File name: Pandora85s1_NewOrleansLA-XULA_20260217_L2Fit_fout2c5d20250716p1-8.txt File generation date: 20260326T101218.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v5d20250716.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20260217_L1_smca1c5d20250716p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20260217 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0150 305.1556 305.2961 305.4367 305.5772 305.7178 305.8583 305.9988 306.1393 306.2798 306.4203 306.5608 306.7012 306.8417 306.9821 307.1226 307.2630 307.4034 307.5438 307.6842 307.8245 307.9649 308.1052 308.2456 308.3859 308.5262 308.6665 308.8068 308.9471 309.0874 309.2276 309.3679 309.5081 309.6484 309.7886 309.9288 310.0690 310.2091 310.3493 310.4895 310.6296 310.7698 310.9099 311.0500 311.1901 311.3302 311.4703 311.6104 311.7504 311.8905 312.0305 312.1705 312.3105 312.4505 312.5905 312.7305 312.8705 313.0104 313.1504 313.2903 313.4302 313.5702 313.7101 313.8499 313.9898 314.1297 314.2695 314.4094 314.5492 314.6891 314.8289 314.9687 315.1085 315.2482 315.3880 315.5278 315.6675 315.8072 315.9469 316.0867 316.2264 316.3660 316.5057 316.6454 316.7850 316.9247 317.0643 317.2039 317.3435 317.4831 317.6227 317.7623 317.9019 318.0414 318.1809 318.3205 318.4600 318.5995 318.7390 318.8785 319.0179 319.1574 319.2969 319.4363 319.5757 319.7151 319.8545 319.9939 320.1333 320.2727 320.4120 320.5514 320.6907 320.8300 320.9694 321.1087 321.2479 321.3872 321.5265 321.6657 321.8050 321.9442 322.0834 322.2227 322.3619 322.5010 322.6402 322.7794 322.9185 323.0577 323.1968 323.3359 323.4750 323.6141 323.7532 323.8923 324.0313 324.1704 324.3094 324.4484 324.5875 324.7265 324.8655 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260217T145851.1Z 9544.624202 111 1 53.93 2 62.93 124.09 65.15 122.99 0.00 1 0.00 1 0 17 1.777e-02 9.879e-03 3.479e-03 9.248e-04 2.593026e-01 4.695294e-04 2.993318e-03 -6.000000e+00 1.025683e-02 225.38 -2.00 3.24 -2.00 317.74 0.00e+00 1.165235e-03 7.602124e-05 6.891294e-04 -6.000000e+00 4.580082e-04 284.77 -2.00 20.00 -2.00 316.97 0.00e+00 2.185 0.000 302.00 328.00 3 2.8689e+00 1.2419e-03 2.4982e-02 -6.0000e+00 2.5326e-02 2.0782e-02 1.4023e-03 1.2399e-02 -6.0000e+00 2.7416e-02 4.3361e-03 8.6895e-04 6.1270e-03 -6.0000e+00 1.6386e-02 -1.1977e-02 4.4171e-04 1.7694e-03 -6.0000e+00 7.0937e-03 2.4872e-03 1.5699e-04 2.7355e-05 1.8982e-05 -6.0000e+00 4.9443e-04 -4.2406e-03 0.0000e+00 12 8 8 10 0 0 99.99 24.39 0.44 -0.00424 -0.00306 317 35 1 5 0 170.120 32.50 20.01 24.39 21.69 4.4 986.26 -1829 -969 -1545 -2446 -5936 -6320 -3753 -4411 -2784 -3863 -5484 -5713 -3779 -1650 61 86 812 