File name: Pandora85s1_NewOrleansLA-XULA_20260221_L2Fit_fout2c5d20250716p1-8.txt File generation date: 20260326T101556.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v5d20250716.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20260221_L1_smca1c5d20250716p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20260221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0150 305.1556 305.2961 305.4367 305.5772 305.7178 305.8583 305.9988 306.1393 306.2798 306.4203 306.5608 306.7012 306.8417 306.9821 307.1226 307.2630 307.4034 307.5438 307.6842 307.8245 307.9649 308.1052 308.2456 308.3859 308.5262 308.6665 308.8068 308.9471 309.0874 309.2276 309.3679 309.5081 309.6484 309.7886 309.9288 310.0690 310.2091 310.3493 310.4895 310.6296 310.7698 310.9099 311.0500 311.1901 311.3302 311.4703 311.6104 311.7504 311.8905 312.0305 312.1705 312.3105 312.4505 312.5905 312.7305 312.8705 313.0104 313.1504 313.2903 313.4302 313.5702 313.7101 313.8499 313.9898 314.1297 314.2695 314.4094 314.5492 314.6891 314.8289 314.9687 315.1085 315.2482 315.3880 315.5278 315.6675 315.8072 315.9469 316.0867 316.2264 316.3660 316.5057 316.6454 316.7850 316.9247 317.0643 317.2039 317.3435 317.4831 317.6227 317.7623 317.9019 318.0414 318.1809 318.3205 318.4600 318.5995 318.7390 318.8785 319.0179 319.1574 319.2969 319.4363 319.5757 319.7151 319.8545 319.9939 320.1333 320.2727 320.4120 320.5514 320.6907 320.8300 320.9694 321.1087 321.2479 321.3872 321.5265 321.6657 321.8050 321.9442 322.0834 322.2227 322.3619 322.5010 322.6402 322.7794 322.9185 323.0577 323.1968 323.3359 323.4750 323.6141 323.7532 323.8923 324.0313 324.1704 324.3094 324.4484 324.5875 324.7265 324.8655 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260221T140529.4Z 9548.587145 78 1 53.93 2 72.07 113.95 99.92 69.25 0.00 1 0.00 1 0 25 4.660e-02 9.891e-03 2.048e-02 1.917e-03 3.518058e-01 9.920123e-04 4.246368e-03 -6.000000e+00 2.691874e-02 225.64 -2.00 3.24 -2.00 319.37 0.00e+00 1.757752e-03 2.589254e-04 2.067314e-03 -6.000000e+00 1.202072e-03 284.93 -2.00 20.00 -2.00 318.63 0.00e+00 3.204 0.000 302.00 328.00 3 2.8511e+00 2.7884e-03 3.6850e-02 -6.0000e+00 6.6502e-02 -7.9940e-03 3.2550e-03 1.9954e-02 -6.0000e+00 7.1984e-02 6.9719e-03 2.4136e-03 9.5926e-03 -6.0000e+00 4.3018e-02 -1.4739e-02 1.2667e-03 2.5634e-03 -6.0000e+00 1.8607e-02 8.4346e-04 3.9199e-04 5.8474e-05 3.4679e-05 -6.0000e+00 1.2970e-03 -1.1834e-03 0.0000e+00 12 8 8 10 0 0 99.99 25.41 0.52 -0.00118 0.00176 223 25 1 5 0 241.790 33.25 20.00 25.41 28.59 4.4 1013.94 -4775 -19100 -8039 -13663 -15884 -20706 -20925 -1102 -14089 -13471 -4941 -12857 -11693 1985 -4033 -3039 -2107 -4254 -2465 -2627 69 -1088 -2810 -1782 -1719 2232 -3870 -3474 -6214 -6904 -1354 -1329 1145 319 -7118 -6181 -4620 -2331 -2656 1348 -896 899 -598 775 806 1103 469 647 1016 100 1276 1194 1793 2030 1486 1424 2251 672 -97 164 -132 2022 3051 3152 2691 222 135 -1375 -140 1492 826 1227 832 776 -312 -559 -1930 -3695 -2994 -1937 -1951 -1708 -1860 -2438 -1084 -762 183 968 1282 1442 828 -213 -1528 -1607 -1530 -967 -278 928 1128 -123 -654 -1333 -2029 -1450 -474 -1338 -820 -11 188 1166 1708 1802 1508 936 -232 -697 -448 104 386 694 362 569 661 448 196 -62 -1252 -894 -341 -660 -604 -819 -903 -808 -416 153 27 595 736 308 269 -80 -629 -112 -594 -239 -422 -456 -588 -619 -30 -484 -499 -189 -550 -562 99 -252 -216 -162 -355 -215 -240 6 -101 -271 -180 -184 242 -457 -397 -689 -761 -152 -165 154 46 -1091 -899 -701 -396 -541 316 -243 256 -181 238 249 343 147 201 313 32 418 425 681 821 637 628 1010 309 -44 74 -61 966 1582 1787 1603 131 74 -749 -77 909 569 899 624 568 -217 -355 -1124 -2057 -1683 -1201 -1383 -1359 -1626 -2269 -1057 -797 183 1002 1348 1491 892 -213 -1434 -1434 -1404 -972 -312 1051 1402 -158 -814 -1551 -2410 -1671 -576 -1604 -1027 -14 260 1710 2684 2971 2490 1486 -347 -976 -605 143 561 1078 587 920 1045 690 289 -88 -1705 -1185 -472 -997 -981 -1407 -1602 -1479 -799 312 58 1285 1619 674 567 -163 -1244 SS 20260221T141325.0Z 9548.592650 84 1 3.14 2 70.50 115.18 98.35 70.26 0.00 1 0.00 1 0 17 5.218e-02 1.319e-02 3.996e-02 8.727e-03 3.308748e-01 4.442729e-03 3.681138e-03 -6.000000e+00 3.013952e-02 225.64 -2.00 3.24 -2.00 317.74 0.00e+00 1.717084e-03 7.329432e-04 6.143126e-04 -6.000000e+00 1.345906e-03 284.93 -2.00 20.00 -2.00 316.98 0.00e+00 2.962 0.000 302.00 328.00 3 3.5984e+00 1.1744e-02 3.3295e-02 -6.0000e+00 7.4458e-02 1.3882e-02 1.3243e-02 1.5579e-02 -6.0000e+00 8.0597e-02 1.1070e-03 8.3929e-03 7.7865e-03 -6.0000e+00 4.8166e-02 -8.3478e-03 4.3400e-03 2.4597e-03 -6.0000e+00 2.0833e-02 5.1053e-04 6.4787e-04 2.5267e-04 2.4694e-05 -6.0000e+00 1.4521e-03 -1.1302e-03 0.0000e+00 12 9 9 12 1 1 999.00 25.44 0.58 -0.00113 0.00374 1 4 1 5 0 1566.640 33.25 20.00 25.44 28.90 4.4 1015.16 -6211 21543 -6124 -11421 21052 -18448 397 19555 -9751 8788 -26769 -16059 -931 2062 14663 3279 4279 -6461 -5018 4625 -787 4 -1665 4891 -4689 145 -2021 -2647 -836 -354 -477 5034 -1909 -4303 -3888 -2292 -6595 1089 -647 -358 588 -987 -90 2142 683 1573 1173 -785 1901 563 -485 894 1242 2147 4842 -910 1898 199 1684 -504 -285 2476 4047 1176 3283 -1910 -680 -1579 -281 1391 385 15 727 -377 -559 -2235 -689 -2289 -2184 -2063 -3526 -1487 -1735 -2593 -1197 1190 318 2236 2856 1639 -268 583 -1246 -1644 -1534 -66 -757 -375 -355 601 208 -1897 -2050 -1095 -1352 -2191 61 -446 277 1642 860 1530 1161 758 146 -540 -167 1232 700 890 593 -686 1582 491 381 -92 -425 -457 -134 -955 34 -209 -287 -1107 190 -100 -311 -83 1102 627 673 -291 -1768 -428 1283 -511 -982 1182 -1444 27 1198 -896 726 -3212 -1777 -100 253 1859 485 679 -1205 -975 852 -158 1 -341 992 -1106 34 -497 -635 -185 -77 -110 1215 -544 -1345 -1176 -653 -2077 333 -240 -158 268 -487 -46 1097 357 820 613 -413 967 292 -267 525 723 1317 3038 -621 1288 139 1136 -343 -197 1650 2907 948 2528 -1487 -520 -1181 -213 1086 340 14 654 -335 -498 -1842 -538 -1701 -1643 -1723 -3192 -1393 -1782 -2682 -1295 1353 366 2637 3410 1949 -305 640 -1282 -1705 -1630 -72 -879 -462 -480 821 273 -2367 -2489 -1287 -1700 -2837 80 -597 388 2427 1312 2322 1759 1150 207 -750 -223 1668 1008 1308 911 -1066 2355 716 555 -129 -597 -626 -182 -1423 51 -334 -450 -1805 323 -173 -538 -146 1963 1112 1196 -504 -2996 SS 20260221T141730.7Z 9548.595495 87 1 46.66 2 69.70 115.83 97.54 70.77 0.00 1 0.00 1 0 25 3.103e-02 1.015e-02 2.575e-02 3.381e-03 3.150052e-01 1.725751e-03 3.648208e-03 -6.000000e+00 1.792557e-02 225.64 -2.00 3.24 -2.00 318.88 0.00e+00 1.702985e-03 3.913471e-04 1.351521e-03 -6.000000e+00 8.003341e-04 284.93 -2.00 20.00 -2.00 318.13 0.00e+00 2.853 0.000 302.00 328.00 3 4.0361e+00 4.7358e-03 3.2330e-02 -6.0000e+00 4.4285e-02 1.8939e-02 5.4422e-03 1.6061e-02 -6.0000e+00 4.7932e-02 1.3733e-04 3.7918e-03 8.0103e-03 -6.0000e+00 2.8645e-02 -1.0426e-02 2.0007e-03 2.3298e-03 -6.0000e+00 1.2393e-02 3.7479e-04 5.0567e-04 1.0215e-04 2.6138e-05 -6.0000e+00 8.6349e-04 -2.8304e-03 0.0000e+00 12 9 9 12 1 1 100.00 25.46 0.55 -0.00283 0.00097 80 10 1 5 0 576.010 33.25 20.01 25.46 29.05 4.4 1015.62 -3018 621 -11785 -8372 -17253 -5012 -5684 -554 -1216 -8619 -12406 -8213 -3194 186 -4897 1175 -1382 4041 -676 1861 5418 541 -3419 2249 -2113 -1321 1625 -4834 -2323 -5137 3286 1097 -1337 -218 -3603 -5068 -6005 -5583 646 795 731 -307 160 -1083 -227 922 -133 -257 -663 664 1508 1030 1053 1694 1967 1268 797 -257 269 -733 471 1097 2359 3269 1861 375 -435 -2499 -844 991 648 1881 872 1567 881 -960 -1896 -2453 -4277 -1972 -1937 -1102 -2366 -2097 -573 28 -81 1203 1082 1505 677 125 -1397 -1262 -1439 -766 -573 772 738 194 -310 -1597 -2239 -951 -1010 -1477 -502 -534 228 1129 1501 1670 1618 1051 -386 -739 -509 -488 109 954 393 821 791 585 172 228 -1030 -1094 -458 -538 -15 -920 -982 -406 -268 282 -158 713 944 58 65 -201 -637 -111 25 -572 -384 -781 -188 -221 -23 -56 -460 -699 -453 -188 12 -401 114 -148 432 -80 223 647 68 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