4.5982e-05 2.3803e-05 -6.0000e+00 5.7881e-04 -1.0997e-02 0.0000e+00 12 9 9 12 1 1 99.71 23.96 0.42 -0.01100 -0.01163 24 14 1 5 0 415.360 32.50 20.01 23.96 17.75 4.3 970.79 -2978 -1559 -3598 -1656 -6289 -6678 -5568 -2220 -6349 -5129 -6886 -6897 -6051 -2204 -877 -885 144 1081 1391 1313 1394 764 726 1236 845 1573 -351 -1730 -2762 -1893 -962 -67 1940 -134 -3695 -4407 -4448 -3461 -272 764 -99 270 439 62 986 1595 372 394 -336 -377 405 1124 1313 1963 1476 1044 1159 589 214 308 612 1389 2459 2896 2258 -29 -445 -1618 -1016 1083 835 888 1000 960 282 -983 -1853 -3172 -2937 -2319 -2358 -1487 -2220 -2278 -1328 -515 184 674 1376 1490 692 61 -1176 -1639 -1451 -943 -429 712 1063 3 -593 -1150 -2000 -1377 -813 -988 -609 -380 246 1196 1570 1973 1674 1165 222 -533 -510 -73 230 780 649 635 854 729 450 -41 -1008 -667 -172 -414 -228 -652 -763 -663 -364 -77 210 732 750 210 -36 -524 -817 -257 -151 -378 -167 -601 -597 -506 -215 -716 -619 -862 -878 -852 -349 -146 -168 29 229 309 304 332 183 176 313 227 439 -102 -496 -749 -496 -264 -20 620 -43 -1199 -1369 -1452 -1273 -115 353 -52 140 237 35 545 881 207 216 -184 -206 230 683 851 1253 994 724 821 423 152 215 431 1028 1841 2350 1923 -24 -348 -1233 -786 911 743 843 968 908 253 -865 -1482 -2554 -2370 -1925 -2096 -1469 -2283 -2476 -1433 -593 212 807 1667 1776 823 67 -1272 -1679 -1512 -1011 -511 894 1388 4 -774 -1475 -2383 -1670 -990 -1297 -795 -521 336 1727 2316 3034 2572 1715 320 -718 -694 -101 319 1154 961 940 1292 1071 631 -58 -1366 -875 -234 -583 -342 -990 -1193 -1064 -587 -126 358 1267 1325 370 -62 -898 -1356 SS 20260114T152759.3Z 9510.644436 217 1 54.00 2 64.26 137.89 58.33 191.48 0.00 1 0.00 1 0 17 2.235e-02 1.009e-02 3.060e-03 6.018e-04 3.102144e-01 3.057646e-04 3.613766e-03 -6.000000e+00 1.284767e-02 224.35 -2.00 3.24 -2.00 318.19 0.00e+00 1.674606e-03 5.736741e-05 9.670170e-04 -6.000000e+00 5.762887e-04 284.90 -2.00 20.00 -2.00 317.45 0.00e+00 2.289 0.000 302.00 328.00 3 1.8488e+00 8.1573e-04 2.7208e-02 -6.0000e+00 3.1648e-02 1.5834e-02 9.2682e-04 1.4999e-02 -6.0000e+00 3.4285e-02 -9.5236e-04 6.0103e-04 7.5288e-03 -6.0000e+00 2.0509e-02 -1.0049e-02 3.1381e-04 2.2274e-03 -6.0000e+00 8.8964e-03 5.7273e-03 -8.0328e-05 1.7660e-05 2.4625e-05 -6.0000e+00 6.2167e-04 -1.1201e-02 0.0000e+00 12 8 8 10 0 0 99.98 23.98 0.39 -0.01120 -0.01180 501 56 1 5 0 107.760 32.25 20.01 23.98 18.21 4.3 972.60 -4797 -3159 -3054 -4068 -6430 -6935 -9132 -4204 -5054 -4599 -7927 -8094 -5160 -3360 -1147 -547 -698 829 613 1636 1534 352 1037 400 359 -370 -750 -1675 -2664 -1982 -688 -217 610 -610 -3841 -4562 -3720 -2725 -1317 -171 -86 -269 124 424 587 1230 385 320 -210 -222 632 981 1339 1609 1386 1227 1065 510 267 11 825 1562 2411 3087 1990 132 -493 -1465 -433 854 768 1125 959 959 273 -832 -1858 -3118 -3083 -2271 -1947 -1767 -2082 -2152 -1261 -506 229 796 1373 1322 634 145 -1063 -1529 -1378 -1075 -323 623 1006 95 -542 -1348 -2087 -1578 -826 -1179 -872 -415 35 1086 1651 1881 1543 1010 3 -608 -484 -81 296 833 520 529 746 617 178 -17 -1082 -754 -164 -463 -393 -574 -841 -698 -213 73 -5 584 758 296 41 -254 -745 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