857 1502 1271 1119 -186 1539 918 556 -176 35 -1731 -2375 -1819 -281 63 752 -407 -4315 -4362 -4063 -2633 -865 218 -88 -308 94 315 505 1051 809 102 -174 -177 685 638 1215 1545 1257 927 1127 621 116 275 553 1527 2279 2890 2054 -95 -746 -1595 -747 950 908 999 1028 873 429 -895 -1728 -2836 -2924 -2133 -1906 -1597 -2060 -2128 -1268 -465 10 688 1162 1339 662 132 -977 -1486 -1052 -1030 -468 765 961 126 -564 -1226 -1957 -1392 -772 -1100 -771 -350 -43 1086 1620 1759 1562 1038 180 -669 -428 -121 277 781 415 512 588 515 262 48 -883 -622 -199 -372 -574 -698 -799 -780 -166 -29 124 657 738 302 46 -200 -669 -156 -92 -155 -240 -542 -537 -318 -413 -286 -432 -629 -659 -469 -230 10 15 152 167 303 266 241 -41 332 209 133 -44 9 -435 -558 -410 -65 16 200 -116 -1241 -1190 -1159 -841 -321 95 -43 -161 51 174 279 577 441 55 -92 -92 367 366 736 895 763 577 713 398 74 171 349 1009 1622 2206 1634 -73 -536 -1102 -519 717 767 900 946 787 368 -710 -1242 -2097 -2151 -1548 -1558 -1451 -2047 -2229 -1393 -546 12 810 1391 1577 806 148 -1014 -1448 -1030 -1093 -549 987 1238 167 -722 -1607 -2393 -1656 -973 -1372 -1005 -476 -61 1619 2554 2879 2535 1607 260 -898 -552 -158 381 1152 644 801 903 768 372 66 -1253 -852 -281 -518 -851 -1082 -1270 -1270 -281 -52 213 1156 1326 541 80 -364 -1187 SS 20260217T152612.6Z 9544.643201 129 1 16.35 2 58.18 129.51 60.36 128.00 0.00 1 0.00 1 0 17 1.519e-02 1.072e-02 5.453e-03 2.476e-03 2.272916e-01 1.262396e-03 2.570279e-03 -6.000000e+00 8.768644e-03 225.38 -2.00 3.24 -2.00 316.39 0.00e+00 1.023716e-03 1.475777e-04 3.016081e-04 -6.000000e+00 3.915294e-04 284.77 -2.00 20.00 -2.00 315.68 0.00e+00 1.890 0.000 302.00 328.00 3 4.3423e+00 3.2615e-03 2.1580e-02 -6.0000e+00 2.1652e-02 3.9229e-02 3.6448e-03 1.0596e-02 -6.0000e+00 2.3438e-02 1.1905e-03 2.1309e-03 5.2162e-03 -6.0000e+00 1.4008e-02 -9.2758e-03 1.0177e-03 1.5208e-03 -6.0000e+00 6.0648e-03 7.9595e-04 1.3139e-04 7.1761e-05 1.8249e-05 -6.0000e+00 4.2266e-04 -4.7504e-03 0.0000e+00 12 9 9 12 1 1 99.66 24.49 0.49 -0.00475 -0.00376 7 3 1 5 0 2042.910 32.75 20.01 24.49 22.58 4.4 989.92 -534 -201 2216 -436 -4689 -2627 -4090 -2557 -197 -781 -4647 -4255 -3003 -492 1644 347 503 917 1161 1530 2582 677 1177 1949 913 -34 -38 -1648 -840 -1797 -503 225 771 -542 -4493 -3984 -3322 -2641 -322 418 388 -15 488 463 -56 614 585 -462 -531 -394 423 836 1470 1758 601 1152 910 499 20 90 321 1820 2465 2837 1123 0 -521 -1426 -1133 910 481 854 827 550 585 -454 -1633 -3438 -2294 -2121 -1900 -1740 -2189 -2403 -777 -210 239 570 1406 1620 839 523 -912 -1530 -1737 -949 -45 437 891 -119 -396 -1262 -1960 -1126 -1046 -1505 -976 -155 -126 1132 1631 1805 1659 1160 136 -468 -460 56 131 845 526 421 852 856 261 93 -845 -476 -129 -355 -836 -322 -611 -739 -240 122 169 854 561 225 -83 -341 -1060 -90 -38 421 -82 -823 -417 -672 -451 -38 -161 -1003 -910 -687 -124 421 100 153 288 377 511 875 233 404 692 343 -13 -15 -643 -301 -622 -177 84 306 -230 -1914 -1595 -1383 -1236 -159 243 253 -9 321 311 -38 410 386 -300 -363 -265 290 561 1037 1301 468 909 732 405 16 71 258 1515 2047 2521 1044 0 -460 -1206 -963 776 460 868 859 562 566 -406 -1425 -2812 -1832 -1837 -1714 -1740 -2229 -2577 -867 -251 283 702 1752 1985 1040 596 -960 -1613 -1841 -1005 -53 525 1160 -160 -511 -1530 -2369 -1322 -1309 -1910 -1290 -213 -170 1592 2418 2765 2510 1667 194 -616 -582 72 177 1221 755 611 1209 1180 365 123 -1079 -623 -163 -478 -1200 -450 -875 -1082 -366 196 268 1378 926 370 -133 -531 -1704 SS 20260217T153523.6Z 9544.649578 132 1 22.33 2 56.66 131.48 58.82 129.81 0.00 1 0.00 1 0 17 1.522e-02 1.063e-02 4.343e-03 1.951e-03 2.183628e-01 9.972651e-04 2.491812e-03 -6.000000e+00 8.783843e-03 225.38 -2.00 3.24 -2.00 316.44 0.00e+00 7.802300e-04 1.183210e-04 3.460497e-04 -6.000000e+00 3.922253e-04 284.77 -2.00 20.00 -2.00 315.72 0.00e+00 1.814 0.000 302.00 328.00 3 4.2666e+00 2.5824e-03 2.0728e-02 -6.0000e+00 2.1689e-02 3.5222e-02 2.8823e-03 1.0200e-02 -6.0000e+00 2.3479e-02 7.2721e-04 1.6890e-03 5.0186e-03 -6.0000e+00 1.4032e-02 -8.3855e-03 8.0956e-04 1.4345e-03 -6.0000e+00 6.0751e-03 9.4225e-04 1.4552e-04 5.6890e-05 1.7315e-05 -6.0000e+00 4.2342e-04 -4.3933e-03 0.0000e+00 12 9 9 12 1 1 99.96 24.52 0.44 -0.00439 -0.00330 17 5 1 5 0 1240.290 32.75 20.00 24.52 22.68 4.4 989.96 -629 2055 -556 -1182 -5262 -3068 -3462 -2576 -699 -2274 -4709 -4271 -2827 352 -107 856 391 1292 1931 1839 1302 483 1411 1506 815 718 261 -1012 -1601 -1652 254 373 822 -1092 -3851 -3630 -3480 -2812 -1127 713 5 -173 395 604 253 785 638 -268 183 -520 311 824 922 1391 1620 891 728 250 186 356 593 1467 2153 2610 1733 -370 -944 -1761 -669 1036 655 973 421 1300 348 -1051 -1438 -3082 -2953 -1939 -1988 -1817 -2012 -2644 -1055 -790 293 895 1320 1169 604 239 -1140 -1374 -1449 -889 -316 667 1169 164 -530 -967 -1976 -1482 -676 -1260 -986 -244 39 997 1549 2066 1675 1163 248 -248 -359 -277 429 815 690 520 933 583 266 -88 -817 -621 58 -429 -507 -601 -673 -812 -345 -7 -72 545 476 365 176 -391 -818 -105 373 -108 -222 -920 -484 -559 -450 -133 -472 -1006 -902 -635 87 -30 239 116 391 601 591 431 161 466 517 295 270 100 -378 -555 -601 93 132 309 -442 -1543 -1371 -1374 -1247 -580 427 3 -113 265 413 173 533 429 -177 116 -328 199 559 660 1042 1261 